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      • SCISCIESCOPUS

        Effects of counter ions on electrochromic behaviors of asymmetrically substituted viologens

        Pande, Gaurav K.,Kim, Namhyeon,Choi, Jin Hui,Balamurugan, Gopal,Moon, Hong Chul,Park, Jong S. North-Holland 2019 Solar Energy Materials and Solar Cells Vol. No.

        <P><B>Abstract</B></P> <P>We present effects of counter anions on electrochromic behavior of asymmetrically substituted viologens, 1-hexyl-1′-nonafluorohexyl viologens (HERFVs). For this purpose, two anions, hexafluorophosphate ([PF<SUB>6</SUB>]<SUP>–</SUP>) and bis(trifluorosulfonyl)imide ([TFSI]<SUP>–</SUP>), were employed for both HERFVs and 1-butyl-3-methylimidazolium ([BMIM]<SUP>+</SUP>)-based ionic liquids. The HERFV-containing electrochromic devices (ECDs) exhibited apparent dependence on the counter ions in terms of optical contrast, switching speed, long-term cyclic stability, coloration efficiency, and memory effect. Specifically, the ECDs based on [HERFV][PF<SUB>6</SUB>]<SUB>2</SUB> showed a redox response at −1.0 V with a color change from colorless to blue. Meanwhile, the coloration of [HERFV][TFSI]<SUB>2</SUB> appeared at −3.0 V, and a significantly long optical memory effect was observed with unstable cyclic repeatability. We attributed this discrepancy to the nature of counter ions, such as size and electronegativity, which may influence the electron transfer process during redox reactions. These results demonstrated that counter anions can exert a significant impact on the EC behaviors of asymmetrically substituted viologens. The presented approach suggests a potential tool for controlling EC properties of viologen derivatives for applications in transmissive windows and eye wear.</P>

      • SCIEKCI등재

        Effect of Temperature and Leaf Wetness Period on the Components of Resistance to Late Leaf Spot Disease in Groundnut

        Pande, Suresh,Rajesh, T.Ratna,Kishore, G.Krishna The Korean Society of Plant Pathology 2004 Plant Pathology Journal Vol.20 No.1

        A complete understanding of the epidemiological factors required for optimum for disease development facilitates the design of effective and reliable screening techniques and also disease prediction models. An attempt was made to study the effects of different temperatures ($15-35^{\circ}C$) and leaf wetness periods (4-24 h) on the development of late leaf spot (LLS) in three groundnut genotypes differing in their susceptibility to LLS infection. Irrespective of the genotype, the disease progress evaluated based on different components of resistance was maximum between $15-20^{\circ}C$ and minimum between $20-25^{\circ}C$. At temperatures $\geq$$30^{\circ}C$, LLS development was insignificant. The overall severity of LLS increased with an increase in the leaf wetness period from 4 h to 12 h a day. Further increase of wetness period to 16 h resulted in a rapid increase in the severity. Thereafter, the disease severity gradually decreased with an increase in the wetness period. The effect of temperature and wetness periods on the individual component of disease quantification was not uniform compared between genotypes with different levels of susceptibility/resistance to LLS infection. The results of this study indicate that temperature and leaf wetness period are critical in late leaf spot screening programs since the expression of disease symptoms measured from disease initiation till defoliation, varied differently in the test genotypes with respect to change in these two parameters.

      • SCIEKCI등재

        Establishment of the Chickpea Wilt Pathogen Fusarium oxysporum f. sp. ciceris in the Soil through Seed Transmission

        Pande S.,Rao, J. Narayana,Sharma M. The Korean Society of Plant Pathology 2007 Plant Pathology Journal Vol.23 No.1

        Chickpea wilt caused by Fusarium oxysporum f. sp. ciceris(FOC) is the most destructive disease in India. It is seed-borne as well as soil-borne pathogen. The role of seed-borne FOC in introducing and establishing wilt in FOC free soils is unknown. Using seeds of FOC infected chickpea cultivar K 850, we provided an evidence of establishing wilt disease in the FOC free soils within three crop cycles or seasons. In the first cycle, typical wilt symptoms were observed in 24 pots in 41 days after sowing. These 24 pots were used for second and third cycles without changing the soil. These 24 pots were sown with seeds collected from healthy plants of a susceptible cultivar JG 62, one seed per pot and development of wilt symptom was recorded. Wilt symptoms appeared in all the pots 26 days after sowing in second cycle and in 16 days after sowing in third cycle. On selective medium, all of the wilted plants yielded FOC in all the three cycles indicating that the mortality was due to wilt. FOC propagules on selective medium were 172, 1197, and 2280 $g^{-1}$ soil at the end of the first, second, and third cycles, respectively. These studies indicated that Fusarium wilt of chickpea is seed-borne and seeds harvested from wilted plants when mixed with healthy seeds can carry the wilt fungus to new areas and can establish the disease in the soil to economic threshold levels within three seasons.

      • SCIEKCI등재

        Effect of Plant Population Densities on the Severity of tate Leaf Spot and Rust of Groundnut

        Pande, S.,Rao, J.Narayana The Korean Society of Plant Pathology 2002 Plant Pathology Journal Vol.18 No.5

        The effect of five plant population densities [5 (D$_1$), 10 (D$_2$), 20 (D$_3$), 30 (D$_4$), and 40 (D$_{5}$) plants/m$^2$] of four groundnut cultivars [ICGV 86699, ICG (FDRS) 10, ICGS 11 and TMV 2] and fungicide application (Kavach, chlorothalonil) to manage late leaf spot (LLS) and rust were studied in a field experiment during the 1995 and 1996 rainy seasons. LLS and rust severities were low in fungicide sprayed plots in all the cultivars irrespective of plant densities. Severities of LLS and rust, and percentage defoliation caused by LLS were significantly more in higher plant densities (D$_4$, D$_{5}$) than in lower plant densities (D$_1$, D$_2$, D$_3$) in fungicide sprayed and unsprayed plots in all the cultivars. All the cultivars gave significantly higher haulm and pod yields in fungicide sprayed plots than in unsprayed plots. Haulm and pod yields were significantly higher in higher plant densities than in lower plant densities. A combination of higher plant densities (D$_4$, D$_{5}$) and fungicide protection against LLS and rust gave maximum yield.yield.

      • SCOPUS

        Quality-Oriented Video Delivery over LTE

        Pande, Amit,Ramamurthi, Vishwanath,Mohapatra, Prasant Korean Institute of Information Scientists and Eng 2013 Journal of Computing Science and Engineering Vol.7 No.3

        Long-term evolution (LTE) is emerging as a major candidate for 4G cellular networks to satisfy the increasing demands for mobile broadband services, particularly multimedia delivery. Multiple-input multiple-output (MIMO) technology combined with orthogonal frequency division multiple access and more efficient modulation/coding schemes (MCS) are key physical layer technologies in LTE networks. However, in order to fully utilize the benefits of the advances in physical layer technologies, the MIMO configuration and MCS need to be dynamically adjusted to derive the promised gains of 4G at the application level. This paper provides a performance evaluation of video traffic with variations in the physical layer transmission parameters to suit the varying channel conditions. A quantitative analysis is provided using the perceived video quality as a video quality measure (evaluated using no-reference blocking and blurring metrics), as well as transmission delay. Experiments are performed to measure the performance with changes in modulation and code rates in poor and good channel conditions. We discuss how an adaptive scheme can optimize the performance over a varying channel.

      • SSCISCOPUSKCI등재
      • SCOPUS

        Quality-Oriented Video Delivery over LTE

        Amit Pande,Vishwanath Ramamurthi,Prasant Mohapatra 한국정보과학회 2013 Journal of Computing Science and Engineering Vol.7 No.3

        Long-term evolution (LTE) is emerging as a major candidate for 4G cellular networks to satisfy the increasing demands for mobile broadband services, particularly multimedia delivery. Multiple-input multiple-output (MIMO) technology combined with orthogonal frequency division multiple access and more efficient modulation/coding schemes (MCS) are key physical layer technologies in LTE networks. However, in order to fully utilize the benefits of the advances in physical layer technologies, the MIMO configuration and MCS need to be dynamically adjusted to derive the promised gains of 4G at the application level. This paper provides a performance evaluation of video traffic with variations in the physical layer transmission parameters to suit the varying channel conditions. A quantitative analysis is provided using the perceived video quality as a video quality measure (evaluated using no-reference blocking and blurring metrics), as well as transmission delay. Experiments are performed to measure the performance with changes in modulation and code rates in poor and good channel conditions. We discuss how an adaptive scheme can optimize the performance over a varying channel.

      • KCI등재후보
      • KCI등재

        Establishment of the Chickpea Wilt Pathogen Fusarium oxysporum f. sp. cicerisin the Soil through Seed Transmission

        S. Pande,M. Sharma,J. Narayana Rao 한국식물병리학회 2007 Plant Pathology Journal Vol.23 No.1

        Chickpea wilt caused by Fusarium oxysporum f. sp. ciceris (FOC) is the most destructive disease in India. It is seed-borne as well as soil-borne pathogen. The role of seed-borne FOC in introducing and establishing wilt in FOC free soils is unknown. Using seeds of FOC infected chickpea cultivar K 850, we provided an evidence of establishing wilt disease in the FOC free soils within three crop cycles or seasons. In the first cycle, typical wilt symptoms were observed in 24 pots in 41 days after sowing. These 24 pots were used for second and third cycles without changing the soil. These 24 pots were sown with seeds collected from healthy plants of a susceptible cultivar JG 62, one seed per pot and development of wilt symptom was recorded. Wilt symptoms appeared in all the pots 26 days after sowing in second cycle and in 16 days after sowing in third cycle. On selective medium, all of the wilted plants yielded FOC in all the three cycles indicating that the mortality was due to wilt. FOC propagules on selective medium were 172, 1197, and 2280 g−1 soil at the end of the first, second, and third cycles, respectively. These studies indicated that Fusarium wilt of chickpea is seed-borne and seeds harvested from wilted plants when mixed with healthy seeds can carry the wilt fungus to new areas and can establish the disease in the soil to economic threshold levels within three seasons.

      • KCI등재

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