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마그네슘용탕의 니켈 함량에 미치는 알루미늄, 망간 및 지르코늄의 영향
정대영 ( Dae Yeong Jeong ),문영훈 ( Young Hoon Moon ),문병기 ( Byoung Gi Moon ),박원욱 ( Won Wook Park ),손근용 ( Keun Yong Sohn ) 한국주조공학회 2015 한국주조공학회지 Vol.35 No.1
Variations of nickel contents and microstructures in molten magnesium alloys on the addition of aluminum, zirconium, and manganese have been investigated. Specimens were prepared by melting under SF6 and CO2 atmosphere and casting into a disc of 29 mm diameter with 7~10 mm thickness from the melt acquired at the top of crucible. Before casting, the molten metal was stirred for 3 minutes after each addition of alloying elements and maintained for 30 minutes for settling down. Results showed that zirconium did not significantly affect the content of nickel while aluminum remarkably reduced it by forming Al3Ni2 phase. When manganese are added to Mg-1wt%Ni alloy along with aluminum, both elements remarkably reduced the content of nickel. The addition of 1.5 wt% manganese to Mg-1wt%Ni alloy containing aluminum further reduced the content of nickel by more than 30%, during which an additional intermetallic phase Al10Mn3Ni was precipitated in the molten magnesium.