황화수소를 제거한 흡착제의 산화재생반응

박도현,이영수,김희택,류경옥 ( Do Hyeon Park,Young Soo Lee,Hee Taik Kim,Kyong Ok Yoo ) 한국화학공학회 1992 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.30 No.6

In order to examine the effects of experimental variables on the oxidative regeneration of sulfided sorbents by H₂S, effluent gas (SO₂) was analyzed by G.C. with variation of reaction conditions and oxidized sorbents were characterized by XRD, SEM, and TGA-DTA. The reactivity of oxidative regeneration was maximum at 750℃ and it was revealed that the Fe₂O₃additive played an important role from the TGA-DTA analysis. Total SO₂ uptake was increased linearly as oxygen increased till 10 vol% and it was decreased drastically as oxygen increased. When the total flow rate was increased, total SO₂ uptake was increased linearly till 125 ml/min and thin-film mass transfer resistance was negligible above 100 ml/min. From the oxidative regeneration of sulfided sorbents with different particle sizes, it was found that for small particle, the SO₂ uptake was little and that the structural change formed during the sulfidation acted as the O₂ diffusion barrier. From the sulfidation at 650℃ after one sulfidation-regeneration cycle, it was found that regenerated sorbent at 750℃ was effective.

식생과 조석의 영향을 고려한 연안습지 퇴적물 내 물질거동 모형의 개발

박도현,왕수균,Park, Do-Hyun,Wang, Soo-Kyun 한국지하수토양환경학회 2009 지하수토양환경 Vol.14 No.6

습지는 다양한 생지화학적 반응기작을 통하여 폐수로부터 유입되는 유기오염물질을 완화/정화하는 지역으로 알려져있다. 본 연구에서는 습지에서 다양한 물질의 성상과 거동을 모의하기 위하여 수학적 모형을 개발하였다. 개발한 모형은 1차원 수직 포화 모형으로 이류, 수리학적 분산, 미생물에 의한 생분해, 산화/환원반응, 식생과 조수 등 외부환경의 영향을 고려하였다. 조수의 영향은 퇴적물 내 공극수의 흐름에 주기적인 변화를 일으키고, 계절에 따라 식생은 증발산과 뿌리로부터의 산소공급을 통해 흐름과 근권 내 산화/환원 환경에 영향을 미친다. 개발된 모형을 적용하여 습지퇴적물 내에 존재하는 관심물질의 공간적 및 시간적 분포 모의를 위한 가상의 수치실험을 수행하였다. 또한 대표적인 중금속 오염물질의 하나인 크롬의 습지퇴적물 내 성상과 거동을 모의하였다. 모의 결과는 식생 뿌리와 조수가 습지퇴적물 내 전자수용체, 환원물질, 중금속의 분포에 지대한 영향을 미칠 수 있음을 보여주었다. Wetlands can remove organic contaminants, metals and radionuclides from wastewater through various biogeochemical mechanisms. In this study, a mathematical model was developed for simulating the fate and transport of chemical species in marsh wetland sediments. The proposed model is a one-dimensional vertical saturated model which is incorporated advection, hydrodynamic dispersion, biodegradation, oxidative/reductive chemical reactions and the effects from external environments such as the growth of plants and the fluctuation of water level due to periodic tides. The tidal effects causes periodic changes of porewater flow in the sediments and the evapotranspiration and oxygen supply by plant roots affect the porewater flow and redox condition on in the rhizosphere along with seasonal variation. A series of numerical experiments under hypothetical conditions were performed for simulating the temporal and spatial distribution of chemical species of interests using the proposed model. The fate and transport of a trace metal pollutant, chromium, in marsh sediments were also simulated. Results of numerical simulations show that plant roots and tides significantly affect the chemical profiles of different electron acceptors, their reduced species and trace metals in marsh sediments.

암석거동의 수치해석적 연구를 위한 균열모형의 적용

박도현,전석원,Park, Do-hyun,Jeon, Seok-won 한국터널지하공간학회 2000 터널기술 Vol.2 No.2

암석은 지질학적 생성과정으로 인해 잠재적으로 많은 구조적 결함을 내포하고 있는 재료이다. 이러한 구조적 결함으로 인해 압축하중을 받고 있는 암석의 변형거동 및 파괴는 비선형적이다. 지금까지의 연구들에서는 암석의 비선형 거동을 모사하기 위해 균열모형, 즉 활주균열모형 (Sliding crack model) 과 전단균열모형 (Shear crack model) 을 사용하였다. 이 연구들에서는 암석의 비선형 응력-변형률 곡선과 균열성장으로 인해 발생되는 유효탄성정수들 ($E_1$, $E_2$, ${\nu}_1$, ${\nu}_2$, $G_2$) 의 변화와 같은 여러 가지 암석 거동을 모사하였다 (Kemeny, 1993; Jeon, 1996, 1998). 대부분의 이러한 연구들은 주로 균열모형의 암석거동의 적용에 대한 타당성을 검증하는데 그쳤으며 지하공간이나 사면설계 등의 실제적인 수치해석을 목적으로 균열모형을 적용한 연구는 그다지 많지 않다. 본 연구에서는 암석의 비선형 응력 변형률 곡선을 모사함으로써 균열모형의 암석에의 적용에 대한 타당성을 검증하며 실제적인 수치해석, 즉 상용되고 있는 유한요소해석 프로그램에 균열모형을 적용하였다. Rock is a very complex and heterogeneous material, containing structural flaws due to geologic generation process. Because of those structural flaws, deformation and failure of rock when subjected to differential compressive stresses is non-linear. To simulate the non-linear behavior of rock, mechanical crack models, that is, sliding and shear crack models have been used in several studies. In those studies, non-linear stress-strain curves and various behaviors of rock including the changes of effective elastic moduli ($E_1$, $E_2$, ${\nu}_1$, ${\nu}_2$, $G_2$) due to crack growth were simulated (Kemeny, 1993; Jeon, 1996, 1998). Most of the studies have mainly focused on the verification of the mechanical crack model with relatively less attempt to apply it to practical purposes such as numerical analysis for underground and/or slope design. In this study, the validity of mechanical crack model was checked out by simulating the non-linear behavior of rock and consequently it was applied to a practical numerical analysis, finite element analysis commonly used.

이동하는 음원에 적합한 고분해능 광대역 LPA 빔형성기법

박도현,박규태,이정훈,이수형,이균경,Park Do-Hyun,Park Gyu-Tae,Lee Jung-Hoon,Lee Su-Hvoung,Lee Kyun-Kyung 한국음향학회 2005 韓國音響學會誌 Vol.24 No.1

본 논문에서는 이동하는 광대역 음원의 위치추정에 적합한 높은 분해능을 가지는 광대역LPA (local polynomial approximation) 빔형성기법을 제안한다. 제안한 기법은 여러 개의 데이터 단편으로부터 구하는 공분산행렬 대신, 하나의 데이터 단편의 여러 개 주파수 성분으로부터 얻은 조향 공분산행렬을 이용하는 STMV(steered minimum variance) 기법을 LPA 빔형성기법에 적용하였다. STMV 기법의 센서가중벡터를 이용하여 LPA 가격함수를 구성하였으며 이를 최대화 시키는 방위각과 각속도를 2차원 탐색을 통하여 추정함으로써 높은 방위각 분해능을 가지도록 하였다. 모의신호와 실제 해상 실험 데이터를 이용하여 제안한 기법의 성능을 기존의 기법과 비교, 분석 하였다 This paper presents a wideband LPA (local polynomial approximation) beamforming algorithm that is appropriate for wideband moving sources. The Proposed wideband LPA algorithm adopts STMV (steered minimum variance) method that utilizes a steered covariance matrix obtained from multiple frequency components in one data snapshot, instead of multiple data snapshots in one frequency bin. The wideband LPA cost function is formed using STMV weight vector. The Proposed algorithm searches for the instantaneous DOA and angular velocity that maximize the wideband LPA cost function. resulting in a higher resolution performance than that of a DS LPA beamforming algorithm. Several simulations using artificial data and sea trial data are used to demonstrate the performance of the Proposed algorithm.

열에너지 저장 암반공동의 형상 및 레이아웃 설계 가이드라인

박도현,박의섭,Park, Dohyun,Park, Eui-Seob 한국암반공학회 2015 터널과지하공간 Vol.25 No.2

열에너지 저장은 고온 또는 저온의 잉여 열에너지를 저장하여 수요 발생 시 사용하기 위한 기술로서 에너지의 수요와 공급 사이의 불균형을 해소하고, 이를 통해 에너지 시스템의 효율을 향상시킬 수 있다. 특히 간헐적인 신재생에너지 자원을 열에너지 형태로 변환하거나 저장함으로써 에너지 믹스에서 신재생에너지의 비중을 제고할 수 있으며, 이를 위해서는 열에너지 저장 장치와의 조합이 반드시 필요하다. 지하 암반공동을 이용한 열에너지 저장은 높은 건설비용이 수반되어 그 활용이 제한적이지만, 대규모의 열에너지를 장기간 저장할 수 있는 가장 현실적인 방법이다. 또한 기후조건에 따라 외부로의 열손실이 영향을 받는 지상의 열저장소와는 달리, 열저장 지하 암반공동은 장기 운영 시 주변 암반의 히팅에 따른 열손실의 감소를 기대할 수 있다. 본고에서는 열저장 암반공동의 형상 및 다중배치 설계 시 고려해야 할 주요 인자들을 소개하고, 저장공간의 설계에 대한 가이드라인을 제안하였다. Thermal energy storage (TES) is a technology that stores surplus thermal energy at high or low temperatures for later use when the customer needs it, not just when it is available. TES systems can help balance energy demand and supply and thus improve the overall efficiency of energy systems. Furthermore, the conversion and storage of intermittent renewable resources in the form of thermal energy can help increase the share of renewable resources in the energy mix which refers to the distribution of energy consumption from different sources, and to achieve this, it is essential to combine renewable resources with TES systems. Underground TES using rock caverns, known as cavern thermal energy storage (CTES), is a viable option for large-scale, long-term TES utilization although its applications are limited because of the high construction costs. Furthermore, the heat loss in CTES can significantly be reduced due to the heating of the surrounding rock occurred during long-term TES, which is a distinctive advantage over aboveground TES, in which the heat loss to the surroundings is significantly influenced by climate conditions. In this paper, we introduced important factors that should be considered in the shape and multiple layout design of TES caverns, and proposed guidelines for storage space design.

A Direct Rapid Phenotypic Antimicrobial Susceptibility Test Enables Early Selection of Optimal Antibiotics to Treat Bacteremia in COVID-19 Patients

박도현,Chang Euijin,Kang Chang Kyung,Choe Pyoeng Gyun,Kim Nam Joong,Kim Taek Soo,Park Wan Beom,Oh Myoung-Don 대한감염학회 2021 Infection and Chemotherapy Vol.53 No.4

Background: Co-infection with bacteria and severe acute respiratory syndrome coronavirus 2 may result in greater use of healthcare resources and a poor prognosis. Therefore, early selection and use of optimal antibiotics are essential. The direct rapid antibiotic susceptibility test (dRAST) can detect antibiotic resistance within 6 h of a Gram smear result. This study aimed to assess the effectiveness of dRAST for improving early selection of appropriate antibiotics for coronavirus disease 2019 (COVID-19) patients with bacteremia. Materials and Methods: This retrospective study included 96 blood culture-positive COVID-19 patients. Bacterial isolates and antimicrobial resistance profiles of each case were evaluated. Cases were divided into two groups based on whether they underwent conventional antibiotic susceptibility test (AST) or dRAST. The time to optimal targeted treatment for the two groups was investigated and compared. In addition, we examined the proportion of cases for which appropriate antibiotics were selected and broad spectrum antibiotics were administered at 72 h from blood sample collection. Results: The mean time to optimal targeted antibiotic treatment was shorter for the dRAST group [55.7; standard deviation (SD), 28.7 vs. 92.3; SD, 51.1 h; P = 0.041]. The proportion of cases receiving optimal targeted antibiotics 72 h after blood collection for culture was higher [6/10 (60.0%) vs. 10/25 (40.0%)] and the percentage receiving broad spectrum antibiotics at 72 h was lower [6/10 (60.0%) vs. 19/25 (76.0%)] in the dRAST group than in the conventional AST group. In terms of microbiology profile, the contamination rate was high (35.5%) and multidrug-resistant strains were common (63.2%) in COVID-19 patients with bacteremia. Conclusion: Application of dRAST for selection of antibiotics to treat bacteremia in COVID-19 patients may enable earlier and optimal treatment. The high incidence of contamination and resistant organisms in blood cultures from COVID-19 patients suggest that dRAST may speed up appropriate targeted treatment.

회원기고 - 온실가스 배출권 거래제 실시에 즈음하여

박도현,Park, Do-Hyeon 한국산림경영인협회 2014 山林經營 Vol.213 No.-

수리역학 연계해석을 이용한 누수로 인한 터널 구조물 및 지반 거동의 분석

박도현,Dohyun Park 한국암반공학회 2023 터널과지하공간 Vol.33 No.4

Water leakage in tunnels is a defect that can affect tunnel stability and the ground movement by changing the stress and pore water pressure of the surrounding ground. Long-term or large-scale water leaks may lead to damage of tunnel structure and the surrounding environment, such as tunnel lining instability and ground surface settlement. The present study numerically investigated the effects of water leakage on the structural stability of a tunnel and the ground behavior. The tunnel was assumed to be under undrained conditions for preventing the inflow of the surrounding water and leaks occurred in the concrete lining after completion of the tunnel construction. A coupled hydro-mechanical analysis using a TOUGH-FLAC simulator developed in Python was conducted for assessing the leakage induced-behavior of the tunnel structure and ground under different conditions of the amount and location of water leak. Additionally, the effect of hydro-mechanical coupling terms on the results of coupled response was investigated and discussed.

TOUGH-FLAC 기법을 이용한 점열원 주변지반의 복합거동에 대한 벤치마크 수치모사

박도현,Dohyun Park 한국암반공학회 2024 터널과지하공간 Vol.34 No.2

The robustness of a numerical method means that its computational performance is maintained under various modeling conditions. New numerical methods or codes need to be assessed for robustness through benchmark testing. The TOUGH-FLAC modeling approach has been applied to various fields such as subsurface carbon dioxide storage, geological disposal of spent nuclear fuel, and geothermal development both domestically and internationally, and the modeling validity has been examined by comparing the results with experimental measurements and other numerical codes. In the present study, a benchmark test of the TOUGH-FLAC approach was performed based on a coupled thermal-hydro-mechanical behavior problem with an analytical solution. The analytical solution is related to the temperature, pore water pressure, and mechanical behavior of a fully saturated porous medium that is subjected to a point heat source. The robustness of the TOUGH-FLAC approach was evaluated by comparing the analytical solution with the results of numerical simulation. Additionally, the effects of thermal-hydro-mechanical coupling terms, fluid phase change, and timestep on the computation of coupled behavior were investigated.

OFDR을 이용한 PZT형 파장가변 필터의 이력 측정

박도현,예윤해,Park, Do-Hyun,Yeh, Yun-Hae 한국광학회 2008 한국광학회지 Vol.19 No.1

PZT형 파장가변 필터를 이용하여 파장스윕(wavelength-swept) 광원을 구성할 때 발진파장의 변화율을 일정하게 하려면 필터의 이력(hysteresis)특성을 알아야 한다. 이력특성을 무시하고 필터를 구동할 경우 파장스윕 광원을 사용하는 optical frequency domain reflectometry(OFDR) 시스템의 분해능이 떨어진다. 광스펙트럼 분석기(OSA)를 이용하여 필터의 이력특성을 측정할 수도 있지만 측정시간이 너무 길고 실제 구동조건에서의 이력특성은 측정할 수 없다는 문제가 있어 실제 구동조건에서 필터의 이력특성을 고속으로 측정할 수 있는 OFDR의 원리에 기초한 이력 측정법을 제시하였다. 파장스윕 광원과 간섭계, 신호처리 장치, 그리고 PC 프로그램으로 구성된 고속 이력측정장치를 구현하고, 이를 사용하여 필터 구동조건에서의 이력특성을 측정하였다. 마지막으로 측정된 이력특성을 파장스윕광원의 구동에 적용하여 선형적 파장변화를 얻음으로써 새로운 이력측정법의 유효성을 검증하였다. Implementation of a wavelength-swept source with constant tuning rate adopting a PZT-type tunable filter, requires the knowledge of hysteresis of the filter used. The hysteresis must be considered to avoid any degradation in resolution of the optical frequency domain reflectometry (OFDR) system. An optical spectrum analyzer (OSA) could be used to do the hysteresis measurement, but its measurement time is too long for the high-speed driving conditions for the filter. We proposed a new hysteresis measurement method based on OFDR, which could measure the hysteresis in a real driving condition. A hysteresis measurement apparatus consisted of wavelength-swept source, interferometer, signal processing unit, and PC program is built and used to do the measurement. It is concluded that the new method is useful in the measurement of hysteresis at real driving conditions by successfully implementing a swept-wavelength source whose wavelength change is linear in time.