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Rajesh,S.S. Pandey,W. Takashima,K. Kaneto 한국물리학회 2005 Current Applied Physics Vol.5 No.2
A conducting polypyrrole lm has been prepared on indium tin oxide coated glass plate by electropolymerization of pyrrole in anaqueous solution of enzyme, tyrosinase (PPO), and a redox mediator potassium hexacyanoferrate (II). The enzyme retains its bio-activity well within the polymer lm. Phenol concentration in aqueous solution was quantitatively estimated by monitoring the elec-tron exchange occurring in redox mediator within the polymer matrix i.e. direct reduction of Fe (III) to Fe (II) ion at +0.12V vs. Ag/AgCl. The results of amperometric response measurements conducted on enzyme electrode (PPO/Fe2+/PPY/ITO) show a sensitivityof 0.33 AM. 1 cm. 2 and a linear response range of 4.5107.4l M for phenol in aqueous medium. The electrode exhibits a responsetime of about 80 second and is stable for 4 months at 4.C..
Rajesh,K.Kaneto 한국물리학회 2005 Current Applied Physics Vol.5 No.2
A conducting polymer film of N-amino substituted pyrrole monomer has been prepared for covalent immobilization of enzyme for biosensing applications, illustrated by tyrosinase (PPO).The tyrosinase enzyme retains its bioactivity when being immobilized on N-substituted pyrrole polymer film by covalent bonding.The enzyme electrode was characterized by UV.Vis and infrared spectroscopy.Phenolic compounds were quantitatively estimated by the direct electrochemical reduction of enzymatically liberated quinone species at 0.2 V vs. Ag/AgCl. The results of amperometric response measurements conducted on enzyme electrode show sensitivity of 57.6, 71.4 and 45.8 mAM1cm2 and a linear response range of 1.8.170.2, 1.3.110.1 and 2.1.168 lM for phenol, catechol and p-cresol, respectively. The biosensor exhibits a lowest detection limit of 0.9, 0.7 and 1.1 lM, for phenol, catechol and p-cresol, respectively and a period of stable sensitivity of 3 months at 4.5 C.
Effect of Preoperative Vitamin D Levels on Functional Performance after Total Knee Arthroplasty
Rajesh Navin Maniar,Aniket Machindra Patil,Adit Rajesh Maniar,Bharat Gangaraju,Jaivardhan Singh 대한정형외과학회 2016 Clinics in Orthopedic Surgery Vol.8 No.2
Background: Low vitamin D levels affects muscle function. Vitamin D and calcium deficiency cause osteomalacic myopathy and poor functional recovery after hip fractures. The relationship of vitamin D and functional performance after total knee arthroplasty (TKA) is not previously reported. Methods: Influence of vitamin D on functional performance before and after TKA was reviewed retrospectively in 120 patients. Of these, 64 had vitamin D deficiency (25-hydroxy vitamin D < 30 ng/mL) preoperatively. All 120 patients received vitamin D oral supplementation postoperatively. Functional parameters including Western Ontario and McMaster Osteoarthritis Index (WOMAC), Short-Form Health Survey questionnaire, and Knee Society Score were assessed pre- and postoperatively at 3 months. Results: Preoperative function was significantly lower in osteoarthritic patients with vitamin D deficiency (WOMAC score; p = 0.040), but at 3 months all functional scores were similar. Conclusions: We concluded that vitamin D deficiency has a negative effect on function in knee osteoarthritic patients. However, postoperative vitamin D supplementation can lead to functional recovery in these patients. Thus, TKA should not be delayed in vitamin D deficient patients; rather supplementation in the postoperative period is preferable to achieve comparable functional outcome at 3 months to patients with vitamin D sufficiency.
Rajesh Girdhardas Mundhada,Atul Dharmaraj Rewatkar,Aishwarya Atul Rewatkar,Anju Rajesh Mundhada,Nikita Navin Chandak 소화기인터벤션의학회 2023 International journal of gastrointestinal interven Vol.12 No.1
Acute mesenteric occlusion is a life-threatening condition with a significant mortality rate and requires prompt diagnosis and revascularization using open repair, a hybrid procedure, or endovascular intervention. The open approach is associated with significant morbidity and mortality, while endovascular procedures are done by the antegrade or retrograde open mesenteric stent technique and have been observed to improve the prognosis and outcomes of mesenteric ischemia. We report three cases of acute-on-chronic mesenteric ischemia secondary to occlusion with failed percutaneous mesenteric artery stenting. They were successfully treated using a novel hybrid technique, without the need for mesenteric arteriotomy or subsequent arterial repair.
Tailor, Rajesh,Parmar, Rajesh,Kim, Jong-Min,Tailor, Ritesh The Korean Statistical Society 2011 Communications for statistical applications and me Vol.18 No.2
This paper suggests two ratio-cum-product estimators of finite population mean using known coefficient of variation and co-efficient of kurtosis of auxiliary characters. The bias and mean squared error of the proposed estimators with large sample approximation are derived. It has been shown that the estimators suggested by Upadhyaya and Singh (1999) are particular case of the suggested estimators. Almost ratio-cum product estimators of suggested estimators have also been obtained using Jackknife technique given by Quenouille (1956). An empirical study is also carried out to demonstrate the performance of the suggested estimators.
Rajesh Rajagopal,류광선 한국공업화학회 2018 Journal of Industrial and Engineering Chemistry Vol.60 No.-
This paper reports the synthesis of lanthanum oxide/hydroxide nanoparticle (LaNPs)-doped rGO nanosheets. The uniform distribution of LaNPs on the rGO nanosheets was confirmed by FESEM, TEM, and elemental analysis. A dramatic change in electrochemical behavior was observed by adjusting the concentration of LaNPs in rGO (LaG ratio = 1:2, 1:1 and 2:1). The LaG 12 showed a better areal capacitance of 889.29 F cm−2 than LaG 11 (428.58 F cm−2) and LaG 21 (260.72 F cm−2). Further, improved cycle stability (84% after 1000 cycles) with good impedance behavior confirms LaG 12 is a suitable electrode material for high-performance supercapacitor fabrication.
Instability and vibration analyses of FG cylindrical panels under parabolic axial compressions
Rajesh Kumar,Tanish Dey,Sarat K. Panda 국제구조공학회 2019 Steel and Composite Structures, An International J Vol.31 No.2
This paper presents the semi-analytical development of the dynamic instability behavior and the dynamic response of functionally graded (FG) cylindrical shallow shell panel subjected to different type of periodic axial compression. First, in prebuckling analysis, the stresses distribution within the panels are determined for respective loading type and these stresses are used to study the dynamic instability behavior and the dynamic response. The prebuckling stresses within the shell panel are the same as applied in-plane edge loading for the case of uniform and linearly varying loadings. However, this is not true for the case of parabolic loadings. The parabolic edge loading produces all the stresses (σxx, σyy and τxy) within the FG cylindrical panel. These stresses are evaluated by minimizing the membrane energy via Ritz method. Using these stresses the partial differential equations of FG cylindrical panel are formulated by applying Hamilton‟s principal assuming higher order shear deformation theory (HSDT) and von-Kármán non-linearity. The non-linear governing partial differential equations are converted into a set of Mathieu-Hill equations via Galerkin‟s method. Bolotin method is adopted to trace the boundaries of instability regions. The linear and non-linear dynamic responses in stable and unstable region are plotted to know the characteristics of instability regions of FG cylindrical panel. Moreover, the non-linear frequency-amplitude responses are obtained using Incremental Harmonic Balance (IHB) method.