Preparation of ultra-porous graphene oxide using a glucose-mediated hydrothermal method for efficient removal of fluoride ions from water: kinetics, isotherms and co-existing ions studies

Sahoo Shraban Kumar,Sahoo Jitendra Kumar,Biswal Susanta Kumar,Gagan Kumar Panigrahi 한국탄소학회 2024 Carbon Letters Vol.34 No.1

Porous graphene oxide (P-GO) was successfully synthesized by using a simple glucose mediated hydrothermal method form prepared graphene oxide (GO). Then the P-GO was characterized by X-ray Powder Diffraction (XRD), Fourier-Transform Infrared (FITR), Raman, Brunauer–Emmett–Teller (BET), Field Emission Scanning Electron Microscopy (FESEM) and Transmission Electron Microscopy (TEM) analysis to determine the crystallinity, surface functionality, surface defect, surface area and porous nature of the material. For the comparative properties studies with P-GO, the synthesised GO was also characterised using the aforementioned analytical techniques. The formation of macroporous 2D sheet-like structure of P-GO with pore size diameters of 0.2–0.5 µm was confirmed by FESEM and TEM images. The surface area of P-GO was found to be 1272 m2/g which is much higher compare to GO (i.e., 172 m2/g) because of porous structure. P-GO was used for the adsorptive removal of F− ions from water using batch adsorption method. The highest adsorption occurs in the pH range of 5–7 with maximum adsorption capacity of 1272 mg/g. The experimental data revealed that the adsorption process obeys Langmuir monolayer isotherm model. The kinetic analysis revealed that the adsorption procedure is extremely rapid and mainly fit to the Pseudo-second-order (PSO) model. The effect of co-existing ions on fluoride adsorption capacity by P-GO decreases in the following order: PO43− > CO32− > SO42− > HCO3− > NO3− > Cl−. The mechanism of adsorption of fluoride onto the P-GO surface includes electrostatic interactions and hydrogen bonding.

A Critical Survey of Seaweed Diversity of Chilika Lake, India

Sahoo, Debasish,Sahu, Nivedita,Sahoo, Dinabandhu The Korean Society of Phycology 2003 ALGAE Vol.18 No.1

PCR-SSCP of Serum Lysozyme Gene (Exon-III) in Riverine Buffalo and Its Association with Lysozyme Activity and Somatic Cell Count

Sahoo, Nihar Ranjan,Kumar, Pushpendra,Bhushan, Bharat,Bhattacharya, T.K.,Sharma, Arjava,Dayal, Sanker,Pankaj, Prabhat Kumar,Sahoo, Monalisa Asian Australasian Association of Animal Productio 2010 Animal Bioscience Vol.23 No.8

Serum lysozyme gene is one of the important genes influencing the immune system as its product can cause lysis of bacterial cell wall by cleaving the peptidoglycan layer. The present investigation on the serum lysozyme gene of Indian riverine buffalo was undertaken with the objectives to identify and characterize single nucleotide polymorphic patterns by PCR-SSCP method as well as to study the effect of different genotypes on serum lysozyme activity and somatic cell count. A total of 280 animals comprising four different famous bubaline breeds (Murrah, Mehsana, Surti and Bhadawari), spread over six different farms across the country were used for this study. A 276 bp (partial intron 2, complete exon 3 and partial intron 3) fragment of lysozyme gene was screened for polymorphism using the SSCP technique. Four genotypes namely AA, AB, BC and AC were observed, out of which BC genotype was found to be the most frequent. Among these three alleles, C allele (0.38) was most prevalent in these populations. Various SSCP allelic variants were cloned for sequencing and sequences were submitted to NCBI Genbank. From the alignment of the nucleotide sequences of various allelic variants, it was found that there were differences in 12 positions among the alleles, out of which maximum variation (at 8 places) was found in the intronic region. The allele A was closer to allele-C than allele-B. Allele B was phylogenetically equidistant from both of the other alleles. Mean lysozyme activity determined in serum samples of different animals of Murrah buffalo was $27.35{\pm}2.42\;{\mu}g$ per ml of serum, whereas the mean somatic cell count was $1.25{\pm}0.13{\times}10^5$ cells per ml of milk. The SSCP pattern-wise effects of various genotypes on lysozyme activity and SCC were analyzed. Although the mean values were apparently different in various genotypes, these differences were statistically non-significant. It can be concluded that the riverine buffaloes are sufficiently polymorphic with respect to serum lysozyme gene. The absence of AA genotype in Bhadawari breed of buffalo can be considered as a marker for breed characterization. The difference of four nucleotides in exon-3 indicates high selection pressure on the gene.

Thermal frequency analysis of FG sandwich structure under variable temperature loading

Brundaban Sahoo,Kulmani Mehar,Bamadev Sahoo,Nitin Sharma,Subrata Kumar Panda 국제구조공학회 2021 Structural Engineering and Mechanics, An Int'l Jou Vol.77 No.1

The thermal eigenvalue responses of the graded sandwich shell structure are evaluated numerically under the variable thermal loadings considering the temperature-dependent properties. The polynomial type rule-based sandwich panel model is derived using higher-order type kinematics considering the shear deformation in the framework of the equivalent single-layer theory. The frequency values are computed through an own home-made computer code (MATLAB environment) prepared using the finite element type higher-order formulation. The sandwich face-sheets and the metal core are discretized via isoparametric quadrilateral Lagrangian element. The model convergence is checked by solving the similar type published numerical examples in the open domain and extended for the comparison of natural frequencies to have the final confirmation of the model accuracy. Also, the influence of each variable structural parameter, i.e. the curvature ratios, core-face thickness ratios, end-support conditions, the power-law indices and sandwich types (symmetrical and unsymmetrical) on the thermal frequencies of FG sandwich curved shell panel model. The solutions are helping to bring out the necessary influence of one or more parameters on the frequencies. The effects of individual and the combined parameters as well as the temperature profiles (uniform, linear and nonlinear) are examined through several numerical examples, which affect the structural strength/stiffness values. The present study may help in designing the future graded structures which are under the influence of the variable temperature loading.

Numerical buckling temperature prediction of graded sandwich panel using higher order shear deformation theory under variable temperature loading

Brundaban Sahoo,Bamadev Sahoo,Nitin Sharma,Kulmani Mehar,Subrata Kumar Panda 국제구조공학회 2020 Smart Structures and Systems, An International Jou Vol.26 No.5

The finite element solutions of thermal buckling load values of the graded sandwich curved shell structure are reported in this research using a higher-order kinematic model including the shear deformation effect. The numerical buckling temperature has been computed using an in-house specialized code (MATLAB environment) prepared in the framework of the current mathematical formulation. In addition, the mathematical model includes the excess structural distortion under the influence of elevated environment via Green-Lagrange nonlinear strain. The corresponding eigenvalue equation has been solved to predict the critical buckling temperature of the graded sandwich structure. The numerical stability and the accuracy of the current solution have been confirmed by comparing with the available published results. Thereafter, the model is extended to bring out the influences of structural parameters i.e. the curvature ratio, core-face thickness ratio, support conditions, power-law indices and sandwich types on the thermal buckling behavior of graded sandwich curved shell panels.

Problems and solutions to conduct of thesis of postgraduate medical students during the COVID-19 pandemic: an insight into the students perspective

Alok Kumar Sahoo,Nitasha Mishra,Manisha Sahoo,Premangshu Ghoshal 한국의학교육학회 2023 Korean journal of medical education Vol.35 No.1

Purpose: The coronavirus disease 2019 (COVID-19) pandemic has adversely impacted medical education worldwide. However, its impact on the postgraduate medical thesis and dissertation work is still not evaluated. Through this study, we planned to find out the problems brought by the pandemic and likely alternatives and possible solutions to thrust the academic competence of postgraduate students. Methods: After obtaining institutional ethics committee approval, we sent a 13-item questionnaire to postgraduate medical students in India via various social media online platforms. Data on the impact of the COVID-19 pandemic on thesis work and alternatives/solutions to improve the research competence were collected on a Likert scale and analyzed. Results: We received a total of 398 responses out of which 377 entries were included for final analysis. The majority of participants (88%) reportedly had an adverse impact on the thesis work and out of 25% of the participants who recently submitted their around 45% had to do so without achieving the estimated sample size. The 6-month departmental review for thesis progress was seen in merely 28% of participants. Possible alternatives suggested were the maintenance of log books, task-based assessment of research methodology, departmental audits, and systematic reviews. Solutions suggested for improving the research competence of students were a compulsory research methodology curriculum, a biostatistics department in each institution, permission to conduct thesis work beyond submission time, exclusive time for research work, and financial incentives. Conclusion: Modification in the research aspect of the current postgraduate medical education is the need of the hour and the pandemic has enlightened us regarding the current weaknesses.

Weighted Value Sharing and Uniqueness of Entire Functions

Sahoo, Pulak Department of Mathematics 2011 Kyungpook mathematical journal Vol.51 No.2

In the paper, we study with weighted sharing method the uniqueness of entire functions concerning nonlinear differential polynomials sharing one value and prove two uniqueness theorems, first one of which generalizes some recent results in [10] and [16]. Our second theorem will supplement a result in [17].

Defect-engineered mesoporous ternary nanoarchitecture of zinc-cobalt-oxide/nitrogen-doped graphene as anode material in lithium ion batteries

Sahoo, S.,Bae, S.H.,Lee, Y.S.,Lee, J.M.,Ahn, J.M.,Kim, C.G.,Oh, I.K. Pergamon Press ; Elsevier Science Ltd 2015 Carbon Vol.94 No.-

We report a defect-engineered self-assembly route to a mesoporous ternary ZnCo<SUB>2</SUB>O<SUB>4</SUB>/nitrogen-doped graphene nanoarchitecture as an anode material for lithium ion batteries through a hydrothermal and thermal annealing process. A hetero-nanostructure showed flower-like ZnCo<SUB>2</SUB>O<SUB>4</SUB> nanosheets which were well dispersed and firmly decorated on nitrogen-doped reduced graphene oxide, as atomic-scale defects such as nitrogen-doped sites and oxygen-functional groups in chemically modified graphene oxide can be more reactive nucleation sites to anchor metallic nanoparticles strongly. Strong synergy between N-doped graphene and ZnCo<SUB>2</SUB>O<SUB>4</SUB> is observed as a high-performance anode electrode material for much higher capacity levels and more durable electrochemical stability in lithium ion batteries. The mesoporous nanoarchitecture electrode shows enhanced reversible performance in cyclic anode tests, maintaining a specific energy capacity of 998mAhg<SUP>-1</SUP> after 30cycles at current density of 100mAg<SUP>-1</SUP>.

Meromorphic Functions Sharing a Nonzero Polynomial IM

Sahoo, Pulak Department of Mathematics 2013 Kyungpook mathematical journal Vol.53 No.2

We study the uniqueness of meromorphic functions concerning nonlinear differential polynomials sharing a nonzero polynomial IM. Though the main concern of the paper is to improve a recent result of the present author [12], as a consequence of the main result we also generalize two recent results of X. M. Li and L. Gao [11].

Effect of Formaldehyde Treated Rape Seed Oil Cake Based Diet Supplemented with Molasses on Growth Rate and Histopathological Changes in Goats

Sahoo, B.,Walli, T.K.,Sharma, A.K. Asian Australasian Association of Animal Productio 2006 Animal Bioscience Vol.19 No.7

An experiment with twenty crossbred goat kids (male) of 2-3 months old, weighing about 12 kg was conducted to study the effect of feeding formaldehyde treated rape seed oil cake based diet supplemented with molasses on growth rate and histopathological changes of different organs. Goats were randomly divided into four groups of 5 animals each and were individually fed for a period of 120 days. The animals in group I (URC) and II (URCM) were fed concentrate mixture (CM-I) containing untreated rape seed oil cake (30%) while, the animals in group III (TRC) and IV (TRCM) were offered concentrate mixture (CM-II) containing formaldehyde treated rape seed oil cake. Further, molasses as energy source was additionally supplemented with the concentrate mixture at the rate of 8% of concentrate mixture on dry matter basis to animals in group II and IV. All the animals were maintained on roughage (Berseem hay:wheat straw = 2:1) and concentrate in 50:50 ratio. Average daily gain (g/d) of animals in group IV was significantly (p<0.05) higher than that in group I., but at par with group II and III. Feed conversion efficiency was also significantly (p<0.05) higher in group IV (10.14) than group I and II but at par with group III. The growth rate however increased by 50.2% in group IV showing more consistency in maintaining highest growth rate due to better balance of nutrients. At the end of four months of feeding trial, two animals from each group were sacrificed for histopathological study of different organs. Significant histopathological changes in liver, heart, lungs tissue of animals fed untreated rape seed oil cake diet were recorded which were totally absent in the organ of animals fed formaldehyde treated cake. The liver tissue of goats receiving control diet (containing untreated rape seed oil cake) were found to be associated with engorged central vein and blood vessels. Hepatocytes were swollen, pale and degenerated with cellular infiltration and fibrosis of portal areas. The muscles of heart were found to have intermyofibral edema. Emphysema accompanied by dilated and ruptured alveoli was also recorded in lung tissue. However, histopathological examination of various tissues of goats fed formaldehyde treated cake diet did not exhibit any degenerative changes. Additional supplementation of molasses with or without treated cake diet, apparently did not have any significant effect on ameliorating the above degenerative changes.