디메틸포름아미드 중에서 디이소부틸니트로소아민의 음극 반응 = Cathodic Reaction of Di-iso-butylnitrosoamine in Dimethylformamide Containing 0.1M NaClO₄

다국어 초록 (Multilingual Abstract)

By chronopotentiometric and potential-current methods, the cathodic reactions of di-iso-butylnitroscamine (Di-iso-BNA) were investigated in nonaqueous electrolyte, 0.1M NaClO₄in dimethylformamide, on the platinum electrode process of Di-iso-BNA was ranged from ??.
The E¼ value (-0.264v) of 1mMDi-iso-BNA obtained with S.C.E. reference electrode in dimethylformamide(DMF) was -0.122v larger than the value measured by Pb-Pb(Ⅱ) reference electrode in it at ??.
The transfer coefficient(α), diffusion coefficient (D) and Tafel slope in cathodic reaction of Di-iso-BNA were 0.17, ??, and -0.771v respectively.
As increasing cathodic current density upto ??, short transition times of 5mM
Di-iso-BNA were decreased reversely-that is, chronopotentiometric constants, K values were decreased. Similarly, in accordance with the increase of the concentration of Di-iso-BNA upto 0.1∼5.0mM, the E¼ values were decreased at the constant current density of ??.