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Yanshui Zhou,Kangzhen Xu,Bozhou Wang,Hang Zhang,Qianqian Qiu,Fengqi Zhao 대한화학회 2012 Bulletin of the Korean Chemical Society Vol.33 No.10
A novel energetic compound, bifurazano[3,4-b:3',4'-f ]furoxano[3'',4''-d] oxacyclohetpatriene (BFFO), was synthesized through special etherification and its structure was determined by single crystal X-ray diffraction. The crystal of BFFO·H2O is monoclinic, space group P2(1)/c with crystal parameters of a = 9.324(4) Å, b = 9.727(4) Å, c = 10.391(4) Å, β = 106.305(6)°, V = 904.5(6) Å3, Z = 4, μ = 0.17 mm−1, F(000) = 512 and Dc = 1.866 g cm−3. Spectroscopic properties and thermal behaviors of BFFO were studied. BFFO presents good detonation properties.
Zhou, Yanshui,Xu, Kangzhen,Wang, Bozhou,Zhang, Hang,Qiu, Qianqian,Zhao, Fengqi Korean Chemical Society 2012 Bulletin of the Korean Chemical Society Vol.33 No.10
A novel energetic compound, bifurazano[3,4-b:3',4'-f]furoxano[3'',4''-d] oxacyclohetpatriene (BFFO), was synthesized through special etherification and its structure was determined by single crystal X-ray diffraction. The crystal of $BFFO{\cdot}H_2O$ is monoclinic, space group P2(1)/c with crystal parameters of a = $9.324(4){\AA}$, b = $9.727(4){\AA}$, c = $10.391(4){\AA}$, ${\beta}=106.305(6)^{\circ}$, V = $904.5(6){\AA}^3$, Z = 4, ${\mu}=0.17mm^{-1}$, F(000) = 512 and $D_c=1.866g\;cm^{-3}$. Spectroscopic properties and thermal behaviors of BFFO were studied. BFFO presents good detonation properties.