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        Covalent bonding of ZnO nanostructures with dispersible carbon nanotubes for self-assembly photocatalytic heterostructures

        Tie, Weiwei,Jin, Jiaming,Bhattacharyya, Surjya Sarathi,Yue, Hongwei,Lei, Yan,Zheng, Zhi,He, Weiwei,Lee, Seung Hee Elsevier BV * North-Holland 2019 Applied Surface Science Vol.492 No.-

        <P><B>Abstract</B></P> <P>This work demonstrates the fabrication of zinc oxide‑carbon nanotube (ZnO/CNT) heterostructures with tunable photocatalytic activity via microstructure modulation. The ZnO/CNT heterostructures are constructed in one-step hydrothermal procedure consisting of in situ anchoring of ZnO nanostructures with dispersible CNTs in an aqueous alkali solution containing bile salts as a dispersant. Observation via scanning (SEM) and transmission (TEM) electron microscopy reveals self-assembled heterostructures of monodispersible CNTs tightly surrounding ZnO nanostructures with multimorphology. The XRD, FT-IR, Raman and XPS analysis confirm that the CNTs were successfully incorporated into the ZnO nanostructures with strong interfacial contact of covalent bonding rather than simple mixing. A series of ZnO/CNT heterostructures, which varies according to their degree of doping with dispersible CNTs, exhibit distinct sunlight-induced photocatalytic activity onto the degradation of Rhodamine B (RhB). The superior photocatalytic performance of ZnO/CNT heterostructures originates from synergistic effects of sufficient interfacial bonding, self-assembly microstructures, and continuous conducting pathways between ZnO nanostructures and CNTs, which acquires better sunlight utilization and more efficient separation of electron-hole pair, confirmed by UV–Visible diffuse reflectance spectra as well as photocurrent and photovoltage analysis. This study also proposes a photocatalytic degradation mechanism of RhB dyes through detection of active species confirmed by electron-spin-resonance analysis.</P> <P><B>Highlights</B></P> <P> <UL> <LI> ZnO nanostructures covalently linking with dispersible carbon nanotubes for self-assembly heterostructures are synthesized. </LI> <LI> This sunlight-driven self-assembly heterostructures possess tunable photocatalytic activity via microstructure modulation. </LI> <LI> The charge separation and transfer process are monitored by transient photovoltaic and photocurrent measurement. </LI> </UL> </P>

      • KCI등재

        Auxin signaling is involved in iron deficiency-induced photosynthetic inhibition and shoot growth defect in rice (Oryza sativa L.)

        Kaidong Liu,Runqing Yue,Changchun Yuan,Jinxiang Liu,Lei Zhang,Tao Sun,Yanjun Yang,Shuanggui Tie,Chenjia Shen 한국식물학회 2015 Journal of Plant Biology Vol.58 No.6

        Iron deficiency is one of the most serious nutrient limiting factors that affect rice plant growth and photosynthesis. Several phytohormones, including auxin, participate in iron uptake and homeostasis. However, how auxin signaling is involved in iron deficiency-induced inhibition of shoot growth and photosynthetic efficiency is largely unknown. The Nipponbare (NIP) seedlings displayed typical chlorotic symptoms, biomass reduction and photosynthesis depression when subjected to iron deficiency. We measured the soluble Fe content in the shoots under different conditions. The soluble Fe content in the shoots under Fe deficiency was increased by 1-naphthoxyaceticacids (1-NOA) treatment and was decreased by 1-naphthaleneacetic acid (NAA) treatment. Blocking (1-NOA treatment) or enhancement (NAA treatment) of auxin signaling also affects photosynthetic parameters under Fe deficiency conditions. Furthermore, rice microarray data (GSE17245 and GSE39429) were used to analyze the relationship between iron deficiency responses and auxin signaling in shoots. Most iron deficiency response gene expression levels in the shoots increased under exogenous auxin treatment, and most auxin early response gene expression levels responded to iron deficiency. It suggested that there is a crosstalk between iron deficiency signaling and auxin signaling. Our results indicated that iron deciencyinduced growth inhibition and photosynthesis depression were mediated by systemic auxin signaling.

      • KCI등재

        ANALYZING ISUAL SPECTROPHOTOMETER DATA USING A TWO-COLOR DIAGRAM METHOD

        CHEN ALFRED BING-CHIH,CHIANG PO-SHIH,HUANG TIAN-HSIANG,KUO CHENG-LING,WANG SHI-CHUN,SU HAN-TZONG,HSU RUE-RoN,CHANG MING-HUI,CHANG YEOU-SHIN,LIU TIE-YUE,MENDE STEPHEN B.,FREY HARALD U.,FUKUNISHI HIROSH The Korean Astronomical Society 2005 Journal of The Korean Astronomical Society Vol.38 No.2

        Transient luminous events (TLEs; sprites, elves, jets and etc.) are lightning-related optical flashes occurring above thunderstorms. Since the first discovery of sprites in 1989, scientists have learned a great deal about the morphological, spectroscopic and electromagnetic characteristics of TLEs through ground and spacecraft campaigns. However, most of the TLE studies were based on events recorded over US High Plains. To elucidate the possible biasing effects, space-borne observations are needed and have their merits. Imager of sprites and Upper Atmospheric Lightning (ISUAL) on the FORMOSAT-2 satellite is the first instrument to carry out a true global measurement of TLEs from a low- earth orbit. In this short paper, we apply a common astronomical data analysis technique, two-color diagram, on the ISUAL spectrophotometer (SP) data. By choosing appropriated bandpasses and converting the measured flux of TLEs into the unit of magnitude, two-color diagrams of TLEs can be constructed. We demonstrate that two-color diagrams, which were constructed from the narrow-band spectrophotometer data, can be used to classify different types of TLEs and trace their temporal evolution. The amount of reddening due to Earth's atmosphere can also be estimated from two-color diagrams assembled from the broad-band spectrophotometer data.

      • SCIESCOPUSKCI등재

        GROUND OBSERVATIONS OF SPRITES AND OTHER TLES IN TAIWAN

        WANG YUN-CHING,HSU RUE-RON,SU HAN-TZONG,CHEN ALFRED BING-CHIH,LEE YI-JEN,KUO CHENG-LING,TSAY WEAN-SHUN,CHANG CHAN-KAO,WANG SHI-CHUN,LEE LOU-CHUANG,LIU TIE-YUE The Korean Astronomical Society 2005 Journal of The Korean Astronomical Society Vol.38 No.2

        Sprites, elves and blue jets are collectively denominated as the upper atmospheric transient luminous events (TLEs). They are recently discovered optical flashes between active thunderstorms and the ionosphere. In this report, a brief introduction to the most important characteristics of TLEs is given. Since 2001, scientists from the National Cheng Kung University have been performing yearly summer campaigns from various locations in Taiwan. The main achievements of their yearly campaign are presented.

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