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    UNIFAC 그룹 기여 모델에 의한 n-Octnae+n-Decane 계와 n-Octane+n-Dodecane 계의 인화점 계산 = Flash Point Calculation for n-Octane+n-Decane and n-Octane+n-Dodecane by UNIFAC Group Contribution Model

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    https://www.riss.kr/link?id=A100864329

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    다국어 초록 (Multilingual Abstract) kakao i 다국어 번역

    The flash point is used to categorize inflammable liquids according to their relative flammability. Such a categorization is important for the safe handling, storage, and transportation of inflammable liquids. The flash point temperature of two binary liquid mixtures(n-octane+n-decane and n-octane+n-dodecane) has been measured for the entire concentration range using Seta-flash closed cup tester based on the ASTM D3278 method. The closed cup flash point temperature was estimated using the UNIFAC(Universal Functional Activity Coefficient) group contribution model. The experimentally derived flash point was also compared with the predicted flash point from the UNIFAC model. The UNIFAC model is able to estimate the flash point fairly well for n-octane+n-decane mixture and n-octane+n-dodecane mixture.
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    The flash point is used to categorize inflammable liquids according to their relative flammability. Such a categorization is important for the safe handling, storage, and transportation of inflammable liquids. The flash point temperature of two binary...

    The flash point is used to categorize inflammable liquids according to their relative flammability. Such a categorization is important for the safe handling, storage, and transportation of inflammable liquids. The flash point temperature of two binary liquid mixtures(n-octane+n-decane and n-octane+n-dodecane) has been measured for the entire concentration range using Seta-flash closed cup tester based on the ASTM D3278 method. The closed cup flash point temperature was estimated using the UNIFAC(Universal Functional Activity Coefficient) group contribution model. The experimentally derived flash point was also compared with the predicted flash point from the UNIFAC model. The UNIFAC model is able to estimate the flash point fairly well for n-octane+n-decane mixture and n-octane+n-dodecane mixture.

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    참고문헌 (Reference)

    1 J. Gmehing, "Vapor-Liquid Equilibrium Data Collection"

    2 A. Fredenslund, "Vapor-Liquid Equilibria using UNIFAC" Elsevier 1977

    3 G. M. Wilson, "Vapor Liquid Equilibrium. XI. A New Expression for the Excess Free Energy of Mixing" 86 : 127-130, 1964

    4 B. E. Poling, "The Properties of Gases and Liquids" McGraw-Hill 2001

    5 하동명, "The Flash Point Measurement for Binary Flammable Mixture" 한국가스학회 18 (18): 60-65, 2014

    6 ASTM International, "Standard Test Methods for Flash Point of Liquids by Small Scale Closed-Cup Apparatus(ASTM D3278)"

    7 김화용, "Solubility of triclocarban in pure alkanols at different temperatures" 한국화학공학회 30 (30): 181-186, 2013

    8 Regulations, "Regulation(EC) No. 1272/2008 of the European Parliament and of the Council, on Classification, Labeling and Packaging of Substances and Mixtures, Amending and Repealing Directives 67/548/EEC and 1999/45/Ec, and Amending Regulation(EC. No. 1907/2006"

    9 R. C. Lance, "Measurement of Flash Points : Apparatus, Methodology, Applications" 3 : 107-119, 1979

    10 하동명, "Measurement and estimation of the lower flash points for the flammable binary systems using a Tag open cup tester" 한국화학공학회 24 (24): 551-555, 2007

    1 J. Gmehing, "Vapor-Liquid Equilibrium Data Collection"

    2 A. Fredenslund, "Vapor-Liquid Equilibria using UNIFAC" Elsevier 1977

    3 G. M. Wilson, "Vapor Liquid Equilibrium. XI. A New Expression for the Excess Free Energy of Mixing" 86 : 127-130, 1964

    4 B. E. Poling, "The Properties of Gases and Liquids" McGraw-Hill 2001

    5 하동명, "The Flash Point Measurement for Binary Flammable Mixture" 한국가스학회 18 (18): 60-65, 2014

    6 ASTM International, "Standard Test Methods for Flash Point of Liquids by Small Scale Closed-Cup Apparatus(ASTM D3278)"

    7 김화용, "Solubility of triclocarban in pure alkanols at different temperatures" 한국화학공학회 30 (30): 181-186, 2013

    8 Regulations, "Regulation(EC) No. 1272/2008 of the European Parliament and of the Council, on Classification, Labeling and Packaging of Substances and Mixtures, Amending and Repealing Directives 67/548/EEC and 1999/45/Ec, and Amending Regulation(EC. No. 1907/2006"

    9 R. C. Lance, "Measurement of Flash Points : Apparatus, Methodology, Applications" 3 : 107-119, 1979

    10 하동명, "Measurement and estimation of the lower flash points for the flammable binary systems using a Tag open cup tester" 한국화학공학회 24 (24): 551-555, 2007

    11 T. Khalili, "Measurement and Caluation of Flash Point of Binary Aqueous-Organic and Organic-Organic Solutions" 312 : 101-105, 2006

    12 H. Renon, "Local Compositions in Thermodynamic Excess Functions for Liquid Mixtures" 14 : 135-144, 1968

    13 S. Balasubramonian, "Flash Point Prediction for the Binary Mixture of Phosphatic Solvents and n-Dodecane from UNIFAC Group Contribution Model" 33 : 183-187, 2015

    14 W. A. Affens, "Flammability Properties of Hydrocarbon Solutions in Air" 17 (17): 482-488, 1972

    15 H. L. Chatelier, "Estimation of Firedamp by Flammability Limits" 19 (19): 388-395, 1891

    16 D. A. Crowl, "Chemical Process Safety Fundamentals with Applications" Prentice-Hall 1990

    17 C. L. Yaws, "Chemcal Properties Hand Book" McGraw-Hill Education 1999

    18 S. Kumar, "An Empirical Equation for Vapor Pressure of tri-n-Butyl Phosphate in the Temperature Range of 273. 15 to 562. 15 K" 126 : 237-239, 1999

    19 L. Y. Phoon, "A Review of Flash Point Prediction Models for Flammable Liquid Mixtures" 53 : 12523-12565, 2014

    20 S. Y. Kim, "A Prediction Model for Flash Point of Binary Liquid Mixtures" 23 (23): 166-169, 2010

    21 B. Hanley, "A Model for the Calculation and the Verification of Closed Cup Flash Points for Multicomponent Mixtures" 17 (17): 86-97, 1998

    22 H. J. Liaw, "A Mathematical Model for Predicting the Flash Point of Binary Solutions" 15 : 429-438, 2002

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    2027 평가 재인증평가 신청대상 (재인증)
    2021-01-01 등재 등재학술지 유지 (재인증) KCI등재
    2018-01-01 등재 등재학술지 유지 (등재유지) KCI등재
    2015-01-01 등재 등재학술지 유지 (등재유지) KCI등재
    2011-01-01 등재 등재학술지 유지 (등재유지) KCI등재
    2009-01-01 등재 등재학술지 유지 (등재유지) KCI등재
    2007-01-01 등재 등재학술지 유지 (등재유지) KCI등재
    2005-10-26 학술지명변경 한글명 : 산업안전학회지 -> 한국안전학회지 KCI등재
    2005-02-28 학회명변경 한글명 : 한국산업안전학회 -> 한국안전학회
    영문명 : The Korean Institute Of Industrial Safety -> The Korean Society of Safety
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    2004-01-01 등재 등재학술지 선정 (등재후보2차) KCI등재
    2003-01-01 등재 등재후보 1차 PASS (등재후보1차) KCI등재후보
    2001-07-01 등재 등재후보학술지 선정 (신규평가) KCI등재후보
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