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기포부상분리법에 의한 Cu(Ⅱ)의 제거에 있어서 유동특성에 관한 연구
김현수,박주량,이승무 연세대학교 산업기술연구소 1985 논문집 Vol.17 No.1
This investigation was carried out to study the dynamic characteristics of the removal of Cu(II) from wastewater by the technique of foam fractionation, using sodium-dodecylbenzenesulfornate (DBS) as a foaming agent. The surface excess concentration of Cu(II) with the change of DBS concentration in feed solution and superficial gas velocity was obtained by measuring foam diameter. The value of HTU with the change of DBS concentration and superficial gas velocity was determing by measuring superficial liquid velocity. The experimental results are obtained as follows: 1. When Cu(II) concentration in feed solution is constant, the surface excess concentration of Cu(II) increased as DBS concentration increased. But decreased as superficial gas velocity increased. 2. Equilibrium constant (Tcu/Cw) between the surface excess concentration of foam and the concentration of interstitial liquid increased as DBS concentration in feed solution increased. However it was not affected by the change of superficial gas velocity. 3. For the superficial gas velocity above 10cm/min, the empirical equation was derived as follows: HTU = 2 exp [0.642(??) - 0.19(??)] where, C??(DBS) denotes the DBS concentration in feed solution, and v is the superficial gas velocity.