Comparison of electrodialysis and reverse electrodialysis processes in the removal of Cu(II) from dilute solutions

Sureyya Altin,Elif Oztekin,Ahmet Altin 한국화학공학회 2017 Korean Journal of Chemical Engineering Vol.34 No.8

Electrodialysis (ED) and electrodialysis reversal (EDR) processes have been often used for separation of ions in dilute solutions. In this study, the performance of ED and EDR processes has been examined in the removal of copper from the dilute solutions. First, applied voltage, initial concentration, flow rate, type of electrolyte and the effect of concentration were determined for both processes. Then, separation efficiency, current efficiency, energy requirement and material flux of the processes were calculated, and the performances of the processes were compared. The separation efficiency and energy consumption of EDR process were higher compared to ED process under equal operating conditions. Also, the current efficiency (39.58%) of EDR process was lower than the current efficiency (67.46%) of ED process. It can be said that the ED process is more suitable in terms of energy consumption for separation in the low flow rate and concentration.

Separation of Cd(II) from Aqueous Solutions by A New Consecutive Process Consisting of Supported Liquid Membrane and Electrodialysis

Altin, Sureyya,Altin, Ahmet The Korean Electrochemical Society 2019 Journal of electrochemical science and technology Vol.10 No.1

Supported liquid membrane process usually is used for recovering or enrichment of valuable metals in the industrial wastewater. But, even if the metals in the wastewater was separated with high chemical selectivity, it cannot be enough concentrated since separation performance of supported liquid membrane (SLM) process is limited by concentration gradient between feed solution and stripping solution. If metal concentration in the stripping solution to be enough low, transport of metal through membrane can be accomplishment constantly. Therefore, Electrodialysis (ED) has been placed after SLM process and the stripping solution of SLM was used as the feed solution for the ED process. Transport of ions in the solutions is successfully performed by ED process. Thus, the metal concentration in the stripping solution does not rise as to stop ion transport. Besides, valuable metals easily are concentrated by ED process for re-use. In this study, effects of operation parameters like initial Cd(II) concentration, HCl concentration in the feed solution of SLM and applied voltage are investigated on separation efficiency, flux and permeability of the both processes. As the feed solution concentration increased, all performance values has increased. When initial concentration of 100 mg/L is used, separation performances (SP) are 55% and 70%, for SLM and consecutive process, respectively. The best HCl concentration in the feed solution of SLM has determined as 2 M, in this conditions SP are 64% and 72%, for SLM and consecutive process, respectively. With increased of applied voltage on ED process, SP of the consecutive process has been raised from 72% to 83%. According to the obtained experimental data, consecutive process has better separation performance than SLM. When the separation performances of both processes were compared for the same operating conditions, it was determined higher the separation efficiency, permeability and flux values of the consecutive process, 8%, 9% and %10.6, respectively. Consequently, the use of the consecutive process increases the performance efficiency of both processes. The consecutive process studied has quite a good chemical separation efficiency, and enrichment capability. Moreover, this process requires few water and energy.

Characterization of Novel <i>O</i>-Glycans Isolated from Tear and Saliva of Ocular Rosacea Patients

Ozcan, Sureyya,An, Hyun Joo,Vieira, Ana C.,Park, Gun Wook,Kim, Jae Han,Mannis, Mark J.,Lebrilla, Carlito B. American Chemical Society 2013 JOURNAL OF PROTEOME RESEARCH Vol.12 No.3

<P><I>O</I>-Glycans in saliva and tear isolated from patients suffering from ocular rosacea, a form of inflammatory ocular surface disease, were profiled, and their structures were elucidated using high resolution mass spectrometry. We have previously shown that certain structures, particularly sulfated oligosaccharides, increased in the tear and saliva of rosacea patients. In this study, the structures of these glycans were elucidated using primarily tandem mass spectrometry. There were important similarities in the glycan profiles of tears and saliva with the majority of the structures in common. The structures of the most abundant species common to both tear and saliva, which were also the most abundant species in both, were elucidated. For sulfated species, the positions of the sulfate groups were localized. The majority of the structures were new, with the sulfated glycans comprising mucin <I>core 1</I>- and <I>core 2</I>-type structures. As both saliva and tear are rich in mucins, it is suggested that the <I>O</I>-glycans are mainly components of mucins. The study further illustrates the strong correspondence between the glycans in the tear and saliva of ocular rosacea patients.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/jprobs/2013/jprobs.2013.12.issue-3/pr3008013/production/images/medium/pr-2012-008013_0010.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/pr3008013'>ACS Electronic Supporting Info</A></P>

Comparison of Some 3-(Substituted-Benzylidene)-1, 3-Dihydro-Indolin Derivatives as Ligands of Tyrosine Kinase Based on Binding Mode Studies and Biological Assay

Olgen, Sureyya The Pharmaceutical Society of Korea 2006 Archives of Pharmacal Research Vol.29 No.11

A series of 3-(substituted-benylidene)-1, 3-dihydro- indolin-2-one, 3-(substituted-benylidene)-1, 3-dihydro- indolin-2-thione and 2, 2'-dithiobis 3-(substituted-benylidene)-1, 3-dihydro-indole derivatives was investigated as inhibitor of $p60^{c-Src}$tyrosine kinase by performing receptor docking studies and inhibitory activity toward tyrosine phosphorylation. Some compounds were shown to be docked at the site, where the selective inhibitor PP1 [1-tert-Butyl-3-p-tolyl-1H-pyrazolo[3,4-d]pyrimidine-4-yl-amine] was embedded at the enzyme active site. Evaluation of all compounds for the interactions with the parameters of lowest binding energy levels, capability of hydrogen bond formations and superimposibility on enzyme active site by docking studies, it can be assumed that 3-(substituted-benzylidene)-1, 3-dihydro-indolin-2-one and thione derivatives have better interaction with enzyme active site then 2, 2'-dithiobis 3-(substituted-benzylidene)-1, 3-dihydro indole derivatives. The test results for the inhibitory activity against tyrosine kinase by Elisa method revealed that 3-(substituted-benylidene)-1, 3-dihydro- indolin-2-thione derivatives have more activity then 3-(substituted-benylidene)-1, 3-dihydro- indolin-2-one derivatives.

Synthesis of magnetite iron pumice composite for heterogeneous Fenton-like oxidation of dyes

Cifci, Deniz Izlen,Meric, Sureyya Techno-Press 2020 Advances in environmental research Vol.9 No.3

The removal of two dyes, namely Methylene Blue (MB) and Reactive Brillant Red (RR) from aqueous solution was investigated using magnetite iron coated pumice (MIP) composite in the Fenton-like oxidation process. A weight ratio of 2.5 g (with the molar ratio of Fe³⁺ to Fe²⁺ to be 2) (5%) of iron to the total pumice (50 g) was enabled during synthesis of catalyst. Surface composition and characteristics of the catalyst were assessed by SEM-EDX, FT-IR, Raman spectral analysis. The effect of the amount of pumice solely used or MIP, H₂O₂ concentration, pH and initial concentration of MB or RR dyes on Fenton-like process efficiency was investigated. EDAX spectrums of pumice and MIP showed that oxygen and silisium are the major elements. The Fe content of MIP increased to 2.24%. SEM, FT-IR and Raman spectrums confirmed the impregnation of Fe on pumice surface. The experimental results revealed that high removal rates of dyes could be obtained using MIP that demonstrated a higher stability for removal of MB dye. pH affected the removal efficiency of both dyes and the degradation of both dyes was sharply dropped when pH was increased above 4. The removal of dyes did not significantly change with increasing H₂O₂ concentration. Degradation rates of both MB and RR dyes increased 3.3 and 2.8 times with the use of MIP compared to pumice alone, respectively. Furthermore, MIP enabled a good removal efficiency at higher dye concentrations. It can be emphasized that MIP composite can be used in the heterogeneous Fenton-like systems considering the economic and easily separation aspects.

Optimization of methylene blue adsorption by pumice powder

Cifci, Deniz Izlen,Meric, Sureyya Techno-Press 2016 Advances in environmental research Vol.5 No.1

The main objective of this study is to evaluate adsorptive removal of Methylene Blue (MB) dye from aqueous solution using pumice powder. The effects of pH, adsorption time, agitation speed, adsorbent dose, and dye concentrations on dye adsorption were investigated. Process kinetics and isotherm model constants were determined accordingly. The results showed that adsorbent dose, dye concentration and agitation speed are the important parameters on dye adsorption and the removal of MB did not significantly change by varying pH. A total adsorption process time of 60 min was observed to be sufficient to effectively remove 50 mg/L MB concentration. The MB adsorption data obeyed both pseudo first order and second order kinetic models. Adsorption of MB by pumice fitted well both Langmiur and Freundlich isotherms ($R^2{\geq}0.9700$), except for 150 rpm agitation speed that system fitted only Langmiur isotherm. The results of this study emphasize that pumice powder can be used as a low cost and effective adsorbent for dye removal.

Effective and Reliable Speed Control of Permanent Magnet DC (PMDC) Motor under Variable Loads

Tuna, Murat,Fidan, Can Bulent,Kocabey, Sureyya,Gorgulu, Sertac The Korean Institute of Electrical Engineers 2015 Journal of Electrical Engineering & Technology Vol.10 No.5

This paper presents the effective and reliable speed control of PMDC motors under variable loads and reference speeds. As is known DC motors are more preferred in industrial practices. This is that, the PMDC motors don’t require brush and commutator care and to increase in torque per motor depending on developments in power electronics. In this study, proportional-integral controller (PI) and fuzzy logic controller (FL) have been designed for speed control of PMDC motor. In the design of these controllers, characteristics such as minimum overrun time, response time to the load, settling time and ideal rise time have been taken into consideration for better stability performance. In this design, the best system response was searched by examining the effect of different defuzzification methods onto the fuzzy logic system response. In conclusion, it has been seen that FL controller has a better performance for variable speed-load control of PMDC motor compared to PI controller.

Evaluation of high resolution computed tomography findings of cystic fibrosis

( Ayse Senay Sasihuseyinoglu ),( Derya Ufuk Altıntas ),( Sureyya Soyupak ),( Dilek Dogruel ),( Mustafa Yılmaz ),( Mahir Serbes ),( Gulsah Duyuler ) 대한내과학회 2019 The Korean Journal of Internal Medicine Vol.34 No.2

Background/Aims: Morphological changes due to lung disease in patients with cystic fibrosis (CF) were evaluated using high resolution computed tomography (HRCT), and the HRCT scores obtained using the Bhalla scoring system were correlated with those obtained using clinical and laboratory indicators. Methods: Medical records of 28 children with CF who underwent chest CT in Department of Pediatric Allergy and Immunology, Cukurova University Balcali Hospital between March 2011 and January 2016 were retrospectively reviewed. Demographic data and physical examination, respiratory cultures, pulmonary function tests, and chest HRCT findings were evaluated. Patients were divided into the following two groups according to their forced expiratory volume in the first second (FEV1) values: normal FEV1 (≥ 80% of predicted values) and low FEV1 (< 80% of predicted values). Deep throat or sputum cultures were evaluated for the presence of Pseudomonas aeruginosa (PsA) and other bacteria. HRCT scans were scored using the Bhalla scoring system. Results: No significant correlation was found between the Bhalla scores and sex, age group, or height percentiles. Significant relationships were found between the Bhalla score and weight (p = 0.036) and body mass index (BMI) (p = 0.032) percentiles below the third percentile, bacterial growth in the sputum/ deep throat cultures (p = 0.009), and presence of PsA (p = 0.004). Moreover, a significant correlation was found between the Bhalla score and FEV1 (r = -0.315, p = 0.0272), forced vital capacity (FVC; r = -0.381, p = 0.0178), forced expiratory flow between 25% and 75% of FVC (r = -0.229, p = 0.0431), and BMI (r = -3.368, p = 0.050). Conclusions: Chest HRCT is an important diagnostic tool for the pulmonary evaluation of children with CF.

Effective and Reliable Speed Control of Permanent Magnet DC (PMDC) Motor under Variable Loads

Murat Tuna,Can Bulent Fidan,Sureyya Kocabey,Sertac Gorgulu 대한전기학회 2015 Journal of Electrical Engineering & Technology Vol.10 No.5

This paper presents the effective and reliable speed control of PMDC motors under variable loads and reference speeds. As is known DC motors are more preferred in industrial practices. This is that, the PMDC motors don’t require brush and commutator care and to increase in torque per motor depending on developments in power electronics. In this study, proportional-integral controller (PI) and fuzzy logic controller (FL) have been designed for speed control of PMDC motor. In the design of these controllers, characteristics such as minimum overrun time, response time to the load, settling time and ideal rise time have been taken into consideration for better stability performance. In this design, the best system response was searched by examining the effect of different defuzzification methods onto the fuzzy logic system response. In conclusion, it has been seen that FL controller has a better performance for variable speed-load control of PMDC motor compared to PI controller.

Do Anxiety and Depression Levels Affect the Inflammation Response in Patients Hospitalized for COVID-19

Aybeniz Civan Kahve,Hasan Kaya,Merve Okuyucu,Erol Goka,Sureyya Barun,Yunus Hacimusalar 대한신경정신의학회 2021 PSYCHIATRY INVESTIGATION Vol.18 No.6

Objective The whole world is still struggling with the COVID-19 pandemic. Inflammation response, thought to be associated with severe illness and death, is an important research topic in COVID-19. Inflammation is also an essential condition explored in psychiatric illnesses. Our knowledge about the relationship between the inflammation response and psychiatric comorbidities in patients with COVID-19 is very limited. In this study, the relationship between anxiety and depression levels and inflammation response of patients with COVID-19 hospitalized in the hospital was examined.Methods 175 patients were included in the study. Sociodemographic Data Form, Beck Depression Inventory and Beck Anxiety Inventory were applied to the patients. To evaluate the inflammation responses, blood sedimentation rate, C-reactive protein (CRP), procalcitonin, ferritin, neutrophil/lymphocyte ratio (NLR), and IL-6 levels were examined.Results In our study, no relationship was found between anxiety and depression levels and inflammatory responses in patients hospitalized with a diagnosis of COVID-19. Anxiety and depression levels of women were higher than men, and NLR, ferritin, IL-6 levels were found to be lower than men. Anxiety levels increase with age. There is a positive correlation between NLR and ferritin levels and duration of hospitalization.Conclusion Our study examining the relationship of psychiatric comorbidities with the inflammation response and our increasing literature knowledge, together with studies evaluating the mental effects of COVID-19, suggest that determining the relationship between inflammation responses and psychiatric comorbidities in COVID-19, whose pathophysiology has not been clarified yet, maybe an essential step in interventions on the course of the disease.