Inorganic-organic hybrid nanoporous materials as adsorbent to remove VOCs

다국어 초록 (Multilingual Abstract)

Inorganic–organic hybrid nanoporous materials were prepared by the co-condensation of 1,2-bis(triethoxysilyl)ethane (BTSE) with 1,3-
bis(triethoxysilyl)benzene (BTSB) or 4,4'-bis(triethoxysilyl)-1,1'-biphenyl (BTSP). The nanoporous materials had broad pore-size distribution in
the range of mesopore and macropore. The nanoporous materials prepared by co-condensation of BTSE with more than 30 wt% of BTSP showed
an enhanced removal capability of volatile organic compounds (VOCs) from air compared to that prepared with BTSE only, probably due to the
affirmative interaction between VOCs and aromatic ring in the nanoporous materials. The VOC generation from polypropylene/talc composite
(PPF) was reduced to around half when three part of these inorganic–organic hybrid nanoporous material was added per 100 part of PPF during the
melt compounding process as an additive, which suggests a new application of nanoporous material.

참고문헌 (Reference)

1 S. Polarz, 2 : 581-, 2002

2 C. Schumacher, 45 : 5586-, 2006

3 S. Biz, 40 : 329-, 1998

4 K. Moller, 10 : 2950-, 1998

5 D. Zhao, 120 : 6024-, 1998

6 A. Sayari, 8 : 1840-, 1996

7 M.A. Herna´ndez, 43 : 1779-, 2004

8 A. Corma, 97 : 2373-, 1997

9 A. Dabrowski, 253 : 5747-, 2007

10 X. Shi, 46 : 7944-, 2007

11 B. Tian, 1186-, 2002

12 A.C.C. Chang, 17 : 468-, 2003

13 A. Stein, 12 : 1403-, 2000

14 M.H. Lim, 11 : 3285-, 1999

15 M. Kruk, 13 : 3169-, 2001

16 B.J. Melde, 11 : 3302-, 1999

17 C.M. Bambrough, 201 : 220-, 1998

18 C.M. Bambrough, 8 : 569-, 1998

19 S. Inagaki, 726 : 225-, 2002

20 T. Asefa, 402 : 867-, 1999

21 M.P. Kapoor, 12 : 3078-, 2002

22 A. Bhaumik, 2003 : 470-, 2003

23 K. Nakajima, 17 : 1839-, 2005

24 S. Inagaki, 121 : 9611-, 1999

25 S. Wang, 33 : 694-, 2007

26 P.I. Ravikovitch, 105 : 6817-, 2001

27 A. Galarneau, 17 : 8328-, 2001

28 B.L. Newalkar, 14 : 304-, 2002

29 H.M. Jeong, 16 : 719-, 2005

30 M.A. Markowitz, 104 : 10820-, 2000

31 Inkwon Hong, "VOCs Degradation Performance of TiO2 Aerogel Photocatalyst Prepared in SCF Drying" 한국공업화학회 12 (12): 918-925, 2006

32 Jeong Ho Chang, Kyung Ja Kim, Byung-Soo Bae, Chang Han Shim, "Preparation of Mesoporous Silica using MPEG-b-PLA Diblock Copolymers with Controlled Pore Size at Room Temperature" 한국공업화학회 11 (11): 471-474, 2005

33 Woo-Kul Lee, Su-Mi Im, "Effect of BSA Substitution into Calcium Phosphate on the Surface-mediated Responses of Bone-Forming Cells" 한국공업화학회 12 (12): 932-938, 2006

34 Dong Lyun Cho, Dae Chul Chung, Gwi-Sung Kim, "Decomposition and Solidification of Hazardous Volatile Organic Compounds Through Plasma Chemical Reactions" 한국공업화학회 13 (13): 287-291, 2007

35 Jongheop Yi, Younghun Kim, "Advances in Environmental Technologies via the Application of Mesoporous Materials" 한국공업화학회 10 (10): 41-51, 2004