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Boron removal by means of chemical precipitation with calcium hydroxide and calcium borate formation
Alper Erdem Yilmaz,Recep Boncukcuoglu,Serkan Bayar,Baybars Ali Fil,Mehmet Muhtar Kocakerim 한국화학공학회 2012 Korean Journal of Chemical Engineering Vol.29 No.10
Boron removal was investigated by chemical precipitation from aqueous solutions containing boron using calcium hydroxide. pH, initial boron concentration, amount of Ca(OH)2, stirring speed and solution temperature were selected as operational parameters in a batch system. The highest boron removal efficiency was reached at pH 1.0. Increasing initial boron concentration and amount of calcium hydroxide raised to boron removal efficiency. Boron removal efficiency was highest at a stirring speed of 150 rpm. The most important parameter affecting boron removal efficiency was solution temperature. Increasing solution temperature increased importantly boron removal. XRD analysis showed that CaB3O3(OH)5·4H2O, which is a borate mineral called inyoite, occurred between Ca(OH)2 and borate ions. As a result of the obtained experimental data, when the optimum operational conditions were selected, over 96% of boron removal efficiency was reached by this method.
Adsorption of Ni(II) on ion exchange resin: Kinetics, equilibrium and thermodynamic studies
Baybars Ali Fil,Recep Boncukcuoglu,Alper Erdem Yilmaz,Serkan Bayar 한국화학공학회 2012 Korean Journal of Chemical Engineering Vol.29 No.9
This article describes the ion exchange of a heavy metal Ni(II) from aqueous solutions onto a Dowex HCR-S, cationic resin. Batch adsorption studies were conducted to evaluate the effect of various parameters such as pH, resin dose, stirring speed, temperature, contact time and initial Ni(II) concentration on the removal of Ni(II). Adsorption rate increased with the increase in initial nickel concentration, stirring speed and temperature. Equilibrium adsorption isotherms were measured for the single component system, and the experimental data were analyzed by using Langmuir, Freundlich, Elovich, Temkin, Khan, Sips, Toth, Koble-Corrigan and Radke-Prausnitz isotherm equations. The Sips equation appears to fit the equilibrium data. Different models were tested for their applicability. Adsorption kinetic data were modeled using the Lagergren pseudo-first-order, Ho’s pseudo-second-order and Elovich models. It was found that Ho’s pseudo-second-order model could be used for the prediction of the system’s kinetics. Thermodynamic activation parameters such as ΔG*, ΔS* and ΔH* of the adsorption of Ni(II) on Dowex HCR-S cationic resin were also calculated.