연결부에 아민기를 가지는 디에폭사이드 화합물의 효율적인 합성방법 = Efficient Synthetic Method of Diepoxide Compound Containing Amino group in the Connecting Part

국문 초록 (Abstract)

메틸아민과 에피클로로히드린을 반응시켜 N,N-diglycidly methyl amine을 합성하였다. 이 반응의 진행과정을 GC분석을 통해 반응 중간체들을 관찰함으로써 연구하였다. 연결기로 아민을 사용하여 디에폭사이드 화합물을 합성하는 경우에 있어서는 연결기로 디올을 사용하는 경우에 잘 알려진 1단계 반응(반응초기에 염기를 투입, 분석수율: 36.2%)에 비해서 2단계 반응(염기가 없는 상태에서 반응 후 염기를 투입, 분석수율: 91.5%)이 훨씬 효율적이었다.

다국어 초록 (Multilingual Abstract)

N,N-diglycidyl methyl amine was prepared by reacting methyl amine with epichlorohydrin. The process of the reaction was studied by analyzing intermediates using GC. In the case of preparation of diepoxide compounds using amines as a connecting group, two-step reaction (base was added when the reaction in the absence of base was stopped, yield: 91.5%) was much more efficient than one-step reaction (base was added at the beginning o f the reaction, yield: 36.2%) which has been well-known in the case of using diols as a connecting group.