Kinetics of halogen exchange reaction of 1-phenethyl chloride using radioisotopic tracer halide ions in acetone have been studied.
The rate constant was determined at two temperature and the activation parameters, ?? and ?? were calculated.
The re...
Kinetics of halogen exchange reaction of 1-phenethyl chloride using radioisotopic tracer halide ions in acetone have been studied.
The rate constant was determined at two temperature and the activation parameters, ?? and ?? were calculated.
The reactions were believed to be ?? processes and the orders of relative nucleop- hilicity of halide ions were ??. The reaction rate is slower than that of benzyl chloride.
These were interpreted in terms of so1vation effect of halide ions and HSAB principle.