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      • KCI등재

        Enhanced Mechanical Properties and Thermal Conductivity for GNPs/Al2024 Composites with In Situ SiC Nanorods

        Lili Chen,Yushi Qi,Yanhan Fei,Zhiming Du 대한금속·재료학회 2021 METALS AND MATERIALS International Vol.27 No.10

        In order to significantly enhance the performance of graphene in metal matrix composites, in situ SiC nanorods were successfullyfabricated to enhance graphene nanoplatelets (GNPs)-reinforced Al2024 composite, which was prepared by powdersemi-solid processing and friction stir processing. The SiC–GNPs dispersed in the Al matrix uniformly, SiC nanorodswere randomly grown on GNPs sheets in any direction, bridging GNPs as well as GNPs and the Al matrix. Meanwhile, theinterfacial bonding was effective. The hybrid reinforcement of SiC and GNPs endowed composites with superior mechanicalproperties and thermal conductivity. The in situ SiC nanorods transfer phonons and reduce phonon scattering effect inthe through-plane direction of GNPs, which conducive to heat transmission. The composite exhibits improved mechanicalproperties, maximum tensile strength and hardness of 589 MPa and 193 HV are obtained, with 1.0 wt% GNPs addition,respectively. The thermal conductivity of composite increases with the content of SiC–GNPs. When the content of SiC–GNPsreaches 1.5 wt%, the composite has significantly enhanced thermal conductivity (224 W m−1 K−1), which is 115% timeshigher than that of Al2024. Moreover, the effects of SiC–GNPs on the properties were discussed.

      • SCIESCOPUS

        Effect of pulse electrodeposition parameters on electrocatalytic the activity of methanol oxidation and morphology of Pt/C catalyst for direct methanol fuel cells

        Ye, Feng,Xu, Chao,Liu, Guicheng,Yuan, Mengdi,Wang, Zhiming,Du, Xiaoze,Lee, Joong Kee Pergamon 2018 Energy Conversion and Management Vol. No.

        <P><B>Abstract</B></P> <P>The electrodeposition technique for preparing direct methanol fuel cell electrodes has been developed to increase the Pt utilization and lower the Pt loading. The performance of the Pt/C electrode for methanol oxidation reaction (MOR) was optimized by adjusting the electrodeposition parameters such as applied electrical signal types, ratios of t<SUB>on</SUB>/t<SUB>off</SUB>, deposition temperatures, and electrolyte concentrations, systematically. Furthermore, the effects of two kinds of additives, i.e. polyethylene glycol (PEG) and sodium dodecyl sulfonate (SDS), on the catalytic performance and morphology of Pt catalyst were investigated for MOR by SEM, XRD, cyclic voltammetry and linear sweep voltammetry. The results show that the optimal Pt catalyst has been prepared by the square wave current method with t<SUB>on</SUB>/t<SUB>off</SUB> of 1 s/5 s at 30 °C in a 1.0 mmol L<SUP>−1</SUP> H<SUB>2</SUB>PtCl<SUB>6</SUB> solution with a 10<SUP>−4</SUP> mmol L<SUP>−1</SUP> PEG additive. Moreover, the effect of the additive type and amount on the formation mechanism of the Pt crystallite morphology has also been discussed. From the results, introducing additives into the deposition solution in the pulse electrodeposition process is useful for designing and fabricating electrocatalytic electrodes for direct methanol fuel cells.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Signals include square wave current and potential, cyclic voltammetry and constant current pulse. </LI> <LI> Effects of four applied electrical signal types on Pt catalytic performance are compared. </LI> <LI> Parameters for Pt electrodeposition in constant current pulse mode are optimized systematically. </LI> <LI> Effect mechanism of additive on growth of Pt catalyst is studied in pulse electrodeposition. </LI> <LI> Optimal condition is t<SUB>on</SUB>/t<SUB>off</SUB> of 1 s/5 s, 30 °C, 1 mmol L<SUP>−1</SUP> H<SUB>2</SUB>PtCl<SUB>6</SUB> solution with 10<SUP>−4</SUP> mmol L<SUP>−1</SUP> PEG. </LI> </UL> </P>

      • KCI등재

        Identification and Characterization of EDT1 Conferring Drought Tolerance in Rice

        Tao Wu,Mingxing Zhang,Hongjia Zhang,Kai Huang,Mojun Chen,Chen Chen,Xue Yang,Zhao Li,Haoyuan Chen,Zhiming Ma,Xunming Zhang,Wenzhu Jiang,Xinglin Du 한국식물학회 2019 Journal of Plant Biology Vol.62 No.1

        Basic Leucine Zipper (bZIP) transcription factors(TFs) play important roles in many processes, especially inabiotic stress response in plants. In this study, we characterizeda new gene EHANCED DROUGHT TOLERANCE 1 (EDT1),member of group E of bZIP transcription factor family inrice. The EDT1 protein contains one bZIP domain, oneputative nuclear localization signal (NLS) and six conservedphosphorylation sites. The expression of EDT1 is suppressedby several abiotic stresses, such as cold, droutht, and salt. Corresponding with expression patterns, several stress-associatedcis-acting elements were found in the EDT1 promoter. Theresults of subcellular localization and transactivation abilityanalyses indicated that EDT1 was localized in the nucleusand functioned as a nuclear protein, with its transactivationactivity primarily located in N-terminal. Transgenic riceoverexpressing EDT1 showed drought tolerance that hasbeen significantly improved. Real-time PCR analysis revealedthat some stress-related genes, such as OsbZIP12, SNAC1,OsLEA3, OsbZIP16, OsbZIP10 and OsABI2 were up-regulatedin EDT1 overexpression lines. These results indicate thatEDT1 plays a positive role in drought tolerance and providesvaluable targets for breeding drought-tolerant rice cultivars.

      • KCI등재

        Dislocation Density-Based Constitutive Model and Processing Map for T2 Copper During Isothermal and Time-Variant Deformation

        Gang Chen,Yu Jin,Jing Wang,Cheng Zhang,Qiang Chen,Hongming Zhang,Xingjian Zhao,Zhiyong Li,Changhai Xie,Zhiming Du 대한금속·재료학회 2022 METALS AND MATERIALS International Vol.28 No.9

        Isothermal compression tests were carried out to study the hot deformation behavior of T2 copper under various conditions. The deformation parameters, such as temperature and strain rate, have strong influence on flow stress and microstructureevolution of the alloy. A unified dislocation density-based model considering dynamic recovery and recrystallization wasestablished. And material parameters of the developed model were optimized by genetic algorithm. Comparisons betweenthe experimental and model data demonstrates that the developed model can precisely describe the flow behavior at quitewide range of deformation conditions. Meanwhile, the designed iterative procedure allows the model to be applied in timevariantdeformation conditions. Processing map and microstructure examination were constructed to optimize the processingwindow of the studied alloy. According to the processing maps, flow instability mainly appeared at low temperatures of500–650 °C and strain rates higher than 0.1 s−1. The optimum deformation parameters of T2 copper was concluded as thetemperature range of 700–800 °C and the strain rate of 0.1–1 s−1.

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