<P><B>Abstract</B></P><P>With a corona-excited supersonic expansion technique using a pinhole-type glass nozzle, the jet-cooled <I>o</I>-cyanobenzyl radical was generated from <I>o</I>-tolunitrile ...
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https://www.riss.kr/link?id=A107690868
2005
-
SCOPUS,SCIE
학술저널
6-10(5쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P><B>Abstract</B></P><P>With a corona-excited supersonic expansion technique using a pinhole-type glass nozzle, the jet-cooled <I>o</I>-cyanobenzyl radical was generated from <I>o</I>-tolunitrile ...
<P><B>Abstract</B></P><P>With a corona-excited supersonic expansion technique using a pinhole-type glass nozzle, the jet-cooled <I>o</I>-cyanobenzyl radical was generated from <I>o</I>-tolunitrile seeded in a large amount of inert carrier gas He. The vibronically resolved visible emission spectra of the <I>o</I>-cyanobenzyl radical in the D<SUB>1</SUB>→D<SUB>0</SUB> transition were recorded for the first time with a Fourier transform spectrometer equipped with a visible beam splitter. The electronic transition and a few vibrational modes in the ground electronic state were identified from the analysis of the spectra observed.</P>
Electron affinity and inversion distortion of dibenzo-p-dioxin