Solvent‑free Pechmann synthesis of coumarins catalyzed by magnetic heterogeneous catalyst Fe3O4@ rGO‑NH

Esmail Rezaei‑Seresht,Fatemeh Tafazzoli Gazkoh,Behrooz Maleki 한국탄소학회 2023 Carbon Letters Vol.33 No.1

This work describes the synthesis and characterization of a heterogeneous catalyst consisting of piperazine-functionalized reduced graphene oxide decorated with Fe3O4 nanoparticles ( Fe3O4@rGO-NH), and the study of its catalytic activity as a magnetic heterogeneous catalyst for the Pechmann synthesis of coumarins. Catalyst Fe3O4@ rGO-NH was fully characterized by various techniques, including IR, XRD, TEM, VSM, TGA, and elemental analysis. Then, the catalyst was used as an efficient and easy-separable heterogeneous catalyst for the solvent-free synthesis of some coumarins by Pechmann reaction. The reaction was optimized in terms of reaction time and temperature, catalyst dosage, and the presence/absence of the solvent. Finally, the reusability of the catalyst was studied.

A novel analytical approach for advection diffusion equation for radionuclide release from an area source

Esmail, S.,Agrawal, P.,Aly, Shaban Korean Nuclear Society 2020 Nuclear Engineering and Technology Vol.52 No.4

The method of the Laplace transform has been used to obtain an analytical solution of the three-dimensional steady state advection diffusion equation for the airborne radionuclide release from any nuclear installation such as the power reactor in an area source. The present treatment takes into account the removal of the pollutants through the nuclear reaction. We assume that the pollutants are emitted as a constant rate from the area source. This physical consideration is achieved by assuming that the vertical eddy diffusivity coefficient should be a constant. The prevailing wind speed is a constant in 𝑥- direction and a linear function of the vertical height z. The present model calculations are compared with the other models and the available data of the atmospheric dispersion experiments that were carried out in the nuclear power plant of Angra dos Reis (Brazil). The results show that the present treatment performs well as the analytical dispersion model and there is a good agreement between the values computed by our model and the observed data.

Study on CO₂ Removal from Natural Gas Using a Supersonic Separator

Esmail Lakzian,Mahshid Mirzaie,Heuy Dong Kim 대한기계학회 2023 대한기계학회 춘추학술대회 Vol.2023 No.5

Performance of Heron Turbine with Various Blockage Effects

Esmail Lakzian,Shima Yazdani,Hossein Khabbazi,Kitae Kim,Heuy Dong Kim 대한기계학회 2023 대한기계학회 춘추학술대회 Vol.2023 No.5

Improved Region-Based TCTL Model Checking of Time Petri Nets

Mohammad Esmail Esmaili,Reza Entezari-Maleki,Ali Movaghar 한국정보과학회 2015 Journal of Computing Science and Engineering Vol.9 No.1

The most important challenge in the region-based abstraction method as an approach to compute the state space of time Petri Nets (TPNs) for model checking is that the method results in a huge number of regions, causing a state explosion problem. Thus, region-based abstraction methods are not appropriate for use in developing practical tools. To address this limitation, this paper applies a modification to the basic region abstraction method to be used specially for computing the state space of TPN models, so that the number of regions becomes smaller than that of the situations in which the current methods are applied. The proposed approach is based on the special features of TPN that helps us to construct suitable and small region graphs that preserve the time properties of TPN. To achieve this, we use TPN-TCTL as a timed extension of CTL for specifying a subset of properties in TPN models. Then, for model checking TPN-TCTL properties on TPN models, CTL model checking is used on TPN models by translating TPN-TCTL to the equivalent CTL. Finally, we compare our proposed method with the current region-based abstraction methods proposed for TPN models in terms of the size of the resulting region graph.

Template-oriented synthesis of hydroxyapatite nanoplates for 3D bone printing

Doustkhah, Esmail,Najafi Zare, Reza,Yamauchi, Yusuke,Taheri-Kafrani, Asghar,Mohtasham, Hamed,Esmat, Mohamed,Ide, Yusuke,Fukata, Naoki,Rostamnia, Sadegh,Sadeghi, Morteza H.,Assadi, M. Hussein N. Royal Society of Chemistry 2019 Journal of Materials Chemistry B Vol. No.

<P>The design of hydroxyapatite (HA) nanoarchitecture is critical for fabricating artificial bone tissues as it dictates the biochemical and the mechanical properties of the final product. Herein, we incorporated a simple hard-template approach to synthesise single crystal nanoplates of HA. We used the 2D graphitic nitride (g-C3N4) material to prepare an HA sol-gel under hydrothermal conditions. A new HA nanostructure was then formed during the calcination and removal of g-C3N4 at a higher temperature, which finally led to the production of nanoplates (thickness of ∼100 nm) while in lateral dimension the average size was in the micrometre scale. We characterised the synthesised HA nanoplates with XRD, TEM, and HRTEM. The theoretically predicted nanostructure construction based on Wulff's method is in full agreement with the experimental observations. We then prepared different weight ratios of HA and polylactic acid (PLA) composites for artificial 3D bone fabrication. The strong interaction between PLA and HA's (110) facet, which was the second most prevalent, resulted in the composite's mechanical robustness. After mechanical testing, an optimum ratio was selected for biological studies and 3D printing. Biological experiments demonstrated that the synthesised composite had excellent viability <I>in vitro</I>.</P>

Effects of supplementation cysteine-coated Fe₃O₄ nanoparticles compared to FeSO₄, on reproductive performance in male quail

Abdolvand, Esmail,Farzinpour, Amjad,Vaziry, Asaad Techno-Press 2020 Advances in nano research Vol.9 No.1

Iron has a crucial role in growth as part of metalo-proteins like haemoglobin or myoglobin, enzymes; they are also involved in energetic reactions. Iron plays a vital role in fertility. At high doses, Iron has a harmful consequence on the reproductive system, which can be strongly reflected the final stage of spermatogenesis. Nutritional products are claiming to use nanotechnology and it is important to recognize the potential toxicity of nano-sized nutrients. Recently iron nanoparticles were proposed as a food additive for poultry. The objective of this study was to investigate the effects of L-cystein coated iron oxide nanoparticles on reproductive performance in male quails. The results of Fourier Transform Infrared Spectrometer, Alternating Gradient Force Magnetometer and Scaning Electron Microscopy showed that iron oxide nanoparticles was produced and have been coated with L-cycstein (Fe₃O₄-Cys NPs). A total of 100 one-week-old quail chicks were randomly placed to five groups of five replicates. Four quails (two male and two females) were raised in an individual cage for each replicate. The five experimental treatment diets consisted; negative control diet, with no Iron supplementation; positive control diet supplemented with 60 mg/kg of Fe₃O₄; treatment diets supplemented with 0.6, 6 and 60 mg/kg of L-cystein coated iron oxide nanoparticles. The hemoglobin, Red blood cell, mean corpuscular volume, mean corpuscular hemoglobin, mean corpuscular hemoglobin concentration, gonadal somatic index, daily sperm production, total testicular sperm and sperm viability of the male quails that were fed with diet supplemented by 0.6 mg/kg of Fe₃O₄-Cys NPs were improved as compare with negative control. This study showed that not only the use of the Fe₃O₄-Cys nanoparticles had no side effects but also it can be used as a feed additive to improve the reproductive performance in male quails.

Analysis of the Influence of Electrical Discharge Machining Parameters on Surface Roughness of CK45

Abedi, Esmail,Daneshmand, Saeed,Karimi, Iman,Neyestanak, A. A. Lotfi The Korean Electrochemical Society 2015 Journal of electrochemical science and technology Vol.6 No.4

Electrical discharge machining is an unconventional machining process in which successive sparks applied to machine the electrically conductive materials. Any changes in electrical discharge machining parameters lead to the pieces with distinct surface roughness. The electrical discharge machining process is well applied for high hardness materials or when it is difficult to use traditional techniques to do material removing. Furthermore, this method is widely applied in industries such as aerospace, automobile, molding, and tool making. CK45 is one of the important steels in industrial and electrical discharge machining can be considered as a proper way for its machining because of high hardness of CK45 after thermal operation of the electrical discharge machining process. Optimization of surface roughness as an output parameters as well as electrical discharge machining parameters including current, voltage and frequency for electrical discharge machining of CK45 has been studied using copper tools and kerosene as the dielectric. For such a purpose and to achieve the precise statistical analysis of the experiment results design of experiment was applied while non linear regression method was chosen to assess the response of surface roughness. Then, the results were analyzed by means of ANOVA method and machining parameters with more effects on the desired outputs were determined. Finally, mathematical model obtained for surface roughness.

Could the Breast Prognostic Biomarker Status Change During Disease Progression? An Immunohistochemical Comparison between Primary Tumors and Synchronous Nodal Metastasis

El Nemr Esmail, Reham Shehab,El Farouk Abdel-Salam, Lubna Omer,Abd El Ellah, Mohammed M Asian Pacific Journal of Cancer Prevention 2015 Asian Pacific journal of cancer prevention Vol.16 No.10

Background: Prognostic biomarkers in breast cancer are routinely investigated in the primary tumors to guide further management. However, it is proposed that the expression may change during the disease progression, and may result in a different immune profile in the metastatic nodes. This work aimed to investigate the expression of breast prognostic biomarkers in primary tumors and in its axillary nodal metastasis, to estimate the possible discordant expression. Materials and Methods: 60 paired primary and axillary nodal metastasis samples were collected from patients with primary breast cancer with positive nodal deposits, diagnosed at the Maadi Military Hospital, Cairo, Egypt, during the year 2013. ER, PR and HER2 expression was assessed by immunohistochemistry in all samples Results: 48.3% of the included cases showed concordant results for both ER and PR receptors between the primary tumor and its nodal metastasis while 51.7% showed discordant results and the discordance level was statistically significant. On the other hand, 70% of the cases showed concordant Her2 results between the primary tumors and the nodal deposits, 30% showed discordant results and the difference was significant. Conclusions: The study indicated that the discordance in ER and PR receptor expression between the primary breast tumor and their nodal metastasis may be significant. The possible switch in the biomarker status during the disease progression is worth noting and may change the patient therapeutic planning. So, whether the treatment selection should be based on biomarkers in the lymph node is a topic for further studies and future clinical trials.

Improved Region-Based TCTL Model Checking of Time Petri Nets

Esmaili, Mohammad Esmail,Entezari-Maleki, Reza,Movaghar, Ali Korean Institute of Information Scientists and Eng 2015 Journal of Computing Science and Engineering Vol.9 No.1

The most important challenge in the region-based abstraction method as an approach to compute the state space of time Petri Nets (TPNs) for model checking is that the method results in a huge number of regions, causing a state explosion problem. Thus, region-based abstraction methods are not appropriate for use in developing practical tools. To address this limitation, this paper applies a modification to the basic region abstraction method to be used specially for computing the state space of TPN models, so that the number of regions becomes smaller than that of the situations in which the current methods are applied. The proposed approach is based on the special features of TPN that helps us to construct suitable and small region graphs that preserve the time properties of TPN. To achieve this, we use TPN-TCTL as a timed extension of CTL for specifying a subset of properties in TPN models. Then, for model checking TPN-TCTL properties on TPN models, CTL model checking is used on TPN models by translating TPN-TCTL to the equivalent CTL. Finally, we compare our proposed method with the current region-based abstraction methods proposed for TPN models in terms of the size of the resulting region graph.