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사고 누출 화학물질 중 강산의 생산, 사용 현황 및 사고 사례 분석
신도연,문희선,윤윤열,윤욱,이윤호,하규철,현성필,Shin, Doyun,Moon, Hee Sun,Yoon, Yoon Yeol,Yun, Uk,Lee, Yunho,Ha, Kyoochul,Hyun, Sung Pil 한국지하수토양환경학회 2014 지하수토양환경 Vol.19 No.6
We reviewed literature focusing on the amounts of domestic production, distribution, and consumption of strong acids and their spill cases. In particular, we investigated the chemistry and toxicity of four strong acids classified as "accident preparedness substances," including hydrochloric, nitric, sulfuric, and hydrofluoric acid. We recommend sulfuric and hydrofluoric acid as the chemicals of priority control based on the amounts used and toxicity. An advanced prevention/response system needs to be established along with an improved human and social infrastructure to prevent and efficiently respond to chemical accidents. Understanding the behavior and transport of spilled strong acids in the soil and groundwater environments requires a multi-disciplinary approach since they go through a variety of chemical and biogeochemical reactions with complex geomedia. However, no such research has been done in this area in Korea to the best of our knowledge. We expect the results of this study to contribute as basic data to future research.
박정현,신도연,박현식,정진기,이재천,Park, Jeonghyun,Shin, Doyun,Park, Hyunsik,Jeong, Jinki,Lee, Jae-chun 한국자원리싸이클링학회 2015 資源 리싸이클링 Vol.24 No.4
전세계적으로 시안화법은 일차 광물 혹은 정광으로부터 금을 회수하기 위해 널리 사용되어 왔다. 그러나 이 공정에서 발생하는 다량의 유독한 잔사 및 시안 함유 폐액은 주변 환경 및 생태계에 심각한 문제를 야기할 수 있어 그 사용에 대해 문제가 제기되어 왔으므로 시안화법 이용 시 반드시 시안 함유 폐액의 적절한 처리가 필요하다. 본 연구에서는 금광으로부터 금을 회수하기 위한 습식제련공정인 시안화법과 연계하여 시안 처리 공정을 설계하기 위한 기초연구로서 금 제련에 사용되는 시안화합물의 사용, 규제 및 처리 기술의 국내외 현황을 분석하였다. 또한 무배출 금 회수 및 처리 공정을 설계하기 위한 생물학적 공정에 대하여 소개하였다. Cyanidation has been used worldwide to recover gold from primary ore or concentrate. The use of cyanide is however becoming an emerging issue because of the toxic residue and wastewater made from the process. The cyanide-containing wastewater should be treated properly, obeying the environmental standard and regulations. In the present article, the domestic and international uses, regulations, and treatment technologies of cyanide in gold mining were investigated as a feasibility study to develop a cyanide treatment process as well as the cyanidation process. A biological cyanide treatment process to develop a zeroemission gold recovery and wastewater treatment process was also briefly introduced.
토양 경작법을 이용한 유류오염토양 정화사업 타당성 연구
조은혜,류혜림,신도연,김영진,최용주,남경필,Jho, Eun Hea,Ryu, Hyerim,Shin, Doyun,Kim, Young-Jin,Choi, Yong Ju,Nam, Kyoungphile 한국지하수토양환경학회 2013 지하수토양환경 Vol.18 No.2
The landfarming treatment for the remediation of the petroleum contaminated soil at the returned U.S. Military bases was investigated in this study. Specifically, the bioaugmentation performance using various commercially available petroleum-degrading bacteria was evaluated and the directions for enhancing the performance of the landfarming treatment were suggested. The environmental factors of the soils at the returned U.S. Military bases chosen for remediation indicate that the landfarming treatment can be used as the remediation technique; however, the addition of nitrogen or phosphorus is required. The lab-scale landfarming treatment tests using the model soil and the site soil showed that the degradation efficiency was greater with the model soil than the site soil and that the treatment performance was not affected by the number of bacteria present in the soil in the range of $10^6-10^{12}$ CFU/g. These results suggest that the successful landfarming treatment depends on the petroleum degradability of bacteria used and the environmental conditions during the treatment rather than the number of petroleum-degrading bacteria used.
Physico-chemical 분리 공정에 의한 폐동슬래그로부터 철의 품위향상
이광석,조슬기,신도연,정수복,이재천,김병수,Lee, Kwang-Seok,Jo, Seul-Ki,Shin, Doyun,Jeong, Soo-Bock,Lee, Jae-Chun,Kim, Byung-Su 한국자원리싸이클링학회 2014 資源 리싸이클링 Vol.23 No.3
동정광으로 동을 제련하는 동제련소에서는 대략 35-45%정도 철을 함유한 폐동슬래그가 다량 배출되어 대부분 폐기처분되고 있다. 따라서 폐동슬래그로부터 철을 회수하여 철을 자원화하는 것은 자원의 효율적인 활용측면과 환경문제를 감소하는 측면에서 관심이 크게 증대되고 있다. 본 연구에서는 동제련소에서 발생되는 다량의 철 성분이 포함된 폐동슬래그로부터 철의 품위향상을 위한 physico-chemical 분리 공정이 개발되었다. 개발된 공정은 먼저 폐동슬래그를 1 mm이하로 파쇄하는 공정(1차 파쇄공정)과, 이어서 $1225^{\circ}C$에서 90분 동안 탄소 환원하는 공정(탄소 환원공정), 그리고 환원된 슬래그로부터 $104{\mu}m$ 이하로 2차 파 분쇄하는 공정(2차 파쇄공정)과, 이어서 철 농축물을 분리 회수하는 습식자력선별 공정(습식 자력선별공정)으로 구성된다. 개발된 공정을 이용하여 환원된 폐동슬래그를 0.2 T의 자력세기에서 습식자력선별 함으로써 철 품위가 66 wt.%인 철 농축물을 얻었고, 같은 조건에서 철 회수율은 72%이었다. 따라서 분리 회수된 철 농축물은 철 원료로 사용될 수 있을 것으로 판단된다. A large amount of waste copper slag containing about 35 ~ 45% iron has been generated and discarded every year from pyrometallurgical processes for producing copper from copper concentrate. Thus, recovery of iron from the waste copper slag is of great interest for comprehensive use of mineral resource and reduction of environment problems. In this study, a physico-chemical separation process for upgrading iron from the waste copper slag discharged as an industrial waste has been developed. The process first crushes the waste copper slag below 1 mm (first crushing step), followed by carbon reduction at $1225^{\circ}C$ for 90 min (carbon reduction step). And then, resulting material is again crushed to $-104{\mu}m$ (second crushing step), followed by wet magnetic separation (wet magnetic separation step). Using the developed process, a magnetic product containing more than 66 wt.% iron was obtained from the magnetic separation under a magnetic field strength of 0.2 T for the waste copper slag treated by the reduction reaction. At the same conditions, the percentage recovery of iron was over 72%. The iron rich magnetic product obtained should be used as a iron resource for making pig iron.
잔류 불산에 의한 모델 지질토양시료의 광물 용해 및 비소 용출 특성
전필용,문희선,신도연,현성필,Jeon, Pilyong,Moon, Hee Sun,Shin, Doyun,Hyun, Sung Pil 한국지하수토양환경학회 2018 지하수토양환경 Vol.23 No.2
This study explored secondary effects of the residual hydrofluoric acid (HF) after a hypothetical acid spill accident by investigating the long-term dissolution of minerals and leaching of pre-existing arsenic (As) from two soil samples (i.e., KBS and KBM) through batch and column experiments. An increase in the HF concentration in both soil samples resulted in a dramatic increase in the release of major cations, especially Si. However, the amounts of mineral dissolved were dependent on the soil type and mineral characteristics. Compared to the KBM soil, relatively more Ca, Mg and Si were dissolved from the KBS soil. The column experiment showed that the long-term dissolution rates of the minerals are closely associated with the acid buffering capacity of the two soils. The KBM soil had relatively higher effluent pH values compared to the KBS soil. Also, more As was leached from the KBM soil, with a more amorphous hydrous oxide-bound As fraction. These results suggest that the potential of heavy metal leaching by the residual acid after an acid spill will be influenced by heavy metal speciation and mineral structure in the affected soil.