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      에폭시 복합체의 표면 및 기계적 특성에 미치는 액상고무의 효과 = Influences of Liquid Rubber on the Surfacial and Mechanical Properties of Epoxy Composites

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      https://www.riss.kr/link?id=A75055540

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      다국어 초록 (Multilingual Abstract)

      Epoxy resins are thermoset polymers that exhibit good adhesion, creep resistance, heat resistance, and chemical resistance. These polymers, however, give poor resistance to crack propagation and low impact strength. In this study, epoxy/carboxyl-termi...

      Epoxy resins are thermoset polymers that exhibit good adhesion, creep resistance, heat resistance, and chemical resistance. These polymers, however, give poor resistance to crack propagation and low impact strength. In this study, epoxy/carboxyl-terminated butadiene acrylonitrile (CTBN) and epoxy/amine-terminated butadiene acrylonitrile (ATBN) composites were prepared with different ratio of CTBN and ATBN to improve low impact strength of epoxy resin. The impact strength of epoxy/elastomeric composites shows high values with increasting nonpolar surface free energy while the tensile strength and the glass transition are decreased. The highest surface free energy, impact strength observed when 15 phr CTBN and 15 phr ATBN added, respectively. It can be concluded that as liquid rubber to improve impact strength of epoxy resin, ATBN is more preferable to CTBN.

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      참고문헌 (Reference)

      1 Raja Thomas, 48 : 1965-, 2007

      2 C.K. An, "에폭시 수지의 화학, 합성과 응용" 31 : 130-, 1996

      3 J.H. Lee, "고분자 재료화학" 삼광출판사 2002

      4 Rolf E. Humel, "Understanding materials science" 2001

      5 H.S. Jung, "Toughness Improvement of High performance Epoxy Resin: Ⅱ. Morphology Study of Modified Epoxy Resin" 17 : 513-, 1993

      6 Shyue-Tzoo Lin, "Synthesis and impact properties of siloxane-DGEBA epoxy copolymers" 34 : 1907-, 1996

      7 E.K. Lee, "Stablization of chlorosulfonated polyethylene (CSM) Rubber Emulsion with surfactant mixture" 36 : 246-, 2001

      8 Ochi M, "Rubber-modified epoxy resins coating high funtionality acrylic elastomers" 29 : 1381-, 1984

      9 R. Bagheri, "Role of particle cavitation in rubber-toughened epoxies: Ⅱ. Inter-particle distance" 41 : 269-, 2000

      10 P. Bartlet, "Relationships between structure and mechanical properties of rubber modified epoxy networks cure with dicyanodiamide hardner" 30 : 2955-, 1985

      1 Raja Thomas, 48 : 1965-, 2007

      2 C.K. An, "에폭시 수지의 화학, 합성과 응용" 31 : 130-, 1996

      3 J.H. Lee, "고분자 재료화학" 삼광출판사 2002

      4 Rolf E. Humel, "Understanding materials science" 2001

      5 H.S. Jung, "Toughness Improvement of High performance Epoxy Resin: Ⅱ. Morphology Study of Modified Epoxy Resin" 17 : 513-, 1993

      6 Shyue-Tzoo Lin, "Synthesis and impact properties of siloxane-DGEBA epoxy copolymers" 34 : 1907-, 1996

      7 E.K. Lee, "Stablization of chlorosulfonated polyethylene (CSM) Rubber Emulsion with surfactant mixture" 36 : 246-, 2001

      8 Ochi M, "Rubber-modified epoxy resins coating high funtionality acrylic elastomers" 29 : 1381-, 1984

      9 R. Bagheri, "Role of particle cavitation in rubber-toughened epoxies: Ⅱ. Inter-particle distance" 41 : 269-, 2000

      10 P. Bartlet, "Relationships between structure and mechanical properties of rubber modified epoxy networks cure with dicyanodiamide hardner" 30 : 2955-, 1985

      11 K. Dinakaran, "Preparation and characterization of bismaleimide/ 1,3-dicyanatobenzene modified epoxy intercrosslinked matrices" 39 : 2225-, 2003

      12 Olabisi, Robeson, "Polymer-Polymer Miscibility" Academic Press 1982

      13 Paul, "Polymer-Blends" John Wiley & Sons 2000

      14 S. Wu, "Polymer Interface and adhesion" Marcel Dekker 1982

      15 A W. Adamson, "Physical Chemistry of Surfaces" John wiley 1990

      16 D. Ratna, "Phase separation in liquid rubber modified epoxy mixture. Relationship between curing conditions, morphology and ultimate behavior" 42 : 4209-, 2001

      17 Kunz SC, "Morphology and toughness characterization of epoxy resin modified with amine and carboxyl-terminated rubbers" 23 : 906-, 1982

      18 N. Chiki, "Modification of epoxy resin using reactive liquid (ATBN) rubber" 38 : 251-,

      19 L.T. Manzione, "McPherson, Rubber-modified epoxies. II. Morphology and mechanical properties" 26 : 907-, 1981

      20 L.T. Manzione, "McPherson, Rubber-modified epoxies. I. Transitions and morphology" 26 : 889-, 1981

      21 J.N. Israelachvili, "Intermolecular and Surface Forces" Academic Press 1962

      22 S.J. Park, "Interfacial Forces and Fields: Theory and Applications" Marcel Dekker 1999

      23 S.J. Park, "Interfacial Forces and Field Theory and Applications" Marcel Dekker 1999

      24 Alan C. Meeks, "Fracture and mechanical properties of epoxy resins and rubber-modified epoxy resins" 15 : 675-, 1974

      25 D.K. Owens, "Estimation of the surface free energy of polymers" 13 : 741-, 1969

      26 C.A. May, "Epoxy Resins:Chemistry and Technology" Marcel Dekker 1998

      27 S.J. Park, "Effect of fiber shapes on physical characteristics of non-circular carbon fibers-reinforced composites" 352 : 34-, 2003

      28 S. V. Rosato, "Disigning with Plastics and Composites" Nostrand Reinhold 1991

      29 A.J. Kinloch, "Deformation and fracture behaviour of rubber-toughened epoxy: 2. Failure criteria" 24 : 1355-, 1983

      30 A. J. Kinloch, "Deformation and fracture behaviour of rubber-toughened epoxy: 1. Microstructure and fracture studies" 24 : 1341-, 1983

      31 F.M. Fowkes, "Contact angles and the equilibrium spreading pressures of liquids on hydrophobic solids" 200-, 1980

      32 C.W. Wise, "CTBN rubber phase precipitation in model epoxy resins" 41 : 4625-, 2000

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      학술지 이력

      학술지 이력
      연월일 이력구분 이력상세 등재구분
      2024 평가예정 재인증평가 신청대상 (재인증)
      2021-01-01 평가 등재학술지 선정 (계속평가) KCI등재
      2020-12-01 평가 등재후보로 하락 (재인증) KCI등재후보
      2017-01-01 평가 등재학술지 유지 (계속평가) KCI등재
      2013-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2010-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2009-02-03 학술지명변경 한글명 : 엘라스토머 -> 엘라스토머 및 콤포지트
      외국어명 : elastomer -> Elastomers and Composites
      KCI등재
      2008-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2007-04-03 학회명변경 한글명 : (사)한국고무학회 -> 한국고무학회
      영문명 : The Korean Institute Of Rubber Industry -> The Rubber Society of Korea
      KCI등재
      2006-05-18 학회명변경 영문명 : The Korean Institute Of Rubber Industry -> The Rubber Society of Korea KCI등재
      2005-01-01 평가 등재학술지 선정 (등재후보2차) KCI등재
      2004-01-01 평가 등재후보 1차 PASS (등재후보1차) KCI등재후보
      2003-01-01 평가 등재후보학술지 유지 (등재후보1차) KCI등재후보
      2001-07-01 평가 등재후보학술지 선정 (신규평가) KCI등재후보
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      기준연도 WOS-KCI 통합IF(2년) KCIF(2년) KCIF(3년)
      2016 0.16 0.16 0.16
      KCIF(4년) KCIF(5년) 중심성지수(3년) 즉시성지수
      0.2 0.21 0.257 0.03
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