2D–3D nucleation and growth of palladium on graphite electrode

다국어 초록 (Multilingual Abstract)

Nucleation and growth of palladium on graphite electrode was studied by electrochemical techniques.
Crossovers in cyclic voltammograms demonstrate that the deposition of palladium proceed via a nucleation/growth mechanism. In the early stage of the deposition, two-dimensional (2D–3D)nucleation and growth proceeding through instantaneous and a multitude of progressive steps followed the initial double layer charging. Non-linear fitting methods were applied to obtain the kinetic parameters in the light of Bewick, Fleischmann, and Thirsk theory for 2D and Armstrong, Fleischmann,and Thirsk model for 3D nucleation and growth process.

참고문헌 (Reference)

1 J. Kois, 320 : 9-12, 2011

2 M. Daniel, 114 : 18-22, 2009

3 W.J. Lorenz, 335 : 32-43, 1995

4 R.D. Armstrong, 11 : 208-223, 1966

5 A. Bewick, 58 : 2200-2216, 1962

6 E. Gomez, 422 : 139-147, 1997

7 O. Galkin, 365 : 425-439, 2007

8 E. Barbier, 64 : 363-369, 2009

9 E.E. Finney, 317 : 351-374, 2008

10 Y. Lai, 639 : 187-192, 2010

11 E. Matthijs, 570 : 123-133, 2004

12 F.J. Barry, 537 : 151-163, 2002

13 M.P. Anisimov, 40 : 733-746, 2009

14 E. Varadarajan, 230 : 258-262, 2001

15 M.J. Llorca, 376 : 151-160, 1994

16 R. Gomez, 327 : 202-215, 1995

17 C. Milhano, 614 : 24-30, 2008

18 H. Naohara, 45 : 3305-3309, 2000

19 H. Naohara, 500 : 435-445, 2001

20 S.C. Chen, 314 : 5-14, 2008

21 C.H. Lee, 22 : 877-884, 2007

22 A. Mourato, 53 : 664-672, 2007

23 O. Corduneanu, 624 : 97-108, 2008

24 I. Danaee, 14 : 57-62, 2010

25 B.J. Hinch, 42 : 309-311, 1991

26 G. Meyer, 202 : 125-141, 1988

27 M. Baldauf, 38 : 2145-2153, 1993

28 S.M. Pawar, 459 : 515-520, 2008

29 J. Vazquez-Arenas, 52 : 892-903, 2006

30 I. Danaee, 662 : 415-420, 2011

31 J. Kubisztal, 33 : 4488-4494, 2008

32 J. Kubisztal, 252 : 8605-8610, 2006

33 Q. Han, 400 : 265-269, 2005

34 H. Duncan, 53 : 6845-6850, 2008

35 S. Fletcher, 28 : 917-923, 1983

36 S. Fletcher, 159 : 267-285, 1983

37 D.R. Salinas, 470 : 120-125, 1999

38 M. Jafarian, 36 : 1169-1173, 2006

39 M. Jafarian, 52 : 5437-5443, 2007

40 G.J. Hills, 19 : 657-670, 1974

41 F. Lantelme, 121 : 311-327, 1981

42 G. Gunawardena, 138 : 225-239, 1982

43 G.R. Stafford, 2 : 35-44, 1999

44 R.G. Barradas, 193 : 23-26, 1985

45 G.A. Somorjai, "Surface Chemistry and Catalysis" Wiley 1994

46 J.A. Rodriguez, "Physical and chemical properties of bimetallic surfaces" 24 : 223-287, 1996

47 A.J. Bard, "Electrochemical Methods: Fundamentals and Applications" Wiley 2001

48 M. Fleischmann, "Advanced Electrochemistry and Electrochemical Engineering" Academic 123-, 1963