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Yun Zhao,Jiangquan Ma,Kun Chen,Chuandong Zhang,Chao Yao,Shixiang Zuo,Yong Kong 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2017 NANO Vol.12 No.5
Graphene-based polyaniline (PANI/RGO), used as conductive filler, was synthesized through a new one-pot emulsion polymerization technology. Graphene dispersion (RGO) was obtained by ultrasonically reducing graphene oxide (GO) in a hot sodium hydroxide solution in the absence of any toxic reductant, such as hydrazine hydrate. Sodium dodecyl benzene sulfonate (SDBS), in which RGO sheets were dispersed, was synthesized using dodecyl benzenesulfonic acid (DBSA) and NaOH. In this RGO/SDBS mixture, polyaniline (PANI), doped with multiple acids (HClDBSA), was then uniformly polymerized on the surface of the RGO sheets. The experimental results showed that this reaction improved the dispersion of the RGO in the PANI system, and increased the homogeneous distribution of the formed PANI particles on the RGO surface. The synthesized composite material (PANI/RGO) had good thermal stability, electrical conductivity (about 11.71 S · cm -1) and water dispersibility. Based on its excellent properties, the PANI/RGO was combined with waterborne epoxy resin to prepare anticorrosion coatings. The corrosion resistance of these coatings was studied using Tafel plots, along with other critical properties tested by the national standards. The results suggested that the surface resistivity of the coatings could be as high as 2.48 X 10 8 Ω with the addition around 3 wt.% of the PANI/RGO meeting good antistatic standards. In addition, the antistatic coatings had outstanding corrosion resistance, as well as tremendous physical and chemical properties.
Yongwei Yu,Qing Yang,Jiangquan Ma,Wenliang Sun,Chong Yin,Xiazhang Li,Jun Guo,Qingyan Jiang,Zhiyuan Lu 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.11
A novel strontium titanate/binary metal sulfide (SrTiO3/SnCoS4) heterostructure was synthesized by a simple two-step hydrothermal method. The visible-light-driven photocatalytic performance of SrTiO3/SnCoS4 composites was evaluated in the degradation of methyl orange (MO) under visible light irradiation. The photocatalytic performance of SrTiO3/SnCoS4-5% is much higher than that of pure SrTiO3, SnCoS4, SrTiO3/SnS2 and SrTiO3/CoS2. The SrTiO3/SnCoS4 composite material with 5 wt.% of SnCoS4 showed the highest photocatalytic efficiency for MO degradation, and the degradation rate could reach 95% after 140 min irradiation time. The enhanced photocatalytic activity was ascribed to not only the improvement of visible light absorption efficiency, but also the construction of a heterostructure which make it possible to effectively separate photoexcited electrons and holes in the two-phase interface.
Xingwang Zhou,Jun Yao,Ming Yang,Jiangquan Ma,Qingwei Zhou,Ershen Ou,Zhen Zhang,Xueni Sun 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.4
In this research, a series of novel MoSe2/SrTiO3 heterostructures were successfully prepared by a two-step hydrothermal method. The samples were characterized by XRD, UV-Vis, SEM, TEM, EDS and XPS. Results showed that the degradation of MO under UV is better than that under the visible light. And, MoSe2 loaded on SrTiO3 under UV irradiation demonstrated a higher catalytic activity. The degradation rate of methyl orange was 99.46% for MoSe2/SrTiO3 under the optimum loading weight (0.1 wt.%). This is mainly because the combination of MoSe2 and SrTiO3 prevents electrons and holes recombination in SrTiO3 and · O2 - appears in the system. In general, MoSe2/SrTiO3 heterostructures have good environmental friendliness for photocatalytic degradation.
Xingwang Zhou,Jia Zhou,Yongwei Yu,Jiangquan Ma,Xueni Sun,Lanmei Hu 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2017 NANO Vol.12 No.10
In this research, a series of catalysts based on MoSe2 were synthesized by the hydrothermal method and used for the catalytic hydrogenation of alkali lignin for the first time. For 4 wt.% NiSe2/MoSe2 catalyst, at 290 ℃, under 2MPa H2 pressure for 1.5 h, the conversion of alkali lignin and the yield of bio-oil reached 96.47% and 93.68%, respectively. In addition, the composition of the product (bio-oil) was analyzed via Fourier transform infrared (FTIR) spectrometry, gas chromatography-mass spectrometry (GC-MS) spectra, and proton nuclear magnetic resonance (1HNMR) spectra. Finally, our study demonstrated that those MoSe2-based composite catalysts can effectively degrade the biomass into bio-oil containing valuable chemical products.
Chaochen Ma,Jianbing Gao,Shikai Xing,Liwei Sun,Jiangquan Liu 한국화학공학회 2016 Korean Journal of Chemical Engineering Vol.33 No.12
Non-road diesel engines are important polycyclic aromatic hydrocarbon (PAH) sources in the environment due to their high emission concentration compared to on-road diesel engines. Particle- and gas-phase PAH concentrations of a non-road diesel engine were investigated. Non-thermal plasma (NTP) as an effective after-treatment technology was used to reduce PAH emissions. The results showed that particle-phase PAH concentrations were 329.7 μg/m3, 3,206.7 μg/m3, and 1,185.7 μg/m3 without the action of NTP at three different engine loads respectively. Relatively low concentrations were measured for gas-phase PAHs. Excellent linearity was shown for particle-phase with total PAH concentrations both with, and without, NTP. The gas-phase PAH concentrations linearly increased with engine load without NTP. The five most abundant compounds of PAHs were among low molecular weight (LMW) and medium molecular weight (MMW) compounds. Total PAH cleaning efficiency was beyond 50% when treated with NTP at the three different engine loads. We hypothesized that naphthalene (Nap) concentrations increased greatly at 60% and 80% engine loads because it was produced within the plasma zone by decomposition of high molecular weight (HMW) PAHs. The PAHs content of particulate matter (PM) aggregation at 60% load was approximately three times higher than at 40% and 80% loads. High correlation values were observed for MMW PAHs with total PAH concentrations. Correlations of PAH concentration reduction could be important to clarify the PAH reduction mechanism with NTP technology.