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Design of BOG re-liquefaction system of 20,000 m3 liquid hydrogen carrier
Byeongchang Byeon,Hwalong You,Dongmin Kim,Keun Tae Lee,Mo Se Kim,Gi Dock Kim,Jung Hun Kim,Sang Yoon Lee,Deuk Yong Koh 한국초전도저온학회 2023 한국초전도저온공학회논문지 Vol.25 No.3
This paper presents the design of a re-liquefaction system as a BOG (boil-off gas) handling process in liquid hydrogen transport vessels. The total capacity of the re-liquefaction system was assumed to be 3 ton/day, with a BOR (boil-off rate) of 0.2 %/day inside the cargo. The re-liquefaction cycle was devised using the He-Brayton Cycle, incorporating considerations of BOG capacity and operational stability. The primary components of the system, such as compressors, expanders, and heat exchangers, were selected to meet domestically available specifications. Case studies were conducted based on the specifications of the components to determine the optimal design parameters for the re-liquefaction system. This encompassed variables such as helium mass flow rate, the number of compressors, compressor inlet pressure and compression ratio, as well as the quantity and composition of expanders. Additionally, an analysis of exergy destruction and exergy efficiency was carried out for the components within the system. Remarkably, while previous design studies of BOG re-liquefaction systems for liquid hydrogen vessels were confined to theoretical and analytical realms, this research distinguishes itself by accounting for practical implementation through equipment and system design.
Experimental study on the cryogenic thermal storage unit (TSU) below -70 °C
Byeongchang Byeon,Kyoung Joong Kim,Sangkwon Jeong,Dong min Kim,Mo Se Kim,Gi Dock Kim,Jung Hun Kim,Sang Yoon Lee,Seong Woo Lee,Keun Tae Lee 한국초전도저온학회 2024 한국초전도저온공학회논문지 Vol.26 No.1
Over the past four years, as the COVID-19 pandemic has struck the world, cold chain of COVID-19 vaccination has become a hot topic. In order to overcome the pandemic situation, it is necessary to establish a cold chain that maintains a low-temperature environment below approximately 203K (-70°C), which is the appropriate storage temperature for vaccines, from vaccine suppliers to local hospitals. Usually, cryocoolers are used to maintain low temperatures, but it is difficult for small-scale local distribution to have cryocooler due to budget and power supply issues. Accordingly, in this paper, a cryogenic TSU (Thermal storage unit) system for vaccination cold chain is designed that can maintain low temperatures below -70°C for a long time without using a cryocooler. The performance of the TSU system according to the energy storage material for using as TSU is experimentally evaluated. In the experiments, four types of cold storage materials were used: 20% DMSO aqueous solution, 30% DMSO aqueous solution, paraffin wax, and tofu. Prior to the experiment, the specific heat of the cold storage materials at low temperature were measured. Through this, the thermal diffusivity of the materials was calculated, and paraffin wax had the lowest value. As a result of the TSU system's low-temperature maintenance test, paraffin wax showed the best low-temperature maintenance performance. And it recorded a low-temperature maintenance time that was about 24% longer than other materials. As a result of analyzing the temperature trend by location within the TSU system, it was observed that heat intrusion from the outside was not well transmitted to the low temperature area due to the low thermal conductivity of paraffin wax. Therefore, in the TSU system for vaccine storage, it was experimentally verified that the lower the thermal diffusivity of the cold storage material, the better low temperature maintenance performance.
Kim, Jhongkwon,Byeon, Byeongchang,Kim, Kyoung Joong,Jeong, Sangkwon 한국초전도저온공학회 2020 한국초전도저온공학회논문지 Vol.22 No.4
In this research, the variation of round-trip efficiency in a liquid air energy storage system (LAES) is calculated and an optimal configuration is found. The multiple stages of cold energy storage are simulated with several materials that process latent heat at different temperature ranges. The effectiveness in the charging and discharging processes of LAES is newly defined, and its relationship with the round-trip efficiency is examined. According to defined correlation, the effectiveness of the discharging process significantly affects the overall system performance. The round-trip efficiency is calculated for the combined cold energy storage materials of aqueous dimethyl sulfoxide (DMSO) solution, ethanol, and pentane theoretically. The performance of LAES varies depending on the freezing point of the cold storage materials. In particular, when the LAES uses several cold storage materials, those materials whose freezing points are close to room temperature and liquid air temperature should be included in the cold storage materials. In this paper, it is assumed that only latent heat is used for cold energy storage, but for more realistic analyzes, the additional consideration of the transient thermal situation to utilize sensible heat is required. In the case of such a dynamic system, since there is certainly more increased heat capacity of the entire storage system, the volume of the cold energy storage system will be greatly reduced.