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        Distinct growth phenomenon observed on L-Arg․ CF3COOH crystals

        Xiaojing Liu,Zeyan Wang,Guanghui Zhang,Guangwei Yu,Aidong Duan,Xinqiang Wang,Dong Xu 한국물리학회 2009 Current Applied Physics Vol.9 No.1

        Atomic force microscopy has been employed to study the growth behaviour on the {101} facets of L-Arg ․ CF3COOH crystals grown at 25℃ at a supersaturation of σ = 0.2. Nucleation on the wider step terraces and a large nucleus composed of two separate 2D nuclei were observed for the first time. For the region where blocking occurs convex pattern are found in the macrosteps, which correspond to the sites of the impurities that act as pinning points hindering step propagation. Finally, liquid inclusions will be generated because of disparate formation mechanisms. Atomic force microscopy has been employed to study the growth behaviour on the {101} facets of L-Arg ․ CF3COOH crystals grown at 25℃ at a supersaturation of σ = 0.2. Nucleation on the wider step terraces and a large nucleus composed of two separate 2D nuclei were observed for the first time. For the region where blocking occurs convex pattern are found in the macrosteps, which correspond to the sites of the impurities that act as pinning points hindering step propagation. Finally, liquid inclusions will be generated because of disparate formation mechanisms.

      • KCI등재

        9,9-Dimethyl-9,10-dihydroacridine functionalized phosphoindole oxides with AIE property for OLED application

        Li Jianqing,Zhuang Zeyan,Zhu Xiangyu,Zhao Zujin,BEN ZHONG TANG 한국정보디스플레이학회 2020 Journal of information display Vol.21 No.3

        Aggregation-induced emission (AIE) has attracted widespread attention of late in academic and industrial circles owing to its diverse applications. Developing AIE-active materials for application in organic light-emitting diodes (OLEDs) has become an effective method of improving device efficiency and stability. In this work, two novel luminogens (PIO-α-DMAc and PIO-β-DMAc) consisting of 9,9-dimethyl-9,10-dihydroacridine and phosphoindole oxide were synthesized and systemically characterized. Their crystal structures, thermal stabilities, electronic structures, and electrochemical behaviors were studied. They showed apparent AIE properties and emitted strongly in the aggregated state. Non-doped and doped green OLEDs were fabricated using these luminogens as light-emitting layers, and exhibited high brightness, good electroluminescence efficiencies, and low turn-on voltages

      • KCI등재

        In Situ Synthesis of Ti3+ Self-Doped TiO2/N-Doped Carbon Nanocomposites and its Visible Light Photocatalytic Performance

        Chaoyi Wu,Zhenggang Gao,Shanmin Gao,Qingyao Wang,Zeyan Wang,Baibiao Huang,Ying Dai 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2016 NANO Vol.11 No.8

        Ti3+ self-doped TiO2 (TiO2-x)/N-doped carbon nanostructure composites were prepared via a facile one-step hydrothermal method to optimize the use of visible light and reduce recombination of photogenerated electrons and holes. The composites were characterized by X-ray diffraction, transmission electron microscopy (TEM), high-resolution TEM, X-ray photoelectron spectroscopy, and Fourier-transform infrared spectroscopy. The amounts of carbon and nitrogen sources affect the morphology and photocatalytic performance. At low amounts of the sources, the Ndoped carbon nanostructure is an amorphous film and is well-combined with TiO2-x nanoparticles through surface carbon–oxygen groups. At high amounts of the sources, N-doped carbon quantum dots (NCQDs) were obtained, and carbon atoms could substitute for oxygen atoms in the TiO2 lattice to form Ti–C structures, which are responsible for the high photocatalytic activity under visible light illumination. Transient photocurrent response and electrochemical impedance spectroscopy results indicate that the amorphous hybrid film becomes a trap for electrons and that NCQDs can accelerate electron transfer. The improved visible light photocatalytic property for the TiO2-x/NCQDs composite can be attributed to the enhancement of light absorption and inhibition of the photogenerated electron–hole recombination of anchored NCQDs.

      • KCI등재

        White-Matter Hyperintensities and Lacunar Infarcts Are Associated with an Increased Risk of Alzheimer’s Disease in the Elderly in China

        Shuai Ye,Shuyang Dong,Jun Tan,Le Chen,Hai Yang,Yang Chen,Zeyan Peng,Yingchao Huo,Juan Liu,Mingshan Tang,Yafei Li,Huadong Zhou,Yong Tao 대한신경과학회 2019 Journal of Clinical Neurology Vol.15 No.1

        Background and Purpose This study investigated the contribution of white-matter hyperintensities (WMH) and lacunar infarcts (LI) to the risk of Alzheimer’s disease (AD) in an elderly cohort in China. Methods Older adults who were initially cognitively normal were examined with MRI at baseline, and followed for 5 years. WMH were classified as mild, moderate, or severe, and LI were classified into a few LI (1 to 3) or many LI (≥4). Cognitive function was assessed using the Mini Mental State Examination and the Activities of Daily Living scale. Results Among the 2,626 subjects, 357 developed AD by the end of the 5-year follow-up period. After adjusting for age and other potential confounders, having only WMH, having only LI, and having both WMH and LI were associated with an increased risk of developing AD compared with having neither WMH nor LI. Moderate and severe WMH were associated with an increased risk of developing AD compared with no WMH. Furthermore, patients with many LI had an increased risk of developing AD compared with no LI. Conclusions Having moderate or severe WMH and many LI were associated with an increased risk of developing AD, with this being particularly striking when both WMH and LI were present.

      • KCI등재

        CO2 capture performance of cement-modified carbide slag

        Xiaotong Ma,Yingjie Li,Changyun Chi,Wan Zhang,Zeyan Wang 한국화학공학회 2017 Korean Journal of Chemical Engineering Vol.34 No.2

        A novel and low-cost synthetic CO2 sorbent for calcium looping process, cement-modified carbide slag (CMCS), was synthesized from carbide slag, aluminate cement and by-product of biodiesel by combustion. The effects of synthesis conditions such as combustion temperature, combustion duration, hydration, by-product of biodiesel and cement addition and regeneration temperature on CO2 capture performance of CMCS were investigated. The comprehensively optimum preparation conditions of CMCS were obtained. The highest CO2 capture capacity is 0.62 g/g after 10 cycles, which is 2.18 times as high as that of carbide slag. The addition of aluminate cement improves the CO2 capture performance of CMCS, while excessive aluminate cement is adverse for CO2 capture due to the reduced CaO content in CMCS. The addition of by-product of biodiesel contributes to a uniform sol mixing of carbide slag and cement. The CMCS exhibits higher carbonation and calcination rates than CS. The porous and stable pore structure leads to the better CO2 capture performance and cyclic stability of CMCS.

      • KCI등재

        Simultaneous NO/SO2 removal by coconut shell char/CaO from calcium looping in a fluidized bed reactor

        Boyu Li,Yingjie Li,Wan Zhang,Yuqi Qian,Zeyan Wang 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.4

        A simultaneous NOx/SO2 removal system using bio-char and CaO combined with calcium looping process for CO2 capture was proposed. The simultaneous NO/SO2 removal performance of coconut shell char/CaO experienced CO2 capture cycles was investigated in a fluidized bed reactor. The effects of reaction temperature, mass ratio of CaO to coconut shell coke, CaO particle size and number of CO2 capture cycles from calcium looping process were discussed. The NO removal efficiency of char is improved under the catalysis of CaO. The reaction temperature plays an important role in the simultaneous NO/SO2 removal. Coconut shell char/CaO achieve the highest NO and SO2 removal efficiencies at 825 oC, which are 98% and 100%, respectively. The mass ratio of CaO to coconut shell char of 60 : 100 is a good choice for the simultaneous NO/SO2 removal. Smaller CaO particle size contributes to higher NO and SO2 removal efficiencies of coconut shell char/CaO. The NO and SO2 removal efficiencies of coconut shell char and cycled CaO from calcium looping declined slightly with the number of CO2 capture cycles. In addition, the Ca-based materials balance in process of simultaneous NOx/SO2 removal combined with calcium looping is given. The novel simultaneous NO/SO2 removal method using bio-char and cycled CaO from calcium looping process appears promising.

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