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      • KCI등재

        Electrochemical Degradation of Tetracycline Hydrochloride in Aqueous Medium by (B4C/C)-β-PbO2 Electrode

        Tingting Xie,Hongtao Hu,Donghui Chen,Pengzhe Sun 대한화학회 2017 Bulletin of the Korean Chemical Society Vol.38 No.7

        (B4C/C)-β-PbO2 electrodes were prepared by high-pressure molding technique and characterized by X-ray diffraction, scanning electron microscopy, polarization curves, cyclic voltammetry curves, and corrosion resistance test. In this paper, the effects of initial concentration, current density, electrolyte concentration, pH, and electrode spacing on tetracycline hydrochloride (TCH) degradation were investigated. Results indicated that modified electrode had high electrochemical activities, high oxygen evolution potential, and excellent corrosion resistance. The maximum removal rate of TCH could reach 90.87% at initial concentration of 300 mg/L after 120 min electrolysis with Na2SO4 concentration of 0.2 mol/L, electrode spacing of 1 cm, current density of 30 mA/cm2, and pH 3. Pseudo-first-order kinetics equation was followed during electrocatalytic degradation of TCH with 20%(B4C/C)-β-PbO2 electrode.

      • KCI등재

        Fast Search with Data-Oriented Multi-Index Hashing for Multimedia Data

        ( Yanping Ma ),( Hailin Zou ),( Hongtao Xie ),( Qingtang Su ) 한국인터넷정보학회 2015 KSII Transactions on Internet and Information Syst Vol.9 No.7

        Multi-index hashing (MIH) is the state-of-the-art method for indexing binary codes, as it di-vides long codes into substrings and builds multiple hash tables. However, MIH is based on the dataset codes uniform distribution assumption, and will lose efficiency in dealing with non-uniformly distributed codes. Besides, there are lots of results sharing the same Hamming distance to a query, which makes the distance measure ambiguous. In this paper, we propose a data-oriented multi-index hashing method (DOMIH). We first compute the covariance ma-trix of bits and learn adaptive projection vector for each binary substring. Instead of using substrings as direct indices into hash tables, we project them with corresponding projection vectors to generate new indices. With adaptive projection, the indices in each hash table are near uniformly distributed. Then with covariance matrix, we propose a ranking method for the binary codes. By assigning different bit-level weights to different bits, the returned bina-ry codes are ranked at a finer-grained binary code level. Experiments conducted on reference large scale datasets show that compared to MIH the time performance of DOMIH can be improved by 36.9%-87.4%, and the search accuracy can be improved by 22.2%. To pinpoint the potential of DOMIH, we further use near-duplicate image retrieval as examples to show the applications and the good performance of our method.

      • KCI등재

        Novel In Situ Synthesized Fe@C Magnetic Nanocapsules Used as Adsorbent for Removal of Organic Dyes and Its Recycling

        Ranran Li,Jieyi Yu,Asif Shah,Xinglong Dong,Xiaona Li,Hongtao Yu,Xie Quan,Youngguan Jung 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2016 NANO Vol.11 No.2

        Core/shell type carbon-coated Fe nanocapsules (Fe@C NCs) were in situ synthesized by DC arcdischarge plasma method in methane atmosphere. Such Fe nanocapsules have saturation magnetization of 29.32 emu/g and specific surface area of 85.86 m2/g. The carbon shell of Fe@C NCs was functionalized with oxygen-containing groups (such as –OH or –COOH) by using H2O2. The adsorption of organic dye, e.g., methylene blue (MB) was systematically investigated in different conditions, such as contact time, pH values and temperature. The maximum adsorption capacity (46.5 mg/g) was calculated by fitting the adsorption isotherms with Langmuir model, coincident with the experimental result of 44.5 mg/g. Kinetics data supported pseudo-second order model, and the thermodynamic process of adsorption was revealed as endothermic and spontaneous physisorption. The MB-absorbed Fe@C NCs can be entirely separated from the contaminative solution by a magnetic field and then successfully cycled for regeneration. After repetitive cycles of the adsorption/desorption experiments for five times, the removal efficiency can be maintained over 90%.

      • Large-Scale Production of Graphene Nanoribbons from Electrospun Polymers

        Liu, Nan,Kim, Kwanpyo,Hsu, Po-Chun,Sokolov, Anatoliy N.,Yap, Fung Ling,Yuan, Hongtao,Xie, Yanwu,Yan, Hao,Cui, Yi,Hwang, Harold Y.,Bao, Zhenan American Chemical Society 2014 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY - Vol.136 No.49

        <P>Graphene nanoribbons (GNRs) are promising building blocks for high-performance electronics due to their high electron mobility and dimensionality-induced bandgap. Despite many past efforts, direct synthesis of GNRs with controlled dimensions and scalability remains challenging. Here we report the scalable synthesis of GNRs using electrospun polymer nanofiber templates. Palladium-incorporated poly(4-vinylphenol) nanofibers were prepared by electrospinning with controlled diameter and orientation. Highly graphitized GNRs as narrow as 10 nm were then synthesized from these templates by chemical vapor deposition. A transport gap can be observed in 30 nm-wide GNRs, enabling them to function as field-effect transistors at room temperature. Our results represent the first success on the scalable synthesis of highly graphitized GNRs from polymer templates. Furthermore, the generality of this method allows various polymers to be explored, which will lead to understanding of growth mechanism and rational control over crystallinity, feature size and bandgap to enable a new pathway for graphene electronics.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/jacsat/2014/jacsat.2014.136.issue-49/ja509871n/production/images/medium/ja-2014-09871n_0007.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/ja509871n'>ACS Electronic Supporting Info</A></P>

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