Holographic Polymer Dispersed Liquid Crystal Containing Polyhedral Oligomeric Silsesquioxane (초)

정연길,( Eun Hee Kim ),( Sang Won Myoung ),( Yeon Gil Jung ),( Un Gyu Paig ) 대한금속재료학회 ( 구 대한금속학회 ) 2008 대한금속재료학회 학술대회 개요집 Vol.2008 No.1

수용성 매체에서 뮬라이트의 합성거동 및 입자형상에 미치는 염 및 전구체 pH의 영향

정연길,이재언,신영일,김재원,조창용,Jung, Yeon-Gil,Lee, Jae-Ean,Shin, Young-Ill,Kim, Jae-Won,Jo, Chang-Yong 한국재료학회 2003 한국재료학회지 Vol.13 No.4

The effects of the salt and the precursor pH on the synthesizing behavior and the morphology of mullite have been studied. Two kinds of mullite precursor sols were prepared by the dissolution of two kinds of salt (aluminum nitrate enneahydrate, Al($NO_3$)$_3$ㆍ$9H_2$O; type I and aluminum sulfate 14∼18 water, (SO$Al_4$)$_3$$\cdot$$14∼18H_2$O; type II) into the mixture of colloidal silica sol, respectively. Precursor pH of the sols was controlled to the acidic (pH= 1.5∼2) and basic (pH= 8.5∼9) conditions. The co-products with nitrate and sulfate were completely eliminated at $500^{\circ}C$ and $850^{\circ}C$, respectively, which was confirmed by TG/DTA results. The synthesizing temperature of mullite phase was found to be above $1200^{\circ}C$ for pH= 1.5∼2 and above $1300^{\circ}C$ for pH= 8.5∼9 in type I. However, in type II, the synthesizing temperature of mullite was decreased to $850^{\circ}C$ for pH= 1.5∼2 and $1100^{\circ}C$ for pH= 8.5∼9. The grain size of the mullite synthesized at pH= 8.5∼9 was larger than that at pH= 1.5∼2 in overall heat-treated temperatures, showing smaller grain size in type II. Aspect ratio of the mullite grains was more increased at pH= 1.5∼2 than pH= 8.5∼9 in type I, showing similar aspect ratio at both pH conditions in type II. It was found that the synthesizing temperature and grain size were predominantly governed by the initial precursor pH and decomposition of the salt, with minor effect on the grain morphology.

직응집성형법을 이용한 질화규소의 실형상 성형공정 및 성형특성

정윤성,정연길,백운규,Jung, Yun-Sung,Pagnoux, Cecile,Jung, Yeon-Gil,Paik, Un-Gyu 한국세라믹학회 2002 한국세라믹학회지 Vol.39 No.3

본 연구에서는 복잡 형상의 세라믹체를 효율적으로 성형할 수 있어 새로운 성형기법으로 부각되고 있는 직응집성형(Direct Coagulation Casing, DCC)공정기술에 관하여 콜로이드 계면화학을 이용하여 연구하였다. 높은 고형분량을 가지는 안정된 질화규소 슬립을 제조하기 위하여 분산제, 소결조제 그리고 응집제 각각이 다양한 공정변수에 미치는 영향에 대하여 평가하였다. 1.0 wt% Tetraethylammonium Hydroxide(TEAH)를 첨가하여 염기영역에서 소결조제를 포함한 안정된 51vol%의 질화규소 슬립을 제조할 수 있었다. 질화규소 슬립은 첨가된 $Al(CH_3COO)_2OH$의 온도증가에 따른 열분해를 이용하여 직응집성 유도하였다. 염기영역에서 $Al^{3+}$ 이온들이 aluminum hydroxide$(Al(OH)_3)$ 석출되면서 슬립내 $OH^-$ 농도를 감소시켜 질화규소 슬립을 직응집시켰다. In this proposed study, a new emerging shape forming technique Direct Coagulation Casting(DCC) which enables to fabricate complex-shaped ceramic parts has been investigated using colloid surface chemistry. Various process variables affected by dispersant, coagulation agent and sintering additives, have been evaluated in order to achieve highly concentrated stabilized silicon nitride suspensions. A high solid loading of 51 vol% in the dispersed silicon nitride suspension was prepared with 1.0wt% Tetraethylammonium Hydroxide (TEAH), which obtained a stable silicon nitride suspension with sintering additives $(Al_2O_3\;and\;Y_2O_3)$ in alkaline regions. The addition of hydroxyaluminium diacetate into the suspension, which decomposed at elevated temperatures, led to coagulate of a silicon nitride suspension. In a basic medium, aluminum ions precipitated to aluminum hydroxide $(Al(OH)_3)$, leading to decreased $OH^-$ concentration and, thus, coagulated suspension.

폐유리를 재활용한 타일 제조 및 물리적 특성

김영길,정연길,송준백,신민철,이희수,Kim, Young-Kil,Jung, Yeon-Gil,Song, Jun-Baek,Shin, Min-Chul,Lee, Hee-Soo 한국세라믹학회 2005 한국세라믹학회지 Vol.42 No.3

폐유리와 점토를 이용하여 일축 가압 성형법으로 타익을 제조하였다. 유리함량, 소성온도 및 소성시간에 따른 타일의 흡수율, 밀도, 겉보기 기공률, 압축강도, 마모감량 등을 고찰하였다. 소성온도 및 유리함량이 증가함에 따라 타일의 특성은 향상되었다. 폐유리를 $70wt.\%$ 사용하고 $1,050^{circ}C$에서 소성한 타일이 가장 우수한 특성을 나타내었으며, 이 때의 흡수율, 밀도, 겉보기 기공률, 압축강도, 마모감량은 각각 $0.9\%,\;2.3g/cm^3,\;2.1\%$, 210 MPa, 0.022g이었다. 이는 유리상의 혈성에 의잔 결과로서 타일의 기공 감소 및 치밀화에 기여하기 때문이다. 제조된 타일의 특성은 상용화되고 있는 일반 자기질 타일과 비교하여 우수한 특성을 나타내고 있으며, 바닥 및 내$\cdot$외벽용 무유타일로 적용 가능할 것이다. Wall and floor tiles were fabricated by a dry pressing method using waste glass and clay. The physical properties of the tiles such as absorption, bulk density, porosity, compressive strength, and abrasion loss are investigated with the firing temperature and glass contents. The physical properties are improved with increasing the firing temperature and glass contents. The composition containing the glass of $70 wt%$ and fired at $1050^{\circ}C$ for 2 h has the good properties. The optimal properties obtained in the tiles are the water absorprion of about $0.9\%$, the bulk density of about $2.3\;g/cm^3$, the apparent porosity of about $2.1 \%$, the compressive strength of about 210 MPa, and the abrasion loss of about 0.022 g, when the composition containing the glass of $70\;wt\%$ is fired at $1050^{\circ}C$. The physical proper1ies of tiles fabricated were enhanced compared to the commercial clay tiles, due to easy melting and densification of glassy phase during the firing process.

화학양론 조성의 뮬라이트 합성거동과 입자형상에 미치는 전구체 pH의 영향

이재언,김재원,정연길,장중철,조창용,Lee, Jae-Ean,Kim, Jae-Won,Jung, Yeon-Gil,Chang, Jung-Chel,Jo, Chang-yong 한국재료학회 2002 한국재료학회지 Vol.12 No.7

Stoichiometric mullite ($3Al_2$$O_3$. $2SiO_2$) precursor sol has been prepared by sol-gel method. The effects of the precursor pH and sintering temperature on the synthesizing behavior and morphology of mullite have been studied. Mullite precursor sol was prepared by dissolution of aluminum nitrate enneahydrate (Al($NO_3$)$_3$.9H$_2O) into the mixture of silica sol. Precursor pH of the sols was controlled to acidic condition ($PH\leq$ 1~1.5) and to basic condition ($pH\geq$8.5~9). The synthesized aluminosilicate sols were formed under 20 MPa pressure after drying at $150^{\circ}C$ for 24 hours, and then sintered for 3hours in the temperature range of $1100~1600^{\circ}C$. From TGA/DTA analysis, total weight loss in the aluminosilicate gel of the acidic sample was (equation omitted) 56% and that of the basic sample was (equation omitted) 85%, indicating that the synthesizing temperature of mullite phase for acidic and basic samples was above $1200^{\circ}C$ and $1300^{\circ}C$, respectively. The morphologies of the synthesized mullite were fine and needle-like (or rod-like) for acidic sample, and granular for basic sample that has been sintered above $1300^{\circ}C$. It was found that the morphology of mullite particle was predominantly governed by precursor pH and sintering temperature.

과붕산나트륨 양극 활물질 첨가에 따른 차량용 납산배터리 성능 특성

임태섭,김성준,김상동,양승철,정연길,Lim, Tae Seop,Kim, Sung Jun,Kim, Sang Dong,Yang, SeungCheol,Jung, Yeon-Gil 한국재료학회 2020 한국재료학회지 Vol.30 No.8

The performance characteristics of a lead acid battery are investigated with the content of Sodium Perborate Tetrahydrate (SPT, NaBO₃·4H₂O) in a positive plate active material. SPT, which reacts with water to form hydrogen peroxide, is applied as an additive in the positive plate active material to increase adhesion between the substrate (positive plate) and the active material; this phenomenon is caused by a chemical reaction on the surface of substrate. A positive plate with the increasing content of SPT is prepared to compare its properties. It is confirmed that the oxide layer increases at the interface between the substrate and the active material with increasing content of SPT; this is proven to be an oxide layer through EDS analysis. Battery performance is confirmed: when SPT content is 2.0 wt%, the charging acceptance and high rate discharge properties are improved. In addition, the lifetime performance according to the Standard of Battery Association of Japan (SBA) S0101 test is improved with increasing content of SPT.

Formation pattern 연구를 통한 AGM 연축전지의 충전 효율 향상

김성준,손정훈,김봉구,정연길,Kim, Sung Joon,Son, Jeong Hun,Kim, Bong-Gu,Jung, Yeon Gil 한국결정성장학회 2021 韓國結晶成長學會誌 Vol.31 No.1

CO2 가스 발생 감소와 연비향상을 위해서 HEV 차량은 ISG 시스템을 채용하고 있다. 이 ISG 시스템은 배터리가 감당해야 하는 전기 부하를 증대시켰고, 시동 횟수도 급격히 늘어나게 하였다. 이를 위해 AGM 연축전지가 개발되어 사용되고 있으나, 종래의 연축전지에 비해서 formation 중 전해액량 조절이 더 높은 수준으로 유지해야 됨에 따라 충전시간이 약 3배 가량 길어지게 되었다. 본 연구에서는 formation pattern의 최적화를 통해서 충전효율을 증대시켜 충전시간을 단축하고자 하였다. formation pattern의 최적화를 위해서, 16개 multi step에 10개 충전 step과 6개의 방전 step을 적용하고, step별 충전 전류를 조절한 4가지 조건(21 hr, 24hr, 27 hr, 30 hr)으로 시험을 진행하였다. 그 결과 24 hr 시험 조건이 PbO2 변환율이 가장 높게 분석되었고, 용량 103.3 %, 저온시동성능 38 sec, 충전수입성 37.36 A로 나타났다. Multi-step과 방전 step을 적용한 충전 프로그램의 결과, 충전 중에 국부적으로 급격히 발생된 분극화를 제거하고 전류의 손실을 최소함으로써 충전효율을 증가시킬 수 있음을 검증하였다. 이렇게 충전효율을 증가시킴으로써 본 연구에서는 충전시간을 기존에 비해서 약 30 % 감소시키는 탁월한 결과를 얻을 수 있었다. In order to improve fuel economy and reduce CO2, HEV adopts ISG system as a standard. This ISG system increased the electric load that the battery had to bear, and the number of starting increased rapidly. AGM Lead Acid batteries have been developed and used, but the charging time is about three times longer as the electrolyte amount control during formation must be maintained at a higher level compared to conventional lead-acid batteries. In this study, we tried to shorten the charging time by increasing the charging efficiency through the optimization of the formation pattern. In order to optimize the Formation Pattern, 10 charging steps and 6 discharging steps were applied to 16 multi steps, and the charging current for each step was controlled, and the test was conducted under 4 conditions (21 hr, 24 hr, 27 hr, 30 hr). As a result of simultaneous application of multi-step and discharge step, it was verified that minimizing the current loss and eliminating the sudden polarization during charging contributes to the improvement of charging efficiency. As a result, it showed excellent results in reducing the charging time by about 30 % with improved charging efficiency compared to the previous one.

5ZrSiO₄-xCaCO₃ 혼합계에서 CaCO₃첨가량이 CaZrO₃와 m-ZrO₂의 합성 및 미세구조변화에 미치는 영향

김재원,이재언,조창용,이재현,정연길,Kim, Jae-Won,Lee, Jae-Ean,Jo, Chang-Yong,Lee, Je-hyun,Jung, Yeon-Gil 한국재료학회 2003 한국재료학회지 Vol.13 No.9

Synthesizing behavior and microstructural evolution of $CaZrO_3$and $m-ZrO_2$in a thermal reaction process of $ZrSiO_4$-$xCaCO_3$mixtures, where x is 7 and 19, were investigated to determine the addition amount of CaO in CaO:$ZrO_2$:$SiO_2$ternary composition. CaZrO$_3$-Ca$_2$SiO$_4$precursor prepared by the mixture of $ZrSiO_4$and CaCO$_3$in aqueous suspending media was controlled to the acidic (pH=4.0) condition with HCI solution to enhance the thermal reaction. The addition amount of dispersant into the $ZrSiO_4$-$xCaCO_3$slip increased with increasing mole ratio of $CaCO_3$, which was associated with the viscosity of slip. Decarbonation reaction was activated with an increase of the addition amount of $CaCO_3$, showing different final temperatures in $ZrSiO_4$-$7CaCO_3$and $ZrSiO_4$-$19CaCO_3$mixtures as about 980 and 116$0^{\circ}C$, respectively, for finishing decarbonation reaction. The grain morphology was changed to spherical shape for all samples with an increase of sintering temperature. The grain size and phase composition of the synthesized composites depended on the mixture ratio of Zrsi04 and CacO3 powders, indicating that the main crystals were m-ZrO2 ($\leq$3 $\mu\textrm{m}$) and $CaZrO_3$ ($\leq$ 7 $\mu\textrm{m}$) in $ZrSiO_4$</TEX$>-7CaCO_3$and $ZrSiO_4$-$19CaCO_3$mixtures, respectively.

감액 특성 향상을 위한 하이브리드(Sb/Ca) 액식 연축전지 개발

송승윤,임태섭,김성준,정연길,양승철,Song, Seung Yun,Lim, Tae Seop,Kim, Sung Jun,Jung, Yeon-Gil,Yang, SeungCheol 한국재료학회 2022 한국재료학회지 Vol.32 No.3

One disadvantage of deep cycle flooded lead-acid batteries is increasing water loss caused by use of (+) Pb-Sb / (-) Pb-Sb alloy grid. Water loss is generated by the emission of hydrogen gas from the (-) electrode during battery charging. In this paper, we maintain cycle life aspect through the development of hybrid flooded lead-acid batteries to which a (+) Pb-Sb / (-) Pb-Ca grid is applied and deal with the improvement of water loss. The amount of water loss compared to that of the (-) Pb-Sb grid decreased when Ca was added to the (-) Pb grid. For the (-) Pb-Ca grid, it was confirmed that the time to reach 0.0 V, at which water decomposition occurs, was increased compared to that of the (-) Pb-Sb grid at the NPV (Negative Potential Voltage). In the cycle life test conducted with the BCI (Battery Council International) standard, compared to the (+) Pb-Ca grid, the (+) Pb-Sb grid increased the life cycle of the batteries and the (+) Pb-Ca grid showed an early end of life due to PbO corrosion layer generation, as determined through SEM / EDS and Tear Down analysis. In conclusion, by addition of Sb to (+) Pb grid and Ca to (-) Pb grid, we developed a hybrid flooded lead-acid battery that meets user requirements to improve water loss characteristics and preserve cycle life characteristics.

이미지 처리를 이용한 주차공간의 효율적인 탐지 방법

남기환(Nam kee-hwan),정연길(Jung yeon-gil),정하영(Cheong ha-young),강인화(Kang in-ha),강명구(kang Myung-ku),나상동(Ra sang-dong),배철수(Bae cheol-soo) 한국통신학회 2005 한국통신학회 학술대회논문집 Vol.2005 No.6