http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
기능성 Zeolite-KCIO₃ 복합체에 의한 Chlorothalonil의 분해
최충렬,박만,이동훈,이병묵,이인구,최정,김장억 한국환경농학회 2004 한국환경농학회지 Vol.23 No.2
Salt occlusion in zeolite is a unique phenomenon that takes place only when the salt size is similar to the window size of host zeolite. KClO₃-occluded zeolite, as an environment-friendly oxidant, has a high potential for effective removal of various organic pollutants. This study was carried to investigate the characteristics and the removal kinetics of fungicide chlorothalonil by zeolite-KClO₃ complex. About 10% of KClO₃ was occluded in zeolite pores synthesized by salt-thermal method from fly ash, although the occlusion amount was relatively less compared to that of nitrate salts. By occlusion with KClO₃, no remarkable changes were found in X-ray diffraction patterns of cancrinite, whereas some decrease of overall peak intensities was found with those of sodalite. Different releasing kinetics of ClO^(-)₃ ion were observed in distilled water and soil solution from zeolite-KClO₃ complex. Two reactions, hydration and diffusion, seem to be related with the release of KClO₃. Therefore, the release isotherm of ClO^(-)₃ ion well fitted to the power function model which indicate the release was made by hydration and diffusion. The removal of chlorothalonil by zeolite and KClO₃ reached at reaction equilibrium within 6 hours by 18% and 47%, respectively. However, the chlorothalonil removal by the zeolite-KClO₃ complex increased slowly and steadily up to 92% in 96 hours. These findings suggested that zeolite-KClO₃ complex could be applied for effective removal of organic contaminants in the soil and aqueous environment.
Mesoporous Titanium Oxo-Phosphate에 의한 살균제 Chlorothalonil의 광분해
최충렬,김병하,이병묵,최정,이인구,김장억 한국환경농학회 2003 한국환경농학회지 Vol.22 No.4
Mesoporous titanium oxo-phosphate(Ti-MCM)은 기존의 유기성 오염물질의 광분해제로 널리 이용되고 있는 TiO₂에 비해 표면적이 매우 넓은 장점이 있다. 그러므로 본 연구에서는 Ti-MCM에 의한 chlorothalonil의 흡착 및 광분해 특성을 TiO₂와 비교하였다. 합성된 Ti-MCM은 hexagonal 형태로 d-spacing이 4.1 ㎚이었다. 암조건에서 TiO₂에 의한 chlorothalonil의 흡착은 거의 일어나지 않았으나, Ti-MCM에 의한 흡착은 반응 1시간까지 28%로 급격히 증가하여 흡착평형에 도달하였다. UV조사 하에서 반응 9시간 후의 TiO₂와 Ti-MCM에 의한 chlorothalonil의 제거율은 각각 88%와 100%로 나타났다. 그러나 정치상태에서의 광분해 속도는 chlorothalonil과 Ti-MCM사이의 낮은 접촉에 의한 반응성의 감소로 느린 경향을 나타내었다. 또한 Ti-MCM에 의한 chlorothalonil의 분해효율은 용액의 초기 농도가 낮을수록, pH 7까지 반응용액의 pH가 높을수록 증가하였다. Titanium mesoporous materials have received increasing attention as a new photocatalyst in the field for photocatalytic degradation of organic compounds, The photocatalytic degradation of chlorothlonil by mesoporous titanium oxt-phosphate (Ti-MCM) was investigated in aqueous suspension for comparison with TiO₂ (Degussa, P25) using as an effective photocatalyst of organic pollutants. Mesoporous form of titanium phosphate has been prepared by reaction of sulfuric acid and titanium isopropoxide in the presence of n-hexadecy(trimethylammonium bromide. The XRD patterns of Ti-MCM are hexagonal phases with d-spacings of 4.1 nm. Its adsorption isotherm for chlorothalonil reached at reaction equilibrium within 60 min under dark condition with 28% degradation efficiency. The degradation ratio of chlorothalonil after 9 hours under the UV radiation condition (254 nm) exhibited 100% by TI-MCM and 88% by TiO₂. However, these degradation kinetics in static state showed a slow tendency compared to that of stirred state because of a low contact between titanium matrices and chlorothalonil. Also, degradation efficiency of chlorothalonil was increased with decreasing initial concentration and with increasing pH of solution. As results of this study, it was clear that mesoporous titanium oxo-phosphate with high surface area and crystallinity could be used to photocatalytic degradation of various organic pollutants.
이동훈,최충렬,김광섭,김평열,서정우,박만 경북대학교 농업과학기술연구소 2006 慶北大農學誌 Vol.24 No.-
군위군 오이재배지역을 정밀토양도를 이용하며 토양특성을 조사하구 군위군 노지 및 시설오이 재배지토양의 물리화학적 특성을 조사하여, 연작과 관행적인 토양관리로 인하여 저하된 토양의 이화학적 특성을 오이재배에 적합한 토양으로 개량하기 위한 기초자료로 이용하고자 토양조사를 실시하였다. 조사지역은 군위군 군위읍 외랑리 오이재배단지로서 주요토양통은 토양토에 나타난 단북통과 신정들이 가장 넓게 분포하였으며, 점토함량은 시설재배지내 토양의 경우 양토이었으며, 시설재배지의 외부 토양의 경우 23.8%로 높게 나타났다. 오이 재배지 토양의 화학적 특성 결과에 대한 오이재배지 토양의 적정범위와비교하여 보면 일반적인 화학적 성질에서 서는 유효인산의 함량이 적정범위보다 높은 것을 알 수 있으며, 치환성 양이온 함량은 시설재배지의 외부토양은 적정범위에 속하나 시설재배지 내부토양은 모두 높은 것으로 나타났으며, 최상부 토양은 매우 높으나 l0cm이하는 깊이에 따라 뚜렷한 차이는 없었다. 오이 재배지 토양 중 중금속 함량은 모두 기준치보다 높게 나타났는데, 구리의 함량이 시설재배지가 노지재배지보다 높게 나타났다. The soils of plastic film houses in which intensive cultivation takes place suffer from the serious problems such as severe salinity and accumulation of heavy metals etc. The objective of this research was to examine the change in soil properties with repeated cucumber cultivation under plastic film house at Gunwi-Gun area. The soils were classified mainly to Danbuk and SinJung series. Clay content is lower in the soils of plastic film house than in the field soil. Available P205 and exchangeable cations were accumulated at the level higher than the optimum range. The content of extractable heavy metals were higher in the soils of plastic film house than in those of the field. For optimum yield, much attention should be paied to the management of soils by the pre-soil survey.
최충식,주길재,이동훈,최충렬,이인구,최정 경북대학교 농업과학기술연구소 1999 慶北大農學誌 Vol.17 No.-
This study was conducted to evaluate the effects of microbial inoculation on sewage sludge composting. The number and species of microorganisms in sewage sludge sampled on February were higher than those sampled on August. The composting of sewage sludge is inhibited by the polyacrylamide cation, which was used as a coagulant and known to repress the growth of microorganisms. The growth of all microorganisms was inhibited by the addition of the polyacrylamide cation at a concentration of more than 0.8%. The species and viable counts of microorganisms were observed to increase during composting sewage sludge by inoculation of the effective microorganisms and addition of the pine tree sawdust as a bulking agent, compared with those without inoculation. A variety of organisms in compost(sewage sludge plus sawdust) were observed after composting for 30 days, such as Fragilaria sp., Proales sp., Vorticella sp., Schizothrix sp., Anabaena sp., Zoothaminium sp., Epstylis sp., Arcella sp., Balantidium sp., Actinophrys sp., Synedra sp., Euglypha sp., Ulothrix sp., Anacystis sp., and Clostium sp.