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Bak, Seong-Min,Nam, Kyung-Wan,Chang, Wonyoung,Yu, Xiqian,Hu, Enyuan,Hwang, Sooyeon,Stach, Eric A.,Kim, Kwang-Bum,Chung, Kyung Yoon,Yang, Xiao-Qing American Chemical Society 2013 Chemistry of materials Vol.25 No.3
<P>In this work, we present results from the application of a new in situ technique that combines time-resolved synchrotron X-ray diffraction and mass spectroscopy. We exploit this approach to provide direct correlation between structural changes and the evolution of gas that occurs during the thermal decomposition of (over)charged cathode materials used in lithium-ion batteries. Results from charged Li<SUB><I>x</I></SUB>Ni<SUB>0.8</SUB>Co<SUB>0.15</SUB>Al<SUB>0.05</SUB>O<SUB>2</SUB> cathode materials indicate that the evolution of both O<SUB>2</SUB> and CO<SUB>2</SUB> gases are strongly related to phase transitions that occur during thermal decomposition, specifically from the layered structure (space group <I>R</I>3̅<I>m</I>) to the disordered spinel structure (<I>Fd</I>3̅<I>m</I>), and finally to the rock-salt structure (<I>Fm</I>3̅<I>m</I>). The state of charge also significantly affects both the structural changes and the evolution of oxygen as the temperature increases: the more extensive the charge, the lower the temperature of the phase transitions and the larger the oxygen release. Ex situ X-ray absorption spectroscopy (XAS) and in situ transmission electron microscopy (TEM) are also utilized to investigate the local structural and valence state changes in Ni and Co ions, and to characterize microscopic morphology changes. The combination of these advanced tools provides a unique approach to study fundamental aspects of the dynamic physical and chemical changes that occur during thermal decomposition of charged cathode materials in a systematic way.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/cmatex/2013/cmatex.2013.25.issue-3/cm303096e/production/images/medium/cm-2012-03096e_0014.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/cm303096e'>ACS Electronic Supporting Info</A></P>
Xiao-Dan Yue,Jing-Yu Wang,Xin-Rong Zhang,Ju-Hong Yang,Chun-Yan Shan,Miao-Yan Zheng,Hui-Zhu Ren,Yi Zhang,Shao-Hua Yang,Zhen-Hong Guo,Bai Chang,Bao-Cheng Chang 대한의학회 2017 Journal of Korean medical science Vol.32 No.4
Sodium glucose co-transporter 2 (SGLT-2) inhibitors are newly developed but promising medicine for type 2 diabetes. However, patients with a different renal threshold for glucose excretion (RTG) may have a different reaction to this medicine. Therefore, the objective of this study was to investigate the characteristics of RTG and its impact factors in patients with type 2 diabetes mellitus (T2DM). The clinical and laboratory data of 36 healthy individuals and 168 in-hospital patients with T2DM were collected and analyzed, RTG was calculated using blood glucose (BG) measured by dynamic BG monitoring, urinary glucose excretion (UGE) and estimated glomerular filtration rate (eGFR). The characteristics of RTG were investigated. The risk factors for high RTG were analyzed using non-conditional logistic regression analysis. Our results found that RTG of the T2DM group was higher than that of the healthy individuals (P < 0.05); and 22.22% from the healthy individuals group but 58.33% from the T2DM group had high RTG. Age, duration of diabetes, body mass index (BMI), and homeostasis model assessment insulin resistance index (HOMA-IR) were independently associated with high RTG (P < 0.05). Further stratified analysis revealed that RTG in T2DM patients increased with age, duration of diabetes, and BMI. In conclusion, RTG is increased in patients with T2DM, especially in those with longer diabetic duration, higher BMI, and those who are older. Therefore, these patients may be more sensitive to SGLT-2 inhibitors.
Chang Yuan,Chang Liu,Xueyin Zhang,Tianyang Zhao,Xiangning Xiao,Niang Tang 전력전자학회 2017 JOURNAL OF POWER ELECTRONICS Vol.17 No.3
In modern power systems, high penetration of distributed generators (DGs) results in high stress on system stability. Apart from the intermittent nature of DGs, most DGs do not contribute inertia or damping to systems. As a result, a new control method named virtual synchronous machine (VSM) was proposed, which brought new characteristics to inverters such as synchronous machines (SMs). In addition, different active power droop controls for VSMs are being proposed in literatures. However, they are quite different in terms of their dynamic characteristics despite of the similar control laws. In this paper, mathematical models of a VSM adopting different active power droop controls are built and analyzed. The dynamic performance of the VSM output active power and virtual rotor angular frequency are presented for different models. The influences of the damping factor and droop coefficient on the VSM dynamic behaviors are also investigated in detail. Finally, the theoretical analysis is verified by simulations and experimental results.
Fuzzy Resilient Energy-to-Peak Filtering for Continuous-Time Nonlinear Systems
Chang, Xiao-Heng,Park, Ju H.,Shi, Peng Institute of Electrical and Electronics Engineers, 2017 IEEE Transactions on Fuzzy Systems Vol. No.
<P>The problem of resilient energy-to-peak filtering for a class of uncertain continuous-time nonlinear systems is investigated in this paper. A Takagi–Sugeno fuzzy model with norm-bounded uncertainties is used to represent the nonlinear plant. Attention is focused on the design of an energy-to-peak filter such that the filtering error system is asymptotically stable and the prescribed energy-to-peak filtering performance is guaranteed, where the designed filter is assumed to have additive gain variations. The proposed design is aimed at all filter matrices with gain variations, which improves the existing results on resilient energy-to-peak filtering for continuous-time systems. A simulation example is provided to show the effectiveness of the proposed methods.</P>
Xiao Tang,Kun Tong,Lishan Zhu,Guoqing Fu,Wei Chang,Ting Zhou,Zhibing Zhang,Ling Tong,Ling Zhang,Yuqin Shi,Ling Zhang,Yuqin Shi 대한독성 유전단백체 학회 2016 Molecular & cellular toxicology Vol.12 No.4
Di-2-ethylhexyl phthalate (DEHP) which belongs to phthalatic-acid esters, is a kind of harmful, global environmental pollutants. It is a known endocrine disrupting chemical and male reproductive toxicant. However, the mechanism by which DEHP exposure result in male reproductive toxicity is still unclear. To elucidate the productive toxicity mechanism of DEHP, we attemptted to investigate oxidative stress, apoptotic effects, mRNA and protein expression of apoptosis-associated genes including FasL, caspase-3, and caspase-8 in GC-2spd (mouse spermatogenic cells). The results showed that, with the increase of DEHP concentration, cell apoptosis rate increased; the activities of relation index of oxidative stress such as malondialdehyde (MDA), superoxide dismutase (SOD) and glutatione peroxidase (GSH-PX) changed significantly; the mRNA and protein expression levels of FasL, caspase-3, -8, altered obviously. These results suggested that DEHP could induce apoptosis of GC-2spd cells through oxidative stress and FasL-dependent pathway.
Quantized Static Output Feedback Control For Discrete-Time Systems
Chang, Xiao-Heng,Xiong, Jun,Li, Zhi-Min,Park, Ju H. IEEE 2018 IEEE TRANSACTIONS ON INDUSTRIAL INFORMATICS - Vol.14 No.8
<P>This paper investigates the problem of output feedback control for discrete-time systems with two quantized signals in measurement output and control input. Since the measurement output and control input are quantized by general quantizers before they are passed to the controller and the system, the closed-loop system will include the quantization error terms, which might lead to that the performance of the closed-loop system is not guaranteed. For this purpose, this paper proposes a novel quantized output control strategy such that the closed-loop system is asymptotically stable or satisfies the prescribed <TEX>$\mathcal {H}_\infty$</TEX> performance. The corresponding design conditions for the output feedback controllers and the quantizers’ dynamic parameters are presented in terms of solutions to a set of linear matrix inequalities. Finally, a simulation example is given to prove the effectiveness of the proposed design method.</P>
Protective Effect of Dandelion Extracts on Ethanol-Induced Acute Hepatotoxicity in C57BL/6 Mice
Xiao-Yu Liu,Jie Ma,Chung-Mu Park,Hee-Kyung Chang,Young-Sun Song 한국식품영양과학회 2008 Preventive Nutrition and Food Science Vol.13 No.4
Dandelion (Taraxacum officinale) has been widely used as an anti-inflammatory agent in oriental medicine. In the current study, we investigated the protective effect, and the possible mechanism, of dandelion extracts against ethanol-induced acute hepatotoxicity in C57BL/6 mice. Dandelion water and ethanol extract was administered at 2 g/㎏ body weight (BW) once daily for 7 consecutive days, whereas control and ethanol groups received water by gavage. Ethanol (50% ethanol; 6 g/㎏ BW) was administered 12 hr before sacrificing the mice in order to generate liver injury. Significantly increased serum aspartate aminotransferase (AST) and alanine aminotransferase (ALT) activities as well as liver triglyceride (TG) and cholesterol levels were attenuated by dandelion supplementation. In addition, dandelion extracts not only enhanced alcohol dehydrogenase (ADH) and anti-oxidative enzyme activities, but reduced lipid peroxidation. Cytochrome P450 2E1 (CYP 2E1), one of the critical enzymes xenobiotic metabolism, expression was lower with ethanol treatment but restored by dandelion supplementation. These results were confirmed by improved histopathological changes in fatty liver and hepatic lesions induced by ethanol. In conclusion, dandelion could protect liver against ethanol administration by attenuating of oxidative stress and inflammatory responses.
Relaxed Stability Condition and State Feedback H∞ Controller Design for T-S Fuzzy Systems
Xiao-Heng Chang,Guang-Hong Yang 제어·로봇·시스템학회 2009 International Journal of Control, Automation, and Vol.7 No.1
In this paper, a fuzzy Lyapunov approach is presented for stability analysis and state feedback H∞ controller design for T-S fuzzy systems. A new stability condition is obtained by relaxing the ones derived in previous papers. Then, a set of LMI-based sufficient conditions which can guarantee the existence of state feedback H∞ controller for T-S fuzzy systems is proposed. In comparison with the existing literature, the proposed approach not only provides more relaxed stability conditions but also ensures better H∞ performance. The effectiveness of the proposed approach is shown through two numerical examples.