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다국어 초록 (Multilingual Abstract)

Two novel binuclear metal-organic coordination complexes [Cd_2(L)_2(bpy)_2(H_2O)_2]·6H_2O (1), [Cd_2(L)_2(phen)_2-(H_2O)_2]·2H_2O (2) (where L = 2-methylquinoline-3,4-dicarboxylate dianion, bpy = 2,2'-bipyridine, phen = 1,10-phenanthroline) have been synthesized under hydrothermal conditions and characterized by single crystal Xray diffraction, spectral method (IR), elemental analysis and thermal gravimetric analysis (TGA). Both 1 and 2 consist of two Cd(II) atoms bridged by two monoatomic bridging carboxylate groups from two L ligands,and the second carboxylate group of each L is monodentately coordinated to Cd(II), creating a sevenmembered chelating ring. The coordination at each metal nucleus is completed by a water molecule and a chelating bidentate molecule. The 3D structures of the complexes are stabilized by π-π stacking interactions and hydrogen-bonds.

참고문헌 (Reference)

1 Zhang, J. P, 2385-, 2009

2 Grillone, M. D, 10 : 2171-, 1991

3 Steel, P. J, 38 : 243-, 2005

4 Hunter, C. A, 23 : 101-, 1994

5 Borrows, A. D, 24 : 329-, 1995

6 Evans, O. R, 35 : 511-, 2002

7 Lin, W. B, 120 : 13273-, 1998

8 Lin, W. B, 2263-, 2000

9 Aakeröy, C. B, 38 : 1815-, 1999

10 Sekiya, R, 8 : 4803-, 2000

1 Zhang, J. P, 2385-, 2009

2 Grillone, M. D, 10 : 2171-, 1991

3 Steel, P. J, 38 : 243-, 2005

4 Hunter, C. A, 23 : 101-, 1994

5 Borrows, A. D, 24 : 329-, 1995

6 Evans, O. R, 35 : 511-, 2002

7 Lin, W. B, 120 : 13273-, 1998

8 Lin, W. B, 2263-, 2000

9 Aakeröy, C. B, 38 : 1815-, 1999

10 Sekiya, R, 8 : 4803-, 2000

11 Zhang, J, 1806-, 2001

12 Chapman, M. E, 1 : 159-, 2001

13 Lin, H. S, 46 : 1283-, 2007

14 Dobrzyñska, D, 5 : 1945-, 2005

15 Bu, X. H, 44 : 9837-, 2005

16 Bu, X. H, 7 : 411-, 2005

17 Abu-Youssef, M. A. M, 3177-, 2006

18 Abu-Youssef, M. A. M, 25 : 1187-, 2006

19 Chen Z. F, 5 : 35-, 2002

20 Chen, X. M, 8 : 4811-, 2002

21 Liu, G. F, 1442-, 2002

22 Ye, B. H, 249 : 545-, 2005

23 Hao, H. J, 64 : 965-, 2011

24 Hao, H. J, 41 : 26-, 2011

25 Irvine, R. W, 36 : 1419-, 1983

26 Blessing, R. H, A51 : 33-, 1995

27 Janiak, C, 2781-, 2003

28 Boudalis, A. K, 26 : 276-, 2001

29 Lazarou, K. N, 28 : 1085-, 2009

30 Gómez, V, 39 : 11664-, 2010

31 Ye, B. H, 299 : 1-, 2000

32 Liu, C. S, 636 : 1115-, 2009

33 Sheldrick, G. M, "SHELXS-97, Program for Crystal Structure Solution" University of Göttingen 1997

34 Sheldrick, G. M, "SHELXL-97, Program for Crystal Structure Refinement" University of Göttingen 1997

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2020-01-01	평가	등재학술지 유지 (해외등재 학술지 평가)
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2004-01-01	평가	등재학술지 유지 (등재유지)
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