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RISS 인기검색어
- 검색키워드
- 저자 : Yingze Song (검색결과 6 건)
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Song, Yingze,Zhao, Wen,Zhu, Xingyu,Zhang, Li,Li, Qiucheng,Ding, Feng,Liu, Zhongfan,Sun, Jingyu American Chemical Society 2018 ACS APPLIED MATERIALS & INTERFACES Vol.10 No.18
<P>The lithium-sulfur (Li-S) battery has been deemed as one of the most promising energy-storage systems owing to its high energy density, low cost, and environmental benignancy. However, the capacity decay and kinetic sluggishness stemming from polysulfide shuttle effects have by far posed a great challenge to practical performance. We herein demonstrate the employment of low-cost, wet-chemistry-derived VO<SUB>2</SUB> nanobelts as the effective host additives for the graphene-based sulfur cathode. The VO<SUB>2</SUB> nanobelts displayed an ultrafast anchoring behavior of polysulfides, managing to completely decolor the polysulfide solution in 50 s. Such a fast and strong anchoring ability of VO<SUB>2</SUB> was further investigated and verified by experimental and theoretical investigations. Benefitting from the synergistic effect exerted by VO<SUB>2</SUB> in terms of chemical confinement and catalytic conversion of polysulfides, the Li-S batteries incorporating VO<SUB>2</SUB> and graphene manifested excellent cycling and rate performances. Notably, the batteries delivered an initial discharge capacity of 1405 mAh g<SUP>-1</SUP> when cycling at 0.2 C, showed an advanced rate performance of ∼830 mAh g<SUP>-1</SUP> at 2 C, and maintained a stable cycling performance at high current densities of 1, 2, and 5 C over 200 cycles, paving a practical route toward cost-effective and environmentally benign cathode design for high-energy Li-S batteries.</P> [FIG OMISSION]</BR>
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In-situ PECVD-enabled graphene-V<sub>2</sub>O<sub>3</sub> hybrid host for lithium–sulfur batteries
Song, Yingze,Zhao, Wen,Wei, Nan,Zhang, Li,Ding, Feng,Liu, Zhongfan,Sun, Jingyu Elsevier 2018 Nano energy Vol.53 No.-
<P><B>Abstract</B></P> <P>Lithium–sulfur (Li–S) batteries have been regarded as promising candidates for current energy-storage technologies due to their remarkable advantages in energy density and theoretical capacity. However, one of the daunting challenges remained for advanced Li–S systems thus far deals with the synchronous suppression of polysulfide (LiPS) shuttle and acceleration of redox kinetics. Herein, a cooperative interface bridging adsorptive V<SUB>2</SUB>O<SUB>3</SUB> and conductive graphene is constructed <I>in-situ</I> by virtue of direct plasma-enhanced chemical vapor deposition (PECVD), resulting in the design of a novel V<SUB>2</SUB>O<SUB>3</SUB>-graphene hybrid host to synergize the LiPS entrapment and conversion. The redox kinetics and electrochemical performances of thus-derived cathodes were accordingly enhanced owing to the smooth adsorption-diffusion-conversion of LiPSs even at a sulfur mass loading of 3.7 mg cm<SUP>–2</SUP>. Such interfacial engineering offers us a valuable opportunity to gain insight into the comprehensive regulation of LiPS anchoring ability, electrical conductivity and ion diffusive capability in hybrid hosts on suppressing the LiPS shuttle and propelling the redox kinetics. Our devised PECVD route might pave a new route toward the facial and economic design of hetero-phased multi-functional hosts for high-performance Li–S systems.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Graphene-V<SUB>2</SUB>O<SUB>3</SUB> hybrid host was designed <I>in-situ</I> based on PECVD route. </LI> <LI> Thus-derived cathode showed a low capacity decay of merely 0.046% per cycle at 2 C after 1000 cycles. </LI> <LI> Cathodes with a relatively high sulfur mass loading (3.7 mg cm<SUP>–2</SUP>) were fabricated. </LI> <LI> The smooth adsorption-diffusion-conversion of polysulfides was thoroughly probed <I>via</I> experimental studies and DFT simulations. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>[DISPLAY OMISSION]</P>
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Song, Yingze,Zhao, Wen,Kong, Long,Zhang, Li,Zhu, Xingyu,Shao, Yuanlong,Ding, Feng,Zhang, Qiang,Sun, Jingyu,Liu, Zhongfan The Royal Society of Chemistry 2018 ENERGY AND ENVIRONMENTAL SCIENCE Vol.11 No.9
<P>Lithium-sulfur (Li-S) batteries are deemed as one of the most promising next-generation energy storage systems. However, their practical application is hindered by existing drawbacks such as poor cycling life and low Coulombic efficiency due to the shuttle effect of lithium polysulfides (LiPSs). We herein present an <I>in situ</I> constructed VO2-VN binary host which combines the merits of ultrafast anchoring (VO2) with electronic conducting (VN) to accomplish smooth immobilization-diffusion-conversion of LiPSs. Such synchronous advantages have effectively alleviated the polysulfide shuttling, promoted the redox kinetics, and hence improved the electrochemical performance of Li-S batteries. As a result, the sulfur cathode based on the VO2-VN/graphene host exhibited an impressive rate capability with ∼1105 and 935 mA h g<SUP>−1</SUP> at 1C and 2C, respectively, and maintained long-term cyclability with a low capacity decay of 0.06% per cycle within 800 cycles at 2C. More remarkably, favorable cyclic stability can be attained with a high sulfur loading (13.2 mg cm<SUP>−2</SUP>). Even at an elevated temperature (50 °C), the cathodes still delivered superior rate capacity. Our work emphasizes the importance of immobilization-diffusion-conversion of LiPSs toward the rational design of high-load and long-life Li-S batteries.</P>
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Jinhong Yu,Wei Wu,Dan Dai,Yingze Song,Chaoyang Li,Nan Jiang 한국고분자학회 2014 Macromolecular Research Vol.22 No.1
Zinc oxide (ZnO) nanorods were synthesized using a modified wet chemical method. Poly(vinylidene fluoride-co-hexafluoropropylene), P(VDF-HFP), nanocomposites with different ZnO nanorods loadings were prepared viaa solution blend route. Field emission scanning electron microscopic (FE-SEM), X-ray diffraction (XRD), Fouriertransform infrared spectroscopy (FTIR) were used to investigate the structure and morphology of the nanocomposites. XRD and FTIR data indicate that the incorporation of ZnO nanorods promote the crystalline structure transformationof P(VDF-HFP). As the content of ZnO nanorods increases, the β phase structure increases while the α phasedecreases. In addition, the dielectric properties of the P(VDF-HFP) and its composites were systematically studied.
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Enhanced Thermal and Mechanical Properties of Polyimide/Graphene Composites
Wen Dai,Jinhong Yu,Yi Wang,Yingze Song,Hua Bai,Kazuhito Nishimura,Huiwei Liao,Nan Jiang 한국고분자학회 2014 Macromolecular Research Vol.22 No.9
Polyimide (PI)/graphene sheets (GSs) composites were prepared by solution blending. The incorporationof GSs into PI increased the thermal conductivity, thermal stability and mechanical properties of PI. The thermal conductivityof PI/GSs composites was significantly improved compared with that of neat PI from 0.254 to 1.002 W/mK; this can be attributed to the homogeneous dispersion of graphene and the formation of heat conduction pathway. Furthermore, the Young modulus of PI/GSs was raised up to 4.04 GPa, approximately two-fold enhancement incomparison with that of neat PI. In addition, the incorportation of GSs in PI indicated excellent optical transparencyat the lowest weight fractions of GSs and modified wettability of PI films.
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