PbO-$Bi_2O_3-Ga_2O_3$ 유리내 $Nd_{3+}$와 $OH_-$ 사이의 에너지 전달 현상

최용규,허종,Choi, Yong-Gyu,Heo, Jong 한국세라믹학회 1996 한국세라믹학회지 Vol.33 No.8

희토류 첨가 광소재의 나노구조 : Dy 첨가 Ge-As-S 유리의 X-선 흡수 스펙트럼 분석

최용규,송재혁,신용범,허종,Choi, Yong-Gyu,Song, Jay-Hyok,Shin, Yong-Beom,Chernov, Vladimir A.,Heo, Jong 한국세라믹학회 2006 한국세라믹학회지 Vol.43 No.3

Dy $L_3$-edge XANES and EXAFS spectra of chalcogenide Ge-As-S glass doped with ca. 0.2 wt% dysprosium have been investigated along with some reference Dy-containing crystals. Amplitude of the white-line peak in XANES spectrum of the glass sample turns out to be stronger than that of other reference crystals, i.e., $DY_2S_3,\;Dy_2O_3\;and\;DyBr_3$. It has been verified from the Dy $L_3$-edge EXAFS spectra that a central Dy atom is surrounded by $6.7{\pm}0.5$ sulfur atoms in its first coordination shell in the Ge-As-S glass, which is relatively smaller than 7.5 of the $Dy_2S_3$ crystal. Averaged Dy-S inter-atomic-distance of the glass ($2.78{\pm}0.01{\AA}$) also turns out to be somewhat shorter than that of the $Dy_2S_3$ crystal ($2.82{\pm}0.01{\AA}$). Such nanostructural changes occurring at Dy atoms imply there being stronger covalency of Dy-S chemical bonds in the Ge-As-S glass than in the crystal counterpart. The enhanced covalency in the nanostructural environment of $Dy^{3+}$ ions inside the glass would then be responsible for optical characteristics of the $4f{\leftrightarrow}4f$ transitions of the dopants, i.e., increase of oscillator strengths and spontaneous radiative transition probabilities.

$Zn_{2-x}Mn_xSiO_4$ 형광체의 망간 K 흡수단 엑스선 흡수 분광 분석

최용규,임동성,김경현,손기선,박희동,Choi, Yong Gyu,Lim, Dong Sung,Kim, Kyong Hon,Sohn, Kee Sun,Park, Hee Dong 대한화학회 1999 대한화학회지 Vol.43 No.6

PDP(plasma display panel)의 녹색 광원으로 유망한 $Zn_{2-x}Mn_xSiO_4$ 헝광체를 1300$^{\circ}C$에서 고상반응법으로 제조한 후 900$^{\circ}C$에서 후속 열처리를 실시하면 녹색 형광의 강도가 현저히 증가한다. 열처리를 통한 형광 강도의 향상과 망간의 산화 상태 및 국부 구조 변화와의 관계를 파악하고자 망간 K 흡수단의 엑스선 흡수 스펙트럼을 분석하였다. $1s{\rightarrow}3d$ 전이에 해당하는 프리엣지(preedge) 봉우리와 XANES 스펙트럼을 분석한 결과, 망간은 열처리와 무관하게 +2가의 산화 상태를 유지하였으며 Zn 자리를 치환하는 것으로 밝혀졌다. 또한 EXAFS 스펙트럼의 분석을 통하여, Mn은 $MnO_4$ 사면체를 형성하고 Mn-O 쌍의 결합 길이와 디바이월러 인자(Debye-Waller factor)는 열처리 후 공히 감소함을 알 수 있었다. Green-emission intensity of a $Zn_{2-x}Mn_xSiO_4$ phosphor, which is a potential candidate as a green component in PDP device, significantly increases provided that the compound is additionally heat treated at 900$^{\circ}C$ after solid state reaction at 1300$^{\circ}C$. In order to verify origin of such an intensity enhancement after the additional heat treatment in association with the electronic and local structural change at around Mn ions, the Mn K-edge X-ray absorption spectra were recorded. From the analyses of the preedge peak corresponding to $1s{\rightarrow}3d$ bound state transition and XANES spectrum, it is known that most Mn ions are in +2 oxidation state and substitute Zn ion site regardless of the thermal treatment. In addition, EXAFS analyses revealed that Mn ions formed $MnO_4$ tetrahedra with the Mn-O bond length shortened by 0.01${\AA}$ and with reduced Debye-Waller factor in the thermally treated sample.

Er 첨가 황화물계 광섬유의 제조 및 분광학적 특성

최용규,임동성,김경헌,박세호,허종,Choi, Yong-Gyu,Lim, Dong-Sung,Kim, Kyong-Hon,Park, Se-Ho,Heo, Jong 한국세라믹학회 2000 한국세라믹학회지 Vol.37 No.8

An Er-doped sulfide fiber was drawn, and its spectroscopic properties were analyzed. Compositions of a 1000 ppmwt Er3+-doped core and an undoped clad were Ge30-Ga1-Asg-S61 and Ge30-As8-S62, in at.%, respectively. Refractive index of the core composition was approximately 0.01 high than that of the clad. In order to enhance the mechanical stability as well as to prevent infiltration of impurity ions such as OH-, an UV-curable polymer was used for the coating. The optical loss of a fiber formed directly from a polymer coated core rod without cladding was ∼15 dB/m at 1.06$\mu\textrm{m}$. In the case of a fiber with core/clad structure, the optical loss was so high that the stimulated emission of erbium fluorescence was not evident. It is believed that presence of inhomogeneous core/clad interface and crystalline aggregates precipitated in the clad region were responsible for the high optical loss. On the other hand, fluorescence characteristics of Er3+ embedded in the core region were more or loss deteriorate compared to fiber preform, which is attributed to the redistribution of the Er ions along with the partial crystallization of the core glass during the fiberization process.

중금속 산화물 유리내 희토류 원소의 Multiphonon Relaxation 현상

최용규,허종,Choi, Yong-Gyu,Heo, Jong 한국세라믹학회 1998 한국세라믹학회지 Vol.35 No.4

2013~2015년 울릉 난수성 소용돌이의 수온변동

최용규,Choi, Yong-Kyu The Korean Society of Marine Environment and safet 2016 해양환경안전학회지 Vol.22 No.2

울릉 난수성 소용돌이의 수온 변동을 보기 위하여, 동해중부해역(동해항-독도의 지선)에서 2013년 7월부터 2015년 7월까지 소모성 수온기록계(XBT)와 국립수산과학원의 정선 해양 관측 자료를 이용하여 살펴보았다. 울릉 난수성 소용돌이의 완전한 형태를 볼 수 없었을지라도, 조사 단면은 울릉 난수성 소용돌이의 특징을 잘 나타내었다. 그 결과, 수온의 변동계수는 평균 수온이 $3{\sim}4^{\circ}C$의 범위를 가지는 250 m 깊이에서 가장 크게 나타났다. 250 m 층의 수온 변동계수의 수평적 분포는 울릉도와 한국 동해안 사이의 해역에서 가장 컸으며, 이는 울릉 난수성 소용돌이의 핵이 아닌 주변부 해역이었다. 울릉 난수성 소용돌이는 한국 동해 연안에서 남북 혹은 동서로 움직였다, 울릉 난수성 소용돌이는 주로 울릉도 남서 해역에 존재하였으며, 남북 방향으로의 이동성이 동서 방향으로의 이동성보다 크게 나타났다. 250 m 깊이에서 수온의 변동계수가 크게 나타난 것은 울릉 난수성 소용돌이의 하층부에 있는 동해중층수와의 상호 작용에 의한 것으로 보인다. 이것은 울릉 난수성 소용돌이의 하부 깊이에서 울릉 난수성 소용돌이 주변부와 동해중층수와의 상호 작용이 활발하게 발생하고 있음을 시사하고 있다. Based on the Expendable Bathythermograph (XBT) observation and serial oceanographic observation of National Institute of Fisheries Science (NIFS) during July 2013 to July 2015, we examined the temperature variation in the Ulleung Warm Eddy (UWE) in the East Sea. The UWE was always shown during the observation periods even though it was not the whole shape. The coefficient of variation (CV) was largest in the depth of 250 m at the side of the east coast of Korean Peninsula with $3{\sim}4^{\circ}C$ in temperature. CV of the horizontal distribution at 250 m depth was also largest in the region biased along the east coast of Korea. The warm eddy moved not only to the east-west direction but also to the north-south direction in the viewpoint of horizontal distributions of temperature. This region between the Korean Peninsula and Ulleung island also is the passage of the East Korean Warm Current. This means that interaction between the East Korean Warm Current and periphery of warm eddy makes large in the variation of movement along the east coast of Korean Peninsula. The largest variation of temperature at 250 m depth seemed to be significantly correlated with the East Sea Intermediate Water (ESIW) underlying Ulleung Warm Eddy. It is suggested that the interaction between the ESIW and UWE is active in the mid-depth along the periphery of UWE.

갈륨 K 흡수단의 저온 EXAFS를 이용한 PbO-Ga$_2$O$_3$ 유리의 구조 해석

최용규,김경헌,허종,Choi, Yong-Gyu,Kim, Kyong-Hon,Chernov, Vladimir A,Heo, Jong 한국세라믹학회 1998 한국세라믹학회지 Vol.35 No.11

Ga K-edge EXAFS spectra of PbO-Ga2O3 glasses were recorded at liquid nitrogen temperature and analyz-ed in order to quantitatively understand the medium-range-order arrangement around gallium in the glasses. The second peak was generated from a backscattering of the neighbor balliums and the Ga-Ga distance is ~3.13 A with Ga coordination number of ~2.7 Therefore GaO4 tetrahedra are connected through the cor-ner~sharing mode and form their own clusters made of the tetrahedra sharing more than 3 corners while some chains or rings are also present. These connection schemes of the GaO4 tetrahedra are believed to form the substantial part of the network structure.

2010년 동해 영덕 연안의 저염수

최용규,권기영,양준용,Choi, Yong-Kyu,Kwon, Kee-Young,Yang, Joon-Yong 해양환경안전학회 2012 해양환경안전학회지 Vol.18 No.5

동해 영덕 연안의 저염수를 보기 위하여 지난 2010년 격월별(2월 23일, 4월 6일, 6월 8일, 8월 19일, 10월 6일, 12월 20일)로 20개의 정점에서 CTD 관측을 수행하였다. 혼합층은 여름에 약 10 m 깊이로 얕았으며, 겨울에 약 20 m 깊이에서부터 저층까지 혼합층을 나타내었다. 연중 $5^{\circ}C$ 이하의 찬 물이 수온 약층 이심을 점하고 있었다. 염분 약층은 8월에는 깊이 20 m에, 10월에는 깊이 40 m에 분포하였으며 연중 가장 뚜렷하였다. 뚜렷한 저염수는 10월에 깊이 10 m에서 나타났는데, 10월에 강수량-증발량의 값이 음을 보였다, 이것은 10월에 영덕 연안에서 나타나는 저염수가 이류되어 온 것임을 시사하였다. 동해의 영덕 연안에서 나타나는 저염수는 동한 난류가 주요한 역할을 하는 것으로 보여진다. In order to see the oceanographic conditions, the observations of aquaculture farm of ascidian in Youngdeuk, the east coast of Korea were conducted through 6 times-23 February, 6 April, 8 June, 19 August, 6 October and 20 December-in 2010. Surveys were conducted in 20 stations bimonthly using SBE 19 CTD instrument. The mixed layer depth (MLD) was deep in winter and shallow in summer. The cold water below $5^{\circ}C$ in temperature was occupied below thermocline through all season. The temperature was high in the southeastern area. The salinity was increased from the coast to the open sea. The halocline was distinct at 20 m depth in August and at 40 m depth in October. The lowest value of salinity was appeared at the depth of 10 m in October. In addition the value of precipitation minus evaporation denoted negative in October. These low saline water seemed to inflow to the coast from the open sea. Therefore the low saline water moved to the east coast of Korea. The EKWC may play an important role to convey the low saline water. It may affect the aquaculture farm along the coast as the mass mortality of ascidian. It needs to clarify the role and pathway of EKWC to transfer the low saline water along the east coast of Korea.

2013년 2월 동해의 근해 해황에 의한 연안 성층

최용규,김상우,정희동,심정민,권기영,Choi, Yong-Kyu,Kim, Sang-Woo,Jeong, Hee-Dong,Shim, Jeong-Min,Kwon, Kee-Young 해양환경안전학회 2013 해양환경안전학회지 Vol.19 No.4

동해에서 외양의 해양학적 현상으로 인하여 연안역에서 발생할 수 있는 성층 현상을 이해할 목적으로 2013년 2월 국립수산과학원의 해양조사 정선관측 자료와 함께 연안의 3개 지점(속초, 죽변, 감포)에서 조사한 CTD 자료를 분석하였다. 속초와 감포 연안은 혼합 상태였으며, 죽변 연안은 강항 성층을 이루고 있었다. 또한 해양 정선 조사에서 104선(죽변)의 연안쪽 정점에서도 마찬가지로 107선(속초)과 209선(감포)의 연안쪽 정점에 비해서 성층이 강하게 형성되어 있었다. 104선(죽변)의 정점 9의 깊이 200 m층에서 $4.0^{\circ}C$의 양의 수온 편차를 보였으며 이것은 연안까지 이어져 양의 수온 편차를 나타내었으며, $10^{\circ}C$ 등온선이 깊이 200 m까지 아래로 오목한 형태를 나타내었다. 또한 104선의 정점 9를 중심으로 10~40 cm/s의 속도로 시계 방향의 소용돌이가 형성되어 있었다. 이는 죽변 연안에서 나타난 성층은 울릉 난수성 소용돌이의 접안에 의해서 형성된 것임을 보여주었다. 난수성 소용돌의 변화는 동해에서 대구와 같은 냉수성 어종의 회유에 장애물이 될 수도 있어 수산 자원과의 관련성을 밝히는 것도 필요하리라 생각된다. In order to see the stratification phenomenon in the coastal area induced by oceanographic conditions of the open sea, we analyzed the CTD (Conductivity-Temperature-Depth) data taken from the oceanographic survey on February 16~28, 2013. The stratification in Jukbyun coast was stronger than those of Sokcho and Gampo coast. Jukbyun line (104 line in the Serial Oceanographic Observation of National Fisheries Research and Development Institute) showed the anticyclonic eddy in the vertical distribution of temperature. The isotherm of $10^{\circ}C$ was concaved to the depth of 200 m in the middle station (station no. 9) of the line 104. It showed above $4^{\circ}C$ in positive temperature anomaly in the depth of 100~200 m in the middle station (station no. 9) of the line 104. This positive temperature anomaly was stretched to the coastal area with shallower depth. It is suggested that the stratification in Jukbyun coast was resulted from the onshoring of the Ulleung warm eddy. The movement of warm eddy may be act as a block to migration of cold water fishes like cod.

희토류 원소 첨가 비정질 찰코지나이드 : 형광 수명과 유리 구조 변화의 관계

최용규,Choi Yong Gyu 한국세라믹학회 2004 한국세라믹학회지 Vol.41 No.9

Lifetime of excited electronic states inside the 4f configuration of rare-earth elements embedded in chalcogenide glasses is very sensitive to medium-range structural changes of the host glasses. We have measured lifetimes of the 1.6$\mu\textrm{m}$ emission originating from Pr$\^$3+/ : ($^3$F$_3$, $^3$F$_4$)\longrightarrow$^3$H$_4$ transition in amorphous chalcogenide samples consisting of Ge, Sb, and Se elements. The measured lifetimes fumed out to have their maximum at the mean coordination number of -2.67, which arises accordingly from structural changes of the host glasses from 2 dimensional layers to 3 dimensional networks. This new finding supports that the so-called topological structure model together with chemically ordered network model is adequate to explain relationship between the emission properties of rare-earth elements and the medium-range structures of amorphous chalcogenide hosts with a large covalent bond nature. Thus, it is validated to predict site distribution and lifetime of rare-earth elements doped in chalcogenide glasses simply based on their mean coordination number.