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      SCOPUS KCI등재 SCIE

      Recent advances in heighten sulfur resistance of SCR catalysts: A review

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      https://www.riss.kr/link?id=A107280427

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      다국어 초록 (Multilingual Abstract)

      NOx removal by selective catalytic reduction (SCR) technology is a research hotspot in the field of environmental catalysis, and this method is dominated by catalysts. However, denitrification catalyst is easy to be polluted by the presence of SO₂, ...

      NOx removal by selective catalytic reduction (SCR) technology is a research hotspot in the field of environmental catalysis, and this method is dominated by catalysts. However, denitrification catalyst is easy to be polluted by the presence of SO₂, which seriously restricts its practical industrial application. This review focuses on the latest domestic and foreign research results and advancement in improving sulfur resistance of deNOx catalysts, reveals the sulfur poisoning mechanism and regeneration process, as well as introduces the positive role of quantum chemistry in the field of sulfur resistance. In view of the questions set forth in this review, the future development direction of deNOx catalysts is prospected, which provides valuable scientific guidance for the design and development of efficient and practical sulfur resistant deNOx catalysts.

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      목차 (Table of Contents)

      • ABSTRACT
      • 1. Introduction
      • 2. Strategies to Enhance The Sulfur Resistance of Catalysts
      • 3. Regeneration of Sulfur Poisoning Catalyst
      • 4. Application of Quantum Chemistry in the Field of Sulfur Resistance Research
      • ABSTRACT
      • 1. Introduction
      • 2. Strategies to Enhance The Sulfur Resistance of Catalysts
      • 3. Regeneration of Sulfur Poisoning Catalyst
      • 4. Application of Quantum Chemistry in the Field of Sulfur Resistance Research
      • 5. Conclusions and Outlook
      • References
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      참고문헌 (Reference)

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      2 Jia XX, "Understanding the high performance of an iron-antimony binary metal oxide catalyst in selective catalytic reduction of nitric oxide with ammonia and its tolerance of water/sulfur dioxide" 581 : 427-441, 2021

      3 Yang GP, "Understanding SO2 poisoning over different copper species of Cu-SAPO-34 catalyst: A periodic DFT study" 122 : 21468-21477, 2018

      4 Zhou X, "Two-dimensional MnFeCo layered double oxide as catalyst for enhanced selective catalytic reduction of NOx with NH3 at low temperature (25-150°C)" 592 : 117432-, 2020

      5 Zhang ZP, "Two steps synthesis of CeTiOx oxides nanotube catalyst: Enhanced activity,resistance of SO2and H2O for low temperature NH3-SCR of NOx" 282 : 119542-, 2021

      6 Yinming Fan ; Wei Ling ; Bichun Huang ; Lifu Dong ; Chenglong Yu ; Hongxia Xi, "The synergistic effects of cerium presence in the framework and the surface resistance to SO2 and H2O in NH3-SCR" 한국공업화학회 56 : 108-119, 2017

      7 Xiong SC, "The role of the Cu dopant on a Mn3O4 spinel SCR catalyst: Improvement of low-temperature activity and sulfur resistance" 387 : 124090-, 2020

      8 Kwon DW, "The role of ceria on the activity and SO2 resistance of catalysts for the selective catalytic reduction of NOx by NH3" 166-167 : 37-44, 2015

      9 Wang XB, "The insight into the role of CeO2 in improving low-temperature catalytic performance and SO2 tolerance of MnCoCeOx microflowers for the NH3-SCR of NOx" 510 : 145517-, 2020

      10 Fan ZY, "The insight into the role of Al2O3 in promoting the SO2 tolerance of MnOx for low-temperature selective catalytic reduction of NOx with NH3" 398 : 125572-, 2020

      1 Chen JY, "Unusual positive effect of SO2on Mn-Ce mixed-oxide catalyst for the SCR reaction of NOx with NH3" 407 : 127071-, 2021

      2 Jia XX, "Understanding the high performance of an iron-antimony binary metal oxide catalyst in selective catalytic reduction of nitric oxide with ammonia and its tolerance of water/sulfur dioxide" 581 : 427-441, 2021

      3 Yang GP, "Understanding SO2 poisoning over different copper species of Cu-SAPO-34 catalyst: A periodic DFT study" 122 : 21468-21477, 2018

      4 Zhou X, "Two-dimensional MnFeCo layered double oxide as catalyst for enhanced selective catalytic reduction of NOx with NH3 at low temperature (25-150°C)" 592 : 117432-, 2020

      5 Zhang ZP, "Two steps synthesis of CeTiOx oxides nanotube catalyst: Enhanced activity,resistance of SO2and H2O for low temperature NH3-SCR of NOx" 282 : 119542-, 2021

      6 Yinming Fan ; Wei Ling ; Bichun Huang ; Lifu Dong ; Chenglong Yu ; Hongxia Xi, "The synergistic effects of cerium presence in the framework and the surface resistance to SO2 and H2O in NH3-SCR" 한국공업화학회 56 : 108-119, 2017

      7 Xiong SC, "The role of the Cu dopant on a Mn3O4 spinel SCR catalyst: Improvement of low-temperature activity and sulfur resistance" 387 : 124090-, 2020

      8 Kwon DW, "The role of ceria on the activity and SO2 resistance of catalysts for the selective catalytic reduction of NOx by NH3" 166-167 : 37-44, 2015

      9 Wang XB, "The insight into the role of CeO2 in improving low-temperature catalytic performance and SO2 tolerance of MnCoCeOx microflowers for the NH3-SCR of NOx" 510 : 145517-, 2020

      10 Fan ZY, "The insight into the role of Al2O3 in promoting the SO2 tolerance of MnOx for low-temperature selective catalytic reduction of NOx with NH3" 398 : 125572-, 2020

      11 Sun P, "The enhanced SCR performance and SO2 resistance of Mn/TiO2 catalyst by the modification with Nb: A mechanistic study" 447 : 479-488, 2018

      12 Zhang WJ, "Temperature sensitivity of the selective catalytic reduction (SCR) performance of Ce-TiO2in the presence of SO2" 243 : 125419-, 2020

      13 Sheng ZY, "Synthesis of novel MnOx@TiO2core-shell nanorod catalyst for low-temperature NH3-selective catalytic reduction of NOx with enhanced SO2 tolerance" 39 : 821-830, 2018

      14 Yan QH, "Synthesis and catalytic performance of Cu1Mn0.5Ti0.5Ox mixed oxide as low-temperature NH3-SCR catalyst with enhanced SO2resistance" 238 : 236-247, 2018

      15 Wang H, "Superior Performance of Fe1−xWxOδ for the selective catalytic reduction of NOx with NH3: Interaction between Fe and W" 50 : 13511-, 2016

      16 Doronkin DE, "Sulfur poisoning and regeneration of the Ag/γ-Al2O3 catalyst for H2-assisted SCR of NOx by ammonia" 117-118 : 49-58, 2012

      17 Wei L, "Study the low-temperature SCR property of M-doped (M=Ni, Cr, Co, Se, Sn) MnO2(100) through density functional theory (DFT): Improvement of sulfur poisoning resistance" 459 : 31-37, 2018

      18 Gao FY, "Spinel-structured Mn–Ni nanosheets for NH3-SCR of NO with good H2O and SO2 resistance at low temperature" 22 (22): 7486-7501, 2020

      19 Shu Y, "Selective catalytic reaction of NOx with NH3 over Ce-Fe/TiO2-loaded wire-mesh honeycomb: Resistance to SO2 poisoning" 150-151 : 630-635, 2014

      20 Han LP, "SO2-tolerant selective catalytic reduction of NOx over Meso-TiO2@Fe2O3@Al2O3metal-based monolith catalysts" 53 : 6462-6473, 2019

      21 Kang L, "SO2-Tolerant NOx reduction by marvelously suppressing SO2 adsorption over FeδCe1−δVO4catalysts" 54 : 14066-, 2020

      22 Zhou JL, "SO2 and H2O poisoning resistance of manganese oxide-based catalysts for low-temperature selective catalytic reduction of NOx" 37 : 782-791, 2018

      23 Ning RL, "Research progress of low-temperature SCR denitration catalysts" 19 : 223-234, 2019

      24 Liu MH, "Research progress of low temperature selective catalytic reduction(SCR)catalysts for denitrification" 21 : 170-175, 2018

      25 Hu YF, "Research on characteristics of SO2-poison and regeneration of Mn-Ce/TiO2catalyst for low temperature selective catalytic reduction" 21 : 27-33, 2013

      26 Pan H, "Regeneration and sulfur poisoning behavior of In/H-BEA catalyst for NOx reduction by CH4" 401 : 120-126, 2017

      27 Wang LY, "Reaction of NO+CO over Ce-modified Cu-FeOx catalysts at low temperature" 33 : 11688-11704, 2019

      28 Gao FY, "Promotional mechanisms of activity and SO2 tolerance of Co- or Ni-doped MnOx-CeO2 catalysts for SCR of NOx with NH3 at low temperature" 317 : 20-31, 2017

      29 Zha KW, "Promotional effects of Fe on manganese oxide octahedral molecular sieves for alkali-resistant catalytic reduction of NOx: XAFS and in situ DRIFTs study" 381 : 122764-, 2020

      30 Guo K, "Pore size expansion accelerates ammonium bisulfate decomposition for improved sulfur resistance in low-temperature NH3‑SCR" 11 : 4900-4907, 2019

      31 Ma ZX, "Oxide catalysts with ultrastrong resistance to SO2 deactivation for removing nitric oxide at low temperature" 31 : 1903719-, 2019

      32 Peng C, "One-pot synthesis of layered mesoporous ZSM-5 plus Cu ion-exchange: Enhanced NH3-SCR performance on Cu-ZSM-5 with hierarchical pore structures" 385 : 121593-, 2020

      33 Wan J, "One-pot synthesis of Fe/Cu-SSZ-13 catalyst and its highly efficient performance for the selective catalytic reduction of nitrogen oxide with ammonia" 100 : 306-316, 2021

      34 Ma YY, "One-pot synthesis of Cu-Ce co-doped SAPO-5/34 hybrid crystal structure catalysts for NH3-SCR reaction with SO2 resistance" 2020

      35 Wang YZ, "Novel methods for assessing the SO2 poisoning effect and thermal regeneration possibility of MOx−WO3/TiO2 (M = Fe, Mn, Cu, and V) catalysts for NH3‑SCR" 54 : 12612-12620, 2020

      36 Zeng YQ, "Novel Fe-doped CePO4 catalyst for selective catalytic reduction of NO with NH3: The role of Fe3+ ions" 383 : 121212-, 2020

      37 Gao FY, "Novel Co- or Ni-Mn binary oxide catalysts with hydroxyl groups for NH3-SCR of NOx at low temperature" 443 : 103-113, 2018

      38 Li CX, "New insights into the role of WO3 in improved activity and ammonium bisulfate resistance for NO reduction with NH3 over V−W/Ce/Ti catalyst" 57 : 8424-, 2018

      39 Mu JC, "New insight into the effects of NH3 on SO2 poisoning for in situ removal of metal sulfates in low-temperature NH3‑SCR over an Fe−V catalyst" 124 : 21396-21406, 2020

      40 Xu LW, "New insight into SO2 poisoning and regeneration of CeO2-WO3/TiO2and V2O5-WO3/TiO2 catalysts for low-temperature NH3-SCR" 52 : 7064-7071, 2018

      41 Si ZC, "NH3-SCR activity, hydrothermal stability, sulfur resistance and regeneration of Ce0.75Zr0.25O2-PO43- catalyst" 17 : 146-149, 2012

      42 Ma DR, "MnOx–CeO2@TiO2 core–shell composites for low temperature SCR of NOx" 43 : 15161-15168, 2019

      43 Gao FY, "Mn2NiO4spinel catalyst for high-efficiency selective catalytic reduction of nitrogen oxides with good resistance to H2O and SO2 at low temperature" 89 : 145-155, 2020

      44 Lee T, "Metal sulfate poisoning effects over MnFe/TiO2for selective catalytic reduction of NO by NH3 at low temperature" 57 : 4848-4858, 2018

      45 Li G, "Low-temperature NH3-SCR of NOx over MnCeOx/TiO2 catalyst: Enhanced activity and SO2 tolerance by modifying TiO2 with Al2O3"

      46 Han J, "Investigation of the facet-dependent catalytic performance of Fe2O3/CeO2 for the selective catalytic reduction of NO with NH3" 120 : 1523-1533, 2016

      47 Zhang XL, "Improvement of the activity and SO2 tolerance of Sb-modified Mn/PG catalysts for NH3 -SCR at a low temperature" 101 : 1-15, 2020

      48 Wang JY, "Improvement of SO2 resistance of low-temperature Mn-Based denitration catalysts by Fe doping" 4 : 3755-3760, 2019

      49 Kang TH, "Improved catalytic performance and resistance to SO2 over V2O5-WO3/TiO2 catalyst physically mixed with Fe2O3 for low-temperature NH3-SCR" 2020

      50 Wang B, "Improved activity and SO2resistance by Sm-modulated redox of MnCeSmTiOx mesoporous amorphous oxides for low-temperature NH3‑SCR of NO" 10 : 9034-9045, 2020

      51 Kang L, "Improved NOx reduction in the presence of SO2 by using Fe2O3-promoted halloysite-supported CeO2-WO3 catalysts" 53 : 938-945, 2019

      52 Zhao L, "Improved NO reduction in the presence of SO2 by using Zr-promoted calcined NiAl hydrotalcite-like compounds and the regeneration of deactivated catalysts" 263 : 116668-, 2020

      53 Hammershøi PS, "Importance of the Cu oxidation state for the SO2-poisoning of a Cu-SAPO-34 catalyst in the NH3-SCR reaction" 236 : 377-383, 2018

      54 Wang XQ, "Highly active NbOPO4 supported Cu-Ce catalyst for NH3-SCR reaction with superior sulfur resistance" 382 : 122941-, 2020

      55 Li YL, "Hierarchical three-dimensionally ordered macro porous Fe-V binary metal oxide catalyst for low temperature selective catalytic reduction of NOx from marine diesel engine exhaust" 268 : 118455-, 2020

      56 Chang HZ, "Ge, Mn-doped CeO2−WO3 catalysts for NH3−SCR of NOx: Effects of SO2 and H2 regeneration" 201 : 139-144, 2013

      57 Wu X, "Fabrication of highly dispersed Cu-based Oxides as desirable NH3‑SCR catalysts via employing CNTs To decorate the CuAl-layered double hydroxides" 11 : 32917-32927, 2019

      58 Qian WY, "Experimental study on selective catalytic reduction of NO with propene over iron based catalysts supported on aluminum pillared clays" 45 : 1499-1507, 2017

      59 Dong SL, "Experimental study on selective catalytic reduction of NO by C3H6 over Fe/Ti-PILC catalysts" 46 : 1231-1239, 2018

      60 Ma SB, "Excellent low-temperature NH3-SCR NO removal performance and enhanced H2O resistance by Ce addition over the Cu0.02Fe0.2CeyTi1-yOx (y = 0.1, 0.2, 0.3) catalysts" 243 : 125309-, 2020

      61 Yao XJ, "Enhancing the denitration performance and anti-K poisoning ability of CeO2-TiO2/P25 catalyst by H2SO4 pretreatment: Structure-activity relationship and mechanism study" 269 : 118808-, 2020

      62 Liu J, "Enhancement of the SO2 resistance of Mn/TiO2 SCR catalyst by Eu modification : A mechanism study" 223 : 385-393, 2018

      63 Zhang HW, "Enhanced SO2 tolerance of FeCeOx/CNTs catalyst for NO and Hg0 removal by coating shell SiO2" 201 : 106342-, 2020

      64 Liu L, "Efficient Sm modified Mn/TiO2 catalysts for selective catalytic reduction of NO with NH3 at low temperature" 592 : 117413-, 2020

      65 Chen JJ, "Effects of anaerobic SO2 treatment on nano-CeO2 of different morphologies for selective catalytic reduction of NOx with NH3" 382 : 122910-, 2020

      66 Liang QM, "Effects of SO2 and H2O on low-temperature NO conversion over F-V2O5-WO3/TiO2catalysts" 90 : 253-261, 2020

      67 Jiang HX, "Effect of promoters on the catalytic performance and SO2/H2O resistance of α‑MnO2 catalysts for low temperature NH3‑SCR" 58 : 1760-, 2019

      68 Fang NJ, "Effect of calcination temperature on low-temperature NH3-SCR activity and the resistance of SO2 with or without H2O over Fe-Mn-Zr catalyst" 93 : 277-288, 2018

      69 Cai SX, "Design of multi-shell Fe2O3@MnOx@CNTs for the selective catalytic reduction of NO with NH3 : improvement of catalytic activity and SO2tolerance" 8 : 3588-3598, 2016

      70 Liu Z, "Design of assembled composite of Mn3O4@Graphitic carbon porous nano-dandelions:A catalyst for low-temperature selective catalytic reduction of NOx with remarkable SO2 resistance" 269 : 118731-, 2020

      71 Yu R, "Cu-SSZ-13 zeolite-metal oxide hybrid catalysts with enhanced SO2-tolerance in the NH3-SCR of NOx" 269 : 118825-, 2020

      72 Gan LN, "Core-shell-like structured α-MnO2@CeO2 catalyst for selective catalytic reduction of NO:Promoted activity and SO2 tolerance" 391 : 123473-, 2020

      73 Wang XW, "Analysis of NOx emission and control in China and research progress in denitration catalysts" 27 : 1-23, 2019

      74 Huang ZW, "Alkali- and sulfur-resistant tungsten-based catalysts for NOx emissions control" 49 : 14460-14465, 2015

      75 Zeng YY, "Air pollution reduction in China: Recent success but great challenge for the future" 663 : 329-337, 2019

      76 Liu CX, "Activity enhancement of sulphated Fe2O3supported on TiO2–ZrO2 for the selective catalytic reduction of NO by NH3" 528 : 146695-, 2020

      77 Xie AJ, "A γ-Fe2O3-modified nanoflower-MnO2/attapulgite catalyst for low temperature SCR of NOx with NH3" 43 : 2490-2500, 2019

      78 Zhu N, "A superior Fe-V-Ti catalyst with high activity and SO2 resistance for the selective catalytic reduction of NOx with NH3" 382 : 120970-, 2020

      79 Chen SN, "A novel highly active and sulfur resistant catalyst from Mn-Fe-Al layered double hydroxide for low temperature NH3-SCR" 327 : 81-89, 2019

      80 Yu CL, "A MnOx@Eu-CeOx nanorod catalyst with multiple protective effects:Strong SO2-tolerance for low temperature DeNOx processes" 399 : 123011-, 2020

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      학술지 이력

      학술지 이력
      연월일 이력구분 이력상세 등재구분
      2023 평가예정 해외DB학술지평가 신청대상 (해외등재 학술지 평가)
      2020-01-01 평가 등재학술지 유지 (해외등재 학술지 평가) KCI등재
      2010-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2008-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2005-01-01 평가 등재학술지 선정 (등재후보2차) KCI등재
      2004-01-01 평가 등재후보 1차 PASS (등재후보1차) KCI등재후보
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      학술지 인용정보
      기준연도 WOS-KCI 통합IF(2년) KCIF(2년) KCIF(3년)
      2016 0.23 0.23 0.21
      KCIF(4년) KCIF(5년) 중심성지수(3년) 즉시성지수
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