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    MgCl2-CaCl2-NaCl 혼합용융염에서 Mg2+ 이온의 전기화학적 거동 = Electrochemical Behavior of Mg2+ Ions in MgCl2-CaCl2-NaCl Molten Salt

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    https://www.riss.kr/link?id=A102026146

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    The electrochemical behavior of magnesium ions was examined by cyclic voltammetry in a molten MgCl2- CaCl2-NaCl salt. The reduction potential of magnesium ions was measured and those values were estimated with the variation of the concentration of MgCl2 and the temperature of molten salts. The diffusion coefficient of the Mg2+ ions has been determined at 660, 680, 700, 720 and 740 oC. The values were 8.79×10-6, 9.56×10-6, 1.17×10-5, 1.4×10-5 and 1.77×10-5 cm2 s-1, The activation energy for the diffusion processes of Mg2+ ions was found to be 70.28 kJ mol-1 by using the Arrhenius equation.
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    The electrochemical behavior of magnesium ions was examined by cyclic voltammetry in a molten MgCl2- CaCl2-NaCl salt. The reduction potential of magnesium ions was measured and those values were estimated with the variation of the concentration of MgC...

    The electrochemical behavior of magnesium ions was examined by cyclic voltammetry in a molten MgCl2- CaCl2-NaCl salt. The reduction potential of magnesium ions was measured and those values were estimated with the variation of the concentration of MgCl2 and the temperature of molten salts. The diffusion coefficient of the Mg2+ ions has been determined at 660, 680, 700, 720 and 740 oC. The values were 8.79×10-6, 9.56×10-6, 1.17×10-5, 1.4×10-5 and 1.77×10-5 cm2 s-1, The activation energy for the diffusion processes of Mg2+ ions was found to be 70.28 kJ mol-1 by using the Arrhenius equation.

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    참고문헌 (Reference)

    1 Park, H. K., "Review on the Current Status of Magnesium Smelting" 11 (11): 13-18, 2008

    2 정상문, "Preparation of Metallic Niobium from Niobium Pentoxide by and Electrolytic Reduction in a LiCl-Li2O Molten Salt" ELSEVIER SCIENCE SA 452 (452): 27-31, 200803

    3 Thayer, R. L., "Improving the Electrolytic Process for Magnesium Production" 53 (53): 15-17, 2001

    4 Martinez, A. M., "Electrodeposition of Magnesium from the Eutectic LiCl-KCl melt" 34 (34): 1271-1278, 2004

    5 Martinez, A. M., "Electrodeposition of Magnesium from CaCl2- NaCl-KCl-MgCl2 Melts" 151 (151): C508-C513, 2004

    6 정상문, "Electrochemical reduction behavior of U3O8 powder in a LiCl molten salt" PERGAMON-ELSEVIER SCIENCE LTD 55 (55): 1749-1755, 201002

    7 Castrillegjo, Y., "Electrochemical Behavior of Magnesium Ions in the Equimolar CaCl2-NaCl Mixture at 550 °C" 42 (42): 1869-1876, 1997

    8 Rajagopalan, N., "Developing an Energy-Efficient Electrolytic Cell for Magnesium" 52 (52): 18-19, 2000

    9 Store, T., "Determination of Diffusion Coefficients of Depositing Ions in Molten Chlorides by Transient Electrochemical Techniques" 30 (30): 1351-1360, 2000

    10 정상문, "Characteristics of an Electrochemical Reduction of Ta2O5 to Metallic Tantalum in a LiCl-Li2O Molten Salt" ELSEVIER SCIENCE SA 440 (440): 210-215, 200708

    1 Park, H. K., "Review on the Current Status of Magnesium Smelting" 11 (11): 13-18, 2008

    2 정상문, "Preparation of Metallic Niobium from Niobium Pentoxide by and Electrolytic Reduction in a LiCl-Li2O Molten Salt" ELSEVIER SCIENCE SA 452 (452): 27-31, 200803

    3 Thayer, R. L., "Improving the Electrolytic Process for Magnesium Production" 53 (53): 15-17, 2001

    4 Martinez, A. M., "Electrodeposition of Magnesium from the Eutectic LiCl-KCl melt" 34 (34): 1271-1278, 2004

    5 Martinez, A. M., "Electrodeposition of Magnesium from CaCl2- NaCl-KCl-MgCl2 Melts" 151 (151): C508-C513, 2004

    6 정상문, "Electrochemical reduction behavior of U3O8 powder in a LiCl molten salt" PERGAMON-ELSEVIER SCIENCE LTD 55 (55): 1749-1755, 201002

    7 Castrillegjo, Y., "Electrochemical Behavior of Magnesium Ions in the Equimolar CaCl2-NaCl Mixture at 550 °C" 42 (42): 1869-1876, 1997

    8 Rajagopalan, N., "Developing an Energy-Efficient Electrolytic Cell for Magnesium" 52 (52): 18-19, 2000

    9 Store, T., "Determination of Diffusion Coefficients of Depositing Ions in Molten Chlorides by Transient Electrochemical Techniques" 30 (30): 1351-1360, 2000

    10 정상문, "Characteristics of an Electrochemical Reduction of Ta2O5 to Metallic Tantalum in a LiCl-Li2O Molten Salt" ELSEVIER SCIENCE SA 440 (440): 210-215, 200708

    11 Gao, F., "Assessing Environmental Impact of Magnesium ProductionUsing Pidgeon Process in China" 18 (18): 749-754, 2008

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