Electro-chemical Preparation of TiO₂/CNT Electrodes with TNB Electrolyte and Their Photoelectrocatalytic Effect

Feng-Jun Zhang,Ming-Liang Chen,Won-Chun Oh 한국세라믹학회 2009 한국세라믹학회지 Vol.46 No.6

We investigate a method for the electrochemical preparation of titanium dioxide/carbon nanotube (TiO₂/CNT) composites involving the electroplating of Ti in a titanium n-butoxide (TNB) electrolyte into a CNT matrix. The Brunauer-Emmett-Teller (BET) surface areas of TiO₂/CNT composites decrease as the electrochemical operating time increases. Changes in XRD patterns show a typical anatase type on the TiO₂/CNT composite prepared with a CNT matrix by the electroplating method in a TNB solution. In SEM micrographs, the titanium complex particles are uniformly distributed on the CNT surface. The results of chemical elemental analysis for the TiO₂/CNT composites show that most of the spectra for these samples produce stronger peaks for carbon and Ti metal than for any other element. Finally, the prominent photoelectrocatalytic activities of the TiO₂/CNT composites can be attributed to the combined effects of photodegradation of TiO₂, electron assistance of CNT, and the application of a sufficient voltage.

Visible Light Photoelectrocatalytic Properties of Novel Yttrium Treated Carbon Nanotube/Titania Composite Electrodes

Feng-Jun Zhang,Ming-Liang Chen,Kan Zhang,오원춘 대한화학회 2010 Bulletin of the Korean Chemical Society Vol.31 No.1

Photoelectrocatalytic decolorization of methlene blue (MB) in the presence of two types of carbon nanotube/titania and yttrium-treated carbon nanotube/titania electrodes in aqueous solutions were studied under visible light. The prepared composite electrodes were characterized by X-ray diffraction, transmission and scanning electron microscopy, energy dispersive X-ray analysis, and photoelectrocatalytic activity. The photoelectrocatalytic performances of the supported catalysts were evaluated for the decolorization of MB solution under visible light irradiation. The results showed that yttrium incorporation enhanced the decolorization rate of MB. It was found that the photoelectrocatalytic degradation of a MB solution could be attributed to the combined effects caused by the photo-degradation of titania, the electron assistance of carbon nanotube network, the enhancement of yttrium and a function of the applied potential. The repeatability of photocatalytic activity was also tested. The presence of yttrium enhanced the hydrophillicity of yttrium-carbon nanotubes/titania electrode because more OH groups can be adsorbed on the surface.

A novel M2e-multiple antigenic peptide providing heterologous protection in mice

Feng Wen,Ji-Hong Ma,Hai Yu,Fu-Ru Yang,Meng Huang,Yan-Jun Zhou,Ze-Jun Li,Xiu-Hui Wang,Guo-Xin Li,Yi-Feng Jiang,Wu Tong,Guangzhi Tong 대한수의학회 2016 Journal of Veterinary Science Vol.17 No.1

Swine influenza viruses (SwIVs) cause considerable morbidity and mortality in domestic pigs, resulting in a significant economic burden. Moreover, pigs have been considered to be a possible mixing vessel in which novel strains loom. Here, we developed and evaluated a novel M2e-multiple antigenic peptide (M2e-MAP) as a supplemental antigen for inactivated H3N2 vaccine to provide cross-protection against two main subtypes of SwIVs, H1N1 and H3N2. The novel tetra-branched MAP was constructed by fusing four copies of M2e to one copy of foreign T helper cell epitopes. A high-yield reassortant H3N2 virus was generated by plasmid based reverse genetics. The efficacy of the novel H3N2 inactivated vaccines with or without M2e-MAP supplementation was evaluated in a mouse model. M2e-MAP conjugated vaccine induced strong antibody responses in mice. Complete protection against the heterologous swine H1N1 virus was observed in mice vaccinated with M2e-MAP combined vaccine. Moreover, this novel peptide confers protection against lethal challenge of A/Puerto Rico/8/34 (H1N1). Taken together, our results suggest the combined immunization of reassortant inactivated H3N2 vaccine and the novel M2e-MAP provided cross-protection against swine and human viruses and may serve as a promising approach for influenza vaccine development.

Dynamic Analysis of Spine Sagittal Balance during Walking Using Motion Analysis Technology

Jun Feng,Yoon Hyuk Kim,Kyungsoo Kim 대한기계학회 2013 대한기계학회 춘추학술대회 Vol.2013 No.12

Influence of latitude wind pressure distribution on the responses of hyperbolodial cooling tower shell

Jun-Feng Zhang,Yao-Jun Ge,Lin Zhao 한국풍공학회 2013 Wind and Structures, An International Journal (WAS Vol.16 No.6

Interference effects are of considerable concern for group hyperboloidal cooling towers, but evaluation methods and results are different from each other because of the insufficient understanding on the structure behavior. Therefore, the mechanical performance of hyperboloidal cooling tower shell under wind loads was illustrated according to some basic properties drawn from horizontal rings and cantilever beams. The hyperboloidal cooling tower shell can be regarded as the coupling of horizontal rings and meridian cantilever beams, and this perception is beneficial for understanding the mechanical performance under wind loads. Afterwards, the mean external latitude wind pressure distribution, CP(θ), was artificially adjusted to pursue the relationship between different CP(θ) and wind-induced responses. It was found that the maximum responses in hyperboloidal cooling tower shell are primarily dominated by the non-uniformity of CP(θ) but not the local pressure amplitude CP or overall resistance/drag coefficient CD. In all the internal forces, the maximum amplitude of meridian axial tension shows remarkable sensitivity to the variation of CP(θ) and it’s also the controlling force in structure design, so it was selected as an indicator to evaluate the influence of CP(θ) on responses. Based on its sensitivity to different adjustment parameters of CP(θ), an comprehensive response influence factor, RIF, was deduced to assess the meridian axial tension for arbitrary CP(θ).

Characterization and Photonic Effect of Novel Ag-CNT/TiO2 Composites and their Bactericidal Activities

Feng-Jun Zhang,오원춘 대한화학회 2010 Bulletin of the Korean Chemical Society Vol.31 No.7

A novel composite (Ag-CNT/TiO2) of silver treated carbon nanotubes (Ag-CNT) and TiO2 was synthesized via wet chemistry followed by a heat treatment. The dispersion and structure of the silver in the synthesized composites determined by X-ray diffraction (XRD), energy dispersive X-ray (EDX) spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy(TEM). XRD patterns of the composites showed that the composites contained a mixing anatase and rutile phase. The EDX spectra showed the presence of C, O, Ti and Ag peaks. The TiO2 particles were distributed uniformly in the CNT network, and silver particles were virtually fixed on the surface of the tube. The photocatalysis degraded behaviors of the Ag-CNT/TiO2 composites of the methylene blue, which increased with an increase of the silver component. The Ag-CNT/TiO2 composites have excellent antibacterial activities against Escherichia coli (E. Coli), Pseudomonas aeruginosa (P. Aeru) and Bacillus subtilis (B. Sub) under visible light.

Prevalence of Spina Bifida Occulta and Its Relationship With Overactive Bladder in Middle-Aged and Elderly Chinese People

Jun Wei Wu,Yu Rong Xing,Yi Bo Wen,Tian Fang Li,Quan De Feng,Xiao Ping Shang,Yun Long Li,Jin Jin Feng,Xin Xin Wang,Rong Qun Zhai,Xiang Fei He,Tao Chen,Xin Jian Liu,Jian Guo Wen 대한배뇨장애요실금학회 2016 International Neurourology Journal Vol.20 No.2

Purpose: To investigate the prevalence of spina bifida occulta (SBO) and its relationship with the presence of overactive bladder (OAB) in middle-aged and elderly people in China. Methods: A cross-sectional community-based survey was carried out at 7 communities in Zhengzhou City, China from December 15, 2013 to June 10, 2014, where residents aged over 40 years were randomly selected to participate. All of the participants underwent lumbosacral radiographic analysis and relevant laboratory tests. A questionnaire including basic information, past medical history and present illness, and the OAB symptom score was filled out by all participants. Chi-square tests and logistic regression were used for data analysis with a P-value of <0.05 denoting statistical significance. Results: A total of 1,061 subjects were qualified for the final statistical analysis (58.8±11.7 years; male, 471 [44.4%]; female, 590 [55.6%]). The overall prevalence of SBO was 15.1% (160 of 1,061): 18.3% (86 of 471) in men and 12.5% (74 of 590) in women. Among these subjects, 13.7% (145 of 1,061) had OAB: 13.2% (62 of 471) in men and 14.1% (83 of 590) in women. The results of logistic regression showed that age, SBO, history of cerebral infarction (HCI), and constipation were risk factors for OAB (P<0.05), while sex, history of childhood enuresis (HCE), body mass index (BMI), and diabetes mellitus (DM) were not (P>0.05). In men, age, SBO, and constipation were risk factors for OAB (P<0.05), while HCE, BMI, DM, HCI, and benign prostate hyperplasia were not (P>0.05). In women, age, SBO, and HCI were risk factors for OAB (P<0.05), while HCE, BMI, DM, vaginal delivery, and constipation were not (P>0.05). Conclusions: The prevalence of SBO is high and it is related to OAB in middle-aged and elderly people in China.

The Action Research of Game Sense on Elementary School Soccer Team Training

Jun-Feng Zhong,Yuh-Chih Chen 한국스포츠교육학회 2011 한국스포츠교육학회 국제학술대회 자료집 Vol.2011 No.12

Synthesis and characterization of polysilane with double bonds by an electrochemical method

Feng-Jun Zhang,Ming-Liang Chen,Lai Chen,Shi Wu,오원춘 한양대학교 세라믹연구소 2008 Journal of Ceramic Processing Research Vol.9 No.6

Polysilanes with double bonds have been synthesized by the electroreduction of trichloromethylsilane and allyl chloride in a single compartment cell. The polymers have been characterized using FTIR, GPC and 1H NMR. The effects of monomer ratio, monomer concentration, electrode materials, the electrode’s interval time and the amount of electricity supplied were investigated. The results indicate that the ideal molar ratio of MeSiCl3/allyl chloride is 3:1 with a Mg electrode material. The molecular weight and yield of polysilanes became higher with an increase of the charge passed, a shortening of the electrode’s interval time, and a decrease of the monomer concentration.

Studies on the influence factors of wind dynamic responses on hyperbolic cooling tower shells

Jun-Feng Zhang,Qing-Shuai LIU,Yao-Jun Ge,Lin Zhao 국제구조공학회 2019 Structural Engineering and Mechanics, An Int'l Jou Vol.72 No.5

Wind induced dynamic responses on hyperbolic cooling tower (HCT) shells are complicated functions of structure and wind properties, such as the fundamental frequency fmin, damping ratio ζ, wind velocity V, correlationship in meridian direction and so on, but comprehensions on the sensitivities of the dynamic responses to these four factors are still limited and disagree from each other. Following the dynamic calculation in time domain, features of dynamic effects were elaborated, focusing on the background and resonant components σB and σR, and their contributions to the total rms value σT. The σR is always less than σB when only the maximum σT along latitude is concerned and the contribution of σR to σT varies with responses and locations, but the σR couldn’t be neglected for structural design. Then, parameters of the above four factors were artificially adjusted respectively and their influences on the gust responses were illustrated. The relationships of σR and the former three factors were expressed by fitted equations which shows certain differences from the existing equations. Moreover, a new strategy for wind tunnel tests aiming at surface pressures and the following dynamic calculations, which demands less experiment equipment, was proposed according to the influence from meridian correlationship.