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      • Irreversible field-induced magnetic phase transitions and properties of Ho<sub>3</sub>Co

        Baranov, N V,Goto, T,Hilscher, G,Markin, P E,Michor, H,Mushnikov, N V,Park, J-G,Yermakov, A A IOP Pub 2005 Journal of physics, an Institute of Physics journa Vol.17 No.21

        <P>The results of magnetic susceptibility, magnetization, electrical resistivity and specific heat measurements performed on Ho<SUB>3</SUB>Co single crystals show that this compound exhibits two different antiferromagnetic structures: AF<SUB>II</SUB> at 8 K<<I>T</I>< 22 K and AF<SUB>I</SUB> below <I>T</I><SUB>t</SUB>≈8 K. Below the Néel temperature <I>T</I><SUB>N</SUB> = 22 K the application of a magnetic field along the main crystallographic directions induces magnetic phase transitions which are accompanied by giant magnetoresistance. At <I>T</I><<I>T</I><SUB>t</SUB> the field-induced phase transitions along the <B><I>c</I></B>- and <B><I>b</I></B>-axes are found to be irreversible, and a small ferromagnetic component is observed along the <B><I>a</I></B>-axis. These peculiarities are associated with the non-Kramers character of the Ho ion and with the presence of a complex incommensurate magnetic structure of Ho<SUB>3</SUB>Co below <I>T</I><SUB>N</SUB>. The temperature coefficient of the electrical resistivity for Ho<SUB>3</SUB>Co above <I>T</I><SUB>N</SUB> over a wide temperature range is found to differ from that observed for other R<SUB>3</SUB>Co compounds. Such a behaviour is attributed to the presence of an additional contribution to the conduction electron scattering by spin fluctuations induced by f–d exchange in the itinerant d-electron subsystem. The value of this extra contribution and its temperature range is suggested to depend on the spin value of the R ion. The excess of the effective magnetic moment per R ion, which is observed in Ho<SUB>3</SUB>Co and in other R<SUB>3</SUB>M type compounds, is also attributed to spin fluctuations induced by f–d exchange.</P>

      • KCI등재SCOPUS

        Monitoring of the Content of Imidazoline-Containing Corrosion Inhibitor

        ( P. A. Zadorozhny ),( S. V. Sukhoverkhov ),( A. N. Markin ),( K. I. Savin ),( N. A. Prokuda ) 한국부식방식학회 2017 Corrosion Science and Technology Vol.16 No.4

        The qualitative composition of active components of the corrosion inhibitor CGW-85567 was studied. It was found that С18:2 and С18:1 imidazolines and the corresponding imidazolin-amides are the major components. The HPLC/MS technique was developed for their determination in the water solutions of monoethylene glycol (MEG). Industrial application of the inhibitor showed that MEG solution retained high concentration of the inhibitor for a long time after ceasing its addition into pipelines. Low values of the partition coefficients (0.010-0.014) of imidazolines in the system “water solution of MEG (concentration of MEG 62-85% v/v) - gas condensate” have allowed to pass on from the technology of continuous pumping of the inhibitor into protected pipelines to the periodic dosing technology. Taking into account a long time of circulation in the system and high temperatures during MEG regeneration process possible degradation products of the inhibitor were studied. N, N-dimethyl-dodecanamine-1, and N, N-dimethyl-tetradecanamine-1 were identified as major degradation products of the corrosion inhibitor CGW-85567.

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