국내 음용지하수중 전알파 특성 연구

정도환,이영준,주병규,노회정,유순주,김문수,Jeong, Do-Hwan,Lee, Young-Joon,Ju, Byoung-Kyu,Noh, Hoe-Jung,Yu, Soon-Ju,Kim, Moon-Su 한국지하수토양환경학회 2011 지하수토양환경 Vol.16 No.5

Groundwaters were sampled from 730 wells being used for drinking purposes during 2007-2009. These samples were analysed using a gas-flow type GPC (Gas Proportional Counter) according to the USEPA method (900.0). We obtained a gross-alpha counting TDS (total dissolved solid) efficiency curve (Y = 0.0017X2 - 0.3122X + 19.165, X = TDS, Y = efficiency, $R^2$ = 0.9734) using natural uranium standard to get gross ${\alpha}$ value of the samples. The gross alpha values ranged from MDA (minimum detectable activity) to 14.88 pCi/L and 429 samples showed values higher than MDA (< 0.9 pCi/L). Correlations of the uranium values with the total alpha values and the gross-alpha values indicate that uranium values have high impacts on gross-alpha values. Groundwater samples of study areas were classified into four regions according to the rock types; plutonic (granite) rock region (427 areas), metamorphic rock region (181 aeras), sedimentary rock region (70 areas), volcanic rock region (52 areas). Groundwater of Cretaceous granite presented the highest gross-alpha value. Gross alpha in groundwaters showed no relationship with uranium in terms of the geological ages, rocks and minerals.

지하수 중 라듐-226의 분석방법 및 환경 특성에 관한 예비 연구

정도환,김문수,노회정,윤윤열,김동수,이영준,주병규,홍정기,김태승,Jeong, Do-Hwan,Kim, Moon--Su,Noh, Hoe-Jung,Yoon, Yoon-Yeol,Kim, Dong-Soo,Lee, Young-Joon,Ju, Byoung-Kyu,Hong, Jung-Ki,Kim, Tae-Seung 한국지하수토양환경학회 2012 지하수토양환경 Vol.17 No.2

$^{226}Ra$ in groundwater could be analyzed by various methods. LSC (liquid scintillation counter) is used to measure its activity of Ba co-precipitates with Hisafe III scintillation cocktail solution. Counting efficiency was obtained using NIST $^{226}Ra$ standard solution in triplicate and calculated $^{226}Ra$ concentration using the efficiency values. $^{226}Ra$ values of 19 groundwaters having Gross-${\alpha}$ concentrations of more than 5 pCi/L ranged from ND (${\leq}$ 0.1 pCi/L) to 1.18 pCi/L. Geologic settings of the 19 areas are composed of granitic rocks of Pre-Cambrian and Jurassic and Cretaceous, gneiss (schist) of Pre-Cambrian, and volcanic rocks of Cretaceous. No relationship was shown among $^{226}Ra$ a concentrations and in-situ water quality data, and Gross-${\alpha}$, uranium, radon concentrations.

국내 화산암 지역 지하수 중 자연방사성 물질에 대한 환경 특성

정도환,김문수,주병규,홍정기,김동수,김현구,김혜진,박선화,한진석,김태승,Jeong, Do Hwan,Kim, Moon Su,Ju, Byoung Kyu,Hong, Jung Ki,Kim, Dong Su,Kim, Hyun Koo,Kim, Hye Jin,Park, Sun Hwa,Han, Jin Seok,Kim, Tae Seung 한국지하수토양환경학회 2013 지하수토양환경 Vol.18 No.1

We analyzed natural radionuclides in 80 wells in volcanic rock areas and investigated environmental characteristics. Uranium and radon concentrations ranged from ND to $9.70{\mu}g/L$ (median value: 0.21) ${\mu}g/L$, 38~29,222 pCi/L (median value: 579), respectively. In case of gross-${\alpha}$, 26 samples exceeded MDA (minimum detectable activity, < 0.9 pCi/L) value and the activity values ranged from 1.05 to 8.06 pCi/L. The radionuclides concentrations did not exceed USEPA MCL (maximum contaminant level) value of Uranium ($30{\mu}g/L$) and gross-${\alpha}$ (15 pCi/L). But Rn concentrations in 4 samples exceeded USEPA AMCL (Alternative maximum contaminant level, 4,000 pci/L) and one of them showed a significantly higher value (29,222 pCi/L) than the others. The levels of uranium concentrations in volcanic rock aquifer regions were detected in order of andesite, miscellaneous volcanic rocks, rhyolite, basalt aquifer regions. Radon, however, was detected in order of miscellaneous volcanic rocks, rhyolite, andesite, basalt aquifer regions. The correlation coefficient between uranium and radon was r = 0.45, but we found that correlations of radionuclides with in-situ data or major ions were weak or no significant. The correlation coefficient between the depth of wells and uranium concentrations was a slightly higher than that of depth of wells and radons. Radionuclide concentrations in volcanic rock aquifers showed lower levels than those of other rock aquifers such as granite, metamorphic rock aquifers, etc. This result may imply difference of host rock's bearing-radioactive-mineral contents among rock types of aquifers.

Field-Programmable Gate Array를 사용한 탭 딜레이 방식 시간-디지털 변환기의 정밀도 향상에 관한 연구

정도환(Do-Hwan Jung),임한상(Hansang Lim) 대한전자공학회 2014 전자공학회논문지 Vol.51 No.9

탭 딜레이(tapped delay) 방식은 field-programmable gate arrary(FPGA) 내부 리소스를 이용한 설계에 적합하여 FPGA기반 시간-디지털 변환기(time-to-digital converter)로 널리 사용되고 있다. 그런데 이 방식의 시간-디지털 변환기에서는 지연 소자로 사용하는 전용 캐리체인(dedicated carry chain)의 탭 당 지연시간 차이가 정밀도 저하의 가장 큰 원인이 되고 있다. 본 논문에서는 일반적인 구형파 대신 고정된 시간 폭을 가지는 펄스신호를 지연 소자로 인가하고 상승과 하강 엣지에서 두 번의 시간 측정을 통해 전용 캐리체인내 지연시간의 불균일성을 보상하고 정밀도를 향상하는 시간-디지털 변환기 구조를 제안한다. 제안한 구조는 두 번의 시간 측정을 위해 2개 구역의 전용 캐리체인을 필요로 한다. Dual 엣지 보상 전 두 전용 캐리체인에서 탭 당 지연시간의 평균은 각각 17.3 ps, 16.7 ps에서 보상 후 평균은 11.2 ps, 10.1 ps으로 감소하여 각각 35%, 39% 이상 향상되었다. 가장 중요한 탭 당 최대지연 시간은 41.4 ps, 42.1 ps에서 20.1 ps, 20.8 ps 로 50% 이상 감소하였다. A tapped delay line time-to-digital converter (TDC) can be easily implemented using internal carry chains in a field-programmable gate array, and hence, its use is widespread. However, the tapped delay line TDC suffers from performance degradation because of differences in the delay times of dedicated carry chains. In this paper, a dual edge measurement method is proposed instead of a typical step signal to the delay cell to compensate for the performance degradation caused by wide-delay cells in carry chains. By applying a pulse of a fixed width as an input to the carry chains and using the time information between the up and down edges of the signal pulse, the timing accuracy can be increased. Two dedicated carry chain sites are required for the dual edge measurements. By adopting the proposed dual edge measurement method, the average delay widths of the two carry chains were improved by more than 35%, from 17.3 ps and 16.7 ps to 11.2 ps and 10.1 ps, respectively. In addition, the maximum delay times were improved from 41.4 ps and 42.1 ps to 20.1 ps and 20.8 ps, respectively.

음용 지하수 중 라돈 자연저감 특성

노회정,정도환,윤정기,김문수,주병규,전상호,김태승,Noh, Hoe-Jung,Jeong, Do-Hwan,Yoon, Jeong-Ki,Kim, Moon-Su,Ju, Byoung-Kyu,Jeon, Sang-Ho,Kim, Tae-Seung 한국지하수토양환경학회 2011 지하수토양환경 Vol.16 No.1

To investigate the natural reduction characteristics of radon with a short half-life (3.82 day) in drinking Qgroundwater, we analyzed the changes of radon concentrations of groundwater, waters in storage tanks, and tap waters from the small-scale groundwater-supply systems (N = 301) by LSC (Liquid Scintillation Counter). We also analyzed the concentrations of uranium (half-life 4.5 billion years) in the waters by ICP/MS to compare with natural reduction of radon concentration. The radon concentrations of 68 groundwater-supply systems occupying 22.6% of the total samples exceeded the US EPA's Alternative Maximum Contaminant Level (AMCL : 4,000 pCi/L), with the average radon concentration of 7,316 pCi/L (groundwaters), 3,833 pCi/L (tank waters) and 3,407 pCi/L (tap waters). Compared to the radon levels of pumped groundwaters, those of tank and tap waters naturally reduced significantly down to about 50%. Especially, in case of 29 groundwater-supply systems with the groundwater radon concentrations of 4,000~6,000 pCi/L, average radon concentrations of the tank and tap waters naturally decreased down to the AMCL. Therefore this study implies that radon concentrations of drinking groundwater can be effectively reduced by sufficient storage and residence in tanks.

국내 변성암 지역 음용지하수 중 자연방사성물질(²³⁸U, ²²²Rn)의 환경 특성 연구

주병규,김문수,정도환,홍정기,김동수,노회정,윤정기,김태승,Ju, Byoung Kyu,Kim, Moon Su,Jeong, Do Hwan,Hong, Jung Ki,Kim, Dong Su,Noh, Hoe Jung,Yoon, Jeong Ki,Kim, Tae Seung 한국지하수토양환경학회 2013 지하수토양환경 Vol.18 No.3

This study has investigated naturally occurring radioactive materials (N.O.R.M; $^{238}U$, $^{222}Rn$) for 353 drinking groundwater wells in metamorphic rock areas in Korea. Uranium concentrations ranged from N.D (not detected) to 563.56 ${\mu}g/L$ (median value, 0.68 ${\mu}g/L$) and radon concentrations ranged from 108 to 11,612 pCi/L (median value, 1,400 pCi/L). Uranium and radon concentrations in the groundwater generally are similar to USA with similar geological setting. Uranium concentrations in 9 wells (2.6%) exceeded 30 ${\mu}g/L$, which is the maximum contaminant level (MCL) by the US environmental protection agency (EPA), radon concentrations in 46 wells (13%) exceeded 4,000 pCi/L, which is the Alternative MCL (AMCL) by the US.EPA. The log-log correlation coefficient between uranium and radon was 0.32. The correlation coefficient between uranium and pH was 0.12 and the correlation coefficient between radon and temperature was -0.01. The correlation coefficient between uranium and $HCO_3$ was 0.09 and the correlation coefficient between uranium and Ca was 0.11. The median value of uranium was high Chung-Buk (1.78 ${\mu}g/L$), Gyeong-Buk (1.37 ${\mu}g/L$), In-Cheon (1.06 ${\mu}g/L$) for each province. On the other hand, the median value of radon was high In-Cheon (2,962 pCi/L), Chung-Buk (2,339 pCi/L), Jeon-Buk (2,165 pCi/L) for each province. Jeon-Buk for log-log correlation coefficient is the highest (0.63) among provinces.

복운모화강암지역 지하수 중 자연방사성 물질의 경시적 붕괴특성 연구

김문수,김태승,김현구,김동수,정도환,주병규,홍정기,김혜진,박선화,정찬호,조병욱,한진석,Kim, Moon Su,Kim, Tae Seung,Kim, Hyun Koo,Kim, Dong Su,Jeong, Do Hwan,Ju, Byoung Kyu,Hong, Jung Ki,Kim, Hye Jin,Park, Sun Hwa,Jeong, Chan Ho,Cho, Byong 한국지하수토양환경학회 2013 지하수토양환경 Vol.18 No.4

To figure out the decay characteristics of naturally occurring radionuclides, eight sampled groundwaters from a monitoring borehole having high levels of uranium and radon concentrations in a two mica granitic area have analyzed by liquid scintillation counters (LSC) for over 1 year. In December 2011, three groundwater samples (DJ1, DJ2, DJ3) were obtained from each aquifer system located at -20 m, -40 m, -60 m of the monitoring borehole below the ground surface, respectively. Five samples (DJ4, DJ5, DJ6, DJ7, DJ8) were additionally gained from each aquifer positioned -20 m, -40 m, -60 m, -100 m, -105 m of the borehole in February 2012, respectively. Temporal variation characteristics of uranium and radon concentrations have showed over maximum 2.1 times and 1.4 times fluctuations of the values in the same sampling intervals over time, respectively. The intervals of -40 m and -105 m in the borehole have the highest values of uranium and radon concentrations, respectively. This may imply that the concentrations of naturally occurring radionuclides such as uranium and radon in groundwater have been changed over time and indicate that the qualities of groundwaters from the aquifers developed at each interval in the borehole are different each other. This discrepancy, moreover, could be caused by behaviour differences between uranium which is in ionic status having a half life of 4.6 billion years and is transported along with the flowing groundwater, and radon which is in gaseous status having a 3.82 day's half life in the aquifer systems. Physicochemical characteristics of groundwaters from the aquifer systems could be identified by the results of the on-situ measuring items such as pH and Eh, and the major ionic contents. The CPM values of eight groundwater samples analysed by LSC over one year have shown not to follow the theoretical decay curve of the radon. The CPM values of the samples have ranged from 2 to 7.5 after it had passed two months when the theoretical CPM values of the radon started zero since the initial analysis. Alpha and beta particle spectrums have shown the peaks of radium-226, however they have not revealed any peaks of radon and it's daughter products such as polonium-218 and 214, bismuth-214 for the late stage of the analysis. This implies that the groundwater from the borehole may contain radium-226 having a half life of 1,600 years which decays continuously.

경북 영천지역 지하수의 지구화학 및 환경동위원소 연구

김건영,고용권,배대석,원종호,정도환,최병영,Kim, Geon-Young,Koh, Yong-Kwon,Bae, Dae-Seok,Won, Chong-Ho,Jung, Do-Hwan,Choi, Byoung-Young 한국지하수토양환경학회 2007 지하수토양환경 Vol.12 No.4

영천지역 지하수의 지구화학적 특성 연구를 수행하였다. 연구지역의 지하수는 Ca-$HCO_3$형에서부터 Ca-$SO_4$형까지의 영역에 해당하고 일부 시료는 Na-$HCO_3$형에 해당한다. 이들의 지화학적 특성은 주로 시추공이 위치한 지역의 기반암에 의해 영향받았다. 국지적으로 퇴적암내의 황산염광물 및 황화광물과의 반응에 의하여 지하수내의 $SO_4$ 함량이 높은 지하수가 산출되며, Ca이온은 퇴적암내의 탄산염광물에서 유래되었다. Na-$HCO_3$형을 보이는 지하수는 초기에는 주로 방해석과의 반응에 의해 지하수내에 Ca 함량이 증가되었고, 방해석에 대해서 포화상태에 도달한 이후에는 주로 사장석과의 반응에 의해 지하수내 Na의 함량이 조절된 것으로 판단된다. 이와 같은 해석은 이들 지하수들의 낮은 삼중수소 함량으로 뒷받침된다. 수소 및 산소동위원소 분석결과에 의하면 연구지역 지하수는 모두 강수에서 기원하였으며 유형별로 명확히 구별되지 않는다. BH-1, BH-9, BH-12 지하수 수질은 화학적 및 동위원소적으로 심부지하수의 특성을 보여주며, 이들 시추공을 제외한 모든 시추공들에서 시료채취심도에 따른 지화학적 및 동위원소 변화를 명확히 보여주지 않기 때문에 연구지역 전반에 걸쳐 천부지하수와 심부지하수의 혼합양상을 지시한다. 수질분석결과는 연구지역 전반에 걸쳐 농업활동에 의한 지하수 오염이 상당히 진행되고 있음을 알 수 있다. Geochemical and isotope studies on the groundwater system of the Youngcheon area were carried out. Most groundwaters belong to Ca-$HCO_3$ and Ca-$SO_4$ types and some groundwaters belong to Na-$HCO_3$ type. Geochemical characteristics of these groundwaters were mainly affected by their basement rocks around the boreholes. High $SO_4$ content of groundwater is the result of reaction with sulfate or sulfide minerals in the host rock. Ca was originated from the carbonate minerals in the sedimentary rock. After the groundwater was saturated with calcite, the Na-$HCO_3$ type groundwaters were evolved by the reaction with plagioclase for a relatively long residence time. This explanation was supported by low tritium contents of Na-$HCO_3$ type groundwaters. ${\delt}a^{18}O$ and ${\delta}D$ data indicate that the groundwaters are of meteoric water origin and there was no difference between the various types of waters. Grondwaters from the boreholes BH-1, BH-9 and BH-12 showed the geochemical and isotopic characteristics of deep groundwater. Most borehole groundwaters except them did not show the systematic geochemical variations with sampling depth indicating that the shallow and deep groundwaters were mixed with each other throughout the study area. The results of water quality analysis indicate that the study area is highly contaminated by the introduction of agricultural sewage.

[기술논문] 동작 방식과 기능별 회로 분류에 기반한 상용차 배선 회로 표준화 방안

임한상(Hansang Lim),배승득(Seung-Deuk Bae),정도환(Do Hwan Jung),정현철(Hyun Chul Jeong) 한국자동차공학회 2013 한국 자동차공학회논문집 Vol.21 No.4

금호강 하상 퇴적물의 광물성분 및 중금속 분포

김병기 ( Byoung Ki Kim ),김영규 ( Yeong Kyoo Kim ),남은경 ( Eun Kyoung Nam ),정도환 ( Do Hwan Jung ),이지은 ( Ji Eun Lee ) 한국광물학회 2006 광물과 암석 (J.Miner.Soc.Korea) Vol.19 No.4