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Hai Yang,Zhishuo Zheng,Jian Zeng,Huajie Liu,Bing Yi 대한화학회 2012 Bulletin of the Korean Chemical Society Vol.33 No.8
A series of functionalized furans were synthesized by way of a palladium -catalyzed coupling reaction of 2,3,5- trisubstituted furans with aryl chlorides through C-H bond cleavages at C-4 position. The feature of the reaction was facilitative preparation of furan derivatives with good functional group tolerance. All reactions gave the desired products in moderate to good yields in the presences of BuAd2P and t-BuOK in DMF at 120 oC after 15 h.
Hydrochlorination of acetylene to vinyl chloride monomer over bimetallic Au–La/SAC catalysts
Haiyang Zhang,Xugen Wang,Longlong Xu,Mingyuan Zhu,Bin Dai 한국공업화학회 2012 Journal of Industrial and Engineering Chemistry Vol.18 No.1
Gold and gold-based bimetallic catalysts for acetylene hydrochlorination were prepared with HAuCl44H2O and LaCl37H2O as precursors and analyzed by the characterization methods of BET,XRD, SEM, TG and ICP-AES. The results indicate that pitch-based spherical activated carbon SAC is the optimal carrier; Au/C catalyst deactivates easily for coke deposition and the valence change of Au in the reaction, the addition of lanthanum to gold can weaken the occurrence of coke deposition and inhibit the valence change of gold to improve the stability of the catalyst; Under the reaction conditions of temperature 423 K, C2H2 hourly space velocity (GHSV) 360 h1, feed volume ratio V (HCl)/V (C2H2) = 1.15and Au loading of 1 wt%, the optimal atomic ratio of Au, La (a/a) was 1:3, the conversion of acetylene was up to 98% and the selectivity to VCM was more than 99.8%.
Filamin A is required for Spindle Migration and Asymmetric Division in Mouse Oocytes
HaiYang Wang,Suk Namgoong,Jeong Su Oh,Nam-Hyung Kim 한국동물생명공학회(구 한국동물번식학회) 2017 Reproductive & Developmental Biology(Supplement) Vol.41 No.2
Dynamic changes in the actin network are crucial for the cortical migration of spindle and establishment of polarity to ensure asymmetric division during meiotic maturation. Here, we show that Filamin A (FLNA) is an essential actin regulator that controls spindle migration and asymmetric division during oocyte meiosis. FLNA was localized in the cytoplasm and enriched at the cortex and near the chromosomes. Knockdown of FLNA impaired meiotic asymmetric division and spindle migration with a decrease in the amount of cytoplasmic actin mesh and cortical actin levels. Moreover, FLNA knockdown reduced the phosphorylation of Cofilin and Rho kinase (ROCK) near the spindle. Similar phenotypes such as decreased filament actin levels, impaired spindle migration and polar body extrusion were observed when active Cofilin (S3A) was overexpressed or ROCK was inhibited. Notably, we found that FLNA and ROCK interacted directly in mouse oocytes. Taken together, our results show that FLNA plays crucial roles in asymmetric division during meiotic maturation by regulating ROCK-Cofilin-mediated actin reorganization.
Haiyang Yu,Shangbin Yang,Haotao Li,Rongjie Wu,Biqin Lai,Qiujian Zheng 대한척추신경외과학회 2023 Neurospine Vol.20 No.1
After spinal cord injury (SCI), endogenous neural stem cells are activated and migrate to the injury site where they differentiate into astrocytes, but they rarely differentiate into neurons. It is difficult for brain-derived information to be transmitted through the injury site after SCI because of the lack of neurons that can relay neural information through the injury site, and the functional recovery of adult mammals is difficult to achieve. The development of bioactive materials, tissue engineering, stem cell therapy, and physiotherapy has provided new strategies for the treatment of SCI and shown broad application prospects, such as promoting endogenous neurogenesis after SCI. In this review, we focus on novel approaches including tissue engineering, stem cell technology, and physiotherapy to promote endogenous neurogenesis and their therapeutic effects on SCI. Moreover, we explore the mechanisms and challenges of endogenous neurogenesis for the repair of SCI.
Study on Preparation and Properties of PAI Materials Containing Trifluoromethyl in Side Chain
Haiyang Yang,Duxin Li,Jun Yang,Jin Wang,Shunchang Gan,Kaikai Cao,Yufeng Liu 한국고분자학회 2021 Macromolecular Research Vol.29 No.10
Polyamide-imide (PAI) materials with good heat resistance, excellent friction, wear properties, and low water absorption were prepared by acyl chloride process with diamine monomer containing trifluoromethyl in the side chain. The results showed that PAI prepared from 2,2'-bis(trifluoromethyl)-[1,1'-biphenyl]- 4,4'-diamine without flexible hinge group had the best heat resistance, with T g as high as 302.6℃ and T d5% as 490.1℃. With the increase of the proportion of flexible hinge groups in diamine monomer, the thermal properties of PAI materials would decrease. The wear mechanism of PAI prepared from 2,2'-bis(trifluoromethyl)- [1,1'-biphenyl]-4,4'-diamine was mainly adhesive wear. With the increase of the proportion of flexible hinge groups in diamine monomer, the wear mechanism would change from abrasive wear, slight adhesive wear to severe adhesive wear. The friction coefficient and wear loss of PAI prepared by 1,4-bis(4-amino-2-trifluoromethylphenoxy) benzene were the smallest, which were 0.4706 and 3.5, respectively. PAI synthesized by diamine monomer containing trifluoromethyl had low water absorption and high water contact angle. With the increasing flexibility of monomer containing trifluoromethyl diamine, the elongation at break and tensile strength of the material increased gradually.
Autopilots for Small Unmanned Aerial Vehicles: A Survey
HaiYang Chao,YongCan Cao,YangQuan Chen 제어·로봇·시스템학회 2010 International Journal of Control, Automation, and Vol.8 No.1
UAV users. The UAV flight control basics are introduced first. The radio control system and autopilot control system are then explained from both the hardware and software viewpoints. Several typical off-the-shelf autopilot packages are compared in terms of sensor packages, observation approaches and controller strengths. Afterwards some open source autopilot systems are introduced. Conclusion is made with a summary of the current autopilot market and a remark on the future development.
Semi-quantum Key Distribution Protocol Based on Bell States
Haiyang Yu,Yongquan Cai,Shanshan Kong,Fei Xue,Ditta Allah 보안공학연구지원센터 2016 International Journal of Security and Its Applicat Vol.10 No.12
A quantum key distribution protocol with traditional Bob has been proposed recently by Boyer et al. using single-particle state. In this paper, a semi-quantum key distribution protocol is described, in which Einstein-Podolsky-Rosen (EPR) pairs of particles are utilized to generate a secret key in remote places. This extends the quantum key distribution protocol with traditional Bob where the single-qubit channel is replaced by the entangled EPR-pair channel. And quantum Alice is able to do any quantum operations, preparing quantum states and performing quantum measurement, but traditional Bob is not able to prepare and measure a particle in the computational basis, reflect the particles. Furthermore, entanglement states are used in our protocol. The analysis shows that our protocol is secure, which can avoid the beam splitter attack automatically, and the proposed protocol is more efficient than Boyer’s scheme.
( Haiyang Wang ),( Xiaojing Zhao ),( Xiufang Cui ),( Meifeng Wang ),( Chunhua Jiao ),( Jiajia Li ),( Yan Yang ),( Yi Li ),( Hongjie Zhang ) 대한소화기기능성질환·운동학회 2021 Journal of Neurogastroenterology and Motility (JNM Vol.27 No.4
Background/Aims Some inflammatory bowel disease (IBD) patients in remission suffer from irritable bowel syndrome (IBS)-like symptoms (IBD-IBS). The pathogenesis has not yet been elucidated. The study aim is to evaluate relationships among quality of life (QOL), psychological status, and visceral sensitivity, and explore the formation mechanism of IBD-IBS. Methods Forty-seven patients with Crohn’s disease in remission, 24 ulcerative colitis in remission, 26 IBS, and 20 healthy controls were included in the study. The abdominal pain, QOL, anxiety, and depression were evaluated through questionnaires. Visceral sensitivity was measured by rectal balloon distension. The serum levels of 5-hydroxytryptamine (5-HT) and nerve growth factor (NGF) were measured by enzyme-linked immunosorbent assay. The expressions of tryptase, 5-HT, NGF, and related receptors in colonic tissues were detected by immunohistochemistry and western blot. Results Prevalence of IBS-like symptoms in Crohn’s disease and ulcerative colitis patients in clinical remission was 29.8% and 50.0%, respectively. The QOL was lower, the anxiety/depression scores were higher in IBD-IBS patients than those without IBS-like symptoms. Additionally, patients with IBD-IBS existed visceral hypersensitivity. Besides, abdominal pain was associated with poor QOL, visceral hypersensitivity, anxiety, and depression in IBD-IBS patients. The number of mast cells (MCs) and expressions of 5-HT, NGF, and related receptors were higher in IBD-IBS patients than those with no such symptoms. The serum levels of 5-HT and NGF positively correlated with abdominal pain and visceral hypersensitivity. Conclusion IBD-IBS patients may have low QOL and psychological abnormalities, as wells as visceral hypersensitivity which may be related to increased 5-HT and NGF levels released from activated mast cells. (J Neurogastroenterol Motil 2021;27:612-625)