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    Dielectric properties and microstructures of (CaxSr1-x) ZrO3 ceramics

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    https://www.riss.kr/link?id=A105973194

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    The effects of Ca/Sr ratio and the sintering temperature on the properties of (CaxSr(1-x))ZrO3 (CSZ) ceramics were investigatedin this study. CSZ ceramics were prepared using solid-state reaction process, which were sintered in air at temperaturesranging from 1350 oC to 1450 oC. Their structures were characterized by X-ray Diffraction (XRD), Scanning ElectronMicroscopy (SEM), and Transmission Electron Microscopy (TEM). The change in Ca/Sr ratio significantly affected thecrystalline phase and the dielectric properties of the (CaxSr(1-x))ZrO3 ceramics. The secondary phase, Ca0.15Zr0.85O1.85, wasobserved and increased correspondingly with the rising of sintering temperatures. In order to understand the effects ofsecondary phase on the dielectric properties of CSZ ceramics, the Ca0.15Zr0.85O1.85 phase was prepared individually using solidstatemethod. The Ca0.15Zr0.85O1.85 ceramics sintered at 1500 oC for 2 hours possessed a dielectric constant (εr) of 21.7, adielectric loss (tanδ) of 49.510−4 and an Insulation Resistance (IR) of 2.1 × 1010 Ω. The (Ca0.7Sr0.3)ZrO3 ceramics exhibited thebest dielectric properties, with a permittivity of 29, a dielectric loss (tanδ) of 2.7 × 10−4, and an Insulation Resistance (IR) of2.6 × 1012 Ω.
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    The effects of Ca/Sr ratio and the sintering temperature on the properties of (CaxSr(1-x))ZrO3 (CSZ) ceramics were investigatedin this study. CSZ ceramics were prepared using solid-state reaction process, which were sintered in air at temperaturesrang...

    The effects of Ca/Sr ratio and the sintering temperature on the properties of (CaxSr(1-x))ZrO3 (CSZ) ceramics were investigatedin this study. CSZ ceramics were prepared using solid-state reaction process, which were sintered in air at temperaturesranging from 1350 oC to 1450 oC. Their structures were characterized by X-ray Diffraction (XRD), Scanning ElectronMicroscopy (SEM), and Transmission Electron Microscopy (TEM). The change in Ca/Sr ratio significantly affected thecrystalline phase and the dielectric properties of the (CaxSr(1-x))ZrO3 ceramics. The secondary phase, Ca0.15Zr0.85O1.85, wasobserved and increased correspondingly with the rising of sintering temperatures. In order to understand the effects ofsecondary phase on the dielectric properties of CSZ ceramics, the Ca0.15Zr0.85O1.85 phase was prepared individually using solidstatemethod. The Ca0.15Zr0.85O1.85 ceramics sintered at 1500 oC for 2 hours possessed a dielectric constant (εr) of 21.7, adielectric loss (tanδ) of 49.510−4 and an Insulation Resistance (IR) of 2.1 × 1010 Ω. The (Ca0.7Sr0.3)ZrO3 ceramics exhibited thebest dielectric properties, with a permittivity of 29, a dielectric loss (tanδ) of 2.7 × 10−4, and an Insulation Resistance (IR) of2.6 × 1012 Ω.

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    참고문헌 (Reference)

    1 M. Pollet, A362 : 167-173, 2003

    2 K. Kiyoshi, 108 : 355-359, 1998

    3 Y. Suzuki, 83 : 2091-2096, 2000

    4 S. K. Lim, 9 : 143-144, 1999

    5 Woo-Jin Lee, 31 : 521-524, 2005

    6 Weina Chen, 25 : 1505-1511, 2014

    7 Cheng-Hsing Hsu, 787 : 338-341, 2014

    8 H. Stetson, 44 : 420-421, 1961

    9 Changhong Chen, 252 : 7585-7589, 2006

    10 S. Hesaraki, 48 (48): 166-172, 2012

    1 M. Pollet, A362 : 167-173, 2003

    2 K. Kiyoshi, 108 : 355-359, 1998

    3 Y. Suzuki, 83 : 2091-2096, 2000

    4 S. K. Lim, 9 : 143-144, 1999

    5 Woo-Jin Lee, 31 : 521-524, 2005

    6 Weina Chen, 25 : 1505-1511, 2014

    7 Cheng-Hsing Hsu, 787 : 338-341, 2014

    8 H. Stetson, 44 : 420-421, 1961

    9 Changhong Chen, 252 : 7585-7589, 2006

    10 S. Hesaraki, 48 (48): 166-172, 2012

    11 Yi-Seul Kim, 2 (2): R3021-R3025, 2013

    12 R.D. Shannon, A32 : 751-767, 1976

    13 Maik Lang, 286 : 271-276, 2012

    14 Chunsheng Shi, 27 (27): 7118-7120, 2006

    15 Yi, J. Y., 85 : 3004-3010, 2002

    16 Lewis, G. V, 68 : 555-558, 1985

    17 Yeon Soo Sung, 13 : 217-230, 2010

    18 Zushu Li, 90 (90): 364-368, 2007

    19 Michael Pollet, 25 : 2773-2777, 2005

    20 Woo-Jin Lee, 31 : 521-524, 2005

    21 A. J. Moulson, 79 : 79-82, 1990

    22 C. L. Huang, 71 : 17-22, 2001

    23 윤상옥, "Microwave dielectric properties of ceramic/glass composites with bismuth-zinc borosilicate glass" 세라믹공정연구센터 11 (11): 47-51, 2010

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