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이언필 ( Eon Pil Lee ),강세미 ( Se Mi Kang ),황대연 ( Dae Youn Hwang ),정영진 ( Young Jin Jung ),최해욱 ( Hae Wook Choi ),최영호 ( Young Ho Choi ),이재호 ( Jae Ho Lee ) 한국의류산업학회 2012 한국의류산업학회지 Vol.14 No.4
octanethiol and vinyl acetate telomers (R8S-nVAc) were synthesized and hydrolyzed with sodium hydroxide subsequently, 1.2-epoxyhexane was then introduced to the telomers, In addition, we prepared cotelomers of multi-alkylated nonionic surfactants with a molecular structure of xRnMA-yVA (x; hydrophobic group, y; hydrophilic group, MA; methacrylic ester, VA; vinyl alcohol, R; and alkyl group) and cross-linked with sodium tetraborate decahydrate. Their active surface properties were investigated by several techniques such as surface tension, foaming property, and emulsification power measurements. The surface tension of R8S-8.8VA decreased without the introduction of 1.2-Epoxy hexane, and the degree of emulsification and foaming abilities of R8S-8.8VA increased without the introduction of 1.2-Epoxy hexane. However, the differences were insignificant. The epoxy groups were attached to a R8S-8.8VA cotelomer with a limited variation of the active surface properties. The surface tension of 1.1R6MA-8.8VA decreased after cross-linking subsequently, the degree of emulsification and foaming abilities of 1.1R6MA-8.8VA increased after cross-linking. However, there was no clear difference between them. The B-O bonds were attached to a 1.1R6MA-8.8VA cotelomer with a limited variation of the active surface properties.
열처리 온도가 Poly(trimethylene terephthalate)(PTT) 섬유의 역학적 성질과 미세구조에 미치는 효과
정경희 ( Kyung Hui Jeong ),이언필 ( Eon Pil Lee ),이재호 ( Jae Ho Lee ) 한국의류산업학회 2013 한국의류산업학회지 Vol.15 No.6
Polytrimethylene terephthalate(PTT) offers several advantageous properties such as good tensile strength, uniformity, stiffness, toughness, UV stability, resilience, stain resistance, outstanding elastic recovery, and dyeability. The effects of annealing temperature on physical properties and the structure of PTT filaments and yarn were investigated by measuring wide-angle X-ray diffraction (WAXD), density, optical birefringence, dynamic visco elasticity, and tensile testing. The intensity of maximum tan δ decreased and the temperature of maximum tan δ shifted to a higher temperature as the annealing temperature of filaments increased; however, it shifted to a lower temperature when the annealing temperature exceeded 130oC. In addition, crystallinity, density and D-spacing of (010) crystal face increased as the annealing temperature increased. Optical birefringence and specific stress were almost constant up to 100oC and then decreased above 130oC. The shrinkage of PTT filament is 0 in boiling water when annealed above 130oC; consequently, the use of annealed fiber above 130oC can remove thermal instability when dyeing PTT fiber. In the case of yarns, the thermal stability and physical properties of yarns showed the best effect when the ply number is less than 5, twist number is less than 400tpm, and the annealing time is 20minutes.
강세미,노창환,황대연,정영진,최해욱,이언필,이재호,Kang, Se-Mi,Noh, Chang-Hwan,Hwang, Dae-Youn,Jung, Young-Jin,Choi, Hae-Wook,Lee, Eon-Pil,Lee, Jae-Ho 한국섬유공학회 2012 한국섬유공학회지 Vol.49 No.1
The uncrosslinked and crosslinked by ethylene glycol diglycidyl(EGDE) chitosan/sericin blend films were prepared by solvent blending method. Physicochemical properties of the prepared blend films according to various blend ratios were investigated. This was carried out by using universal testing machine, thermogravimeter(TGA), differential scanning calorimeter(DSC), wide angle X-ray diffractometer(WAXD), Fourier transform infrared spectrum(FTIR) and scanning electron microscopy(SEM). With an increase in the sericin mixing ratio, tensile stress increased whereas the tensile strain decreased for uncrosslinking blend films. For a cross linked chitosan/sericin blend film by EGDE, both the tensile stress and strain decreased. Chitosan/sericin blend films exhibit an excellent thermal stability when sericin mixing ratio is 25%. In the infrared spectra, chitosan/sericin blend films showed an absorption band of amide I peak at 1630 $cm^{-1}$ and it is concerned with C=O stretching vibration by strong hydrogen-bond between inter-molecular. These also showed an absorption band of amide II peak at 1521 $cm^{-1}$ concerned with N-H bending vibration. The absorption band of amide I peak decreased with an increase in the chitosan mixing ratio. We identified that there was good miscibility between chitosan and sericin. The water-retention values(WRV) of chitosan/sericin blend films increase as the amount of sericin is raised and this owes to the hydrophilic nature of sericin. Weight loss of the citosan/sericin blend films by cleaning with an aqueous sodium hydroxide increased with an increase in the sericin mixing ratio. This loss is the loss of acetic acid and sericin in the chitosan/sericin blend films and this is because of the molecular weight of the sericin is 1/5 of the chitosan and sericin is dissolved into NaOH solution. Weight loss increased when sericin content was more than 50% for the cross linked chitosan/sericin blend films. From the structure analysis, we identified that there was good miscibility and strong intermolecular interaction between the chitosan molecules that resulted from intermolecular hydrogen bonds.
이재호,노창환,최해욱,정영진,황대연,이언필,Lee, Jae-Ho,Noh, Chang-Hwan,Choi, Hae-Wook,Jung, Young-Jin,Hwang, Dae-Youn,Lee, Eon-Pil 한국섬유공학회 2010 한국섬유공학회지 Vol.47 No.2
Chitosan/poly(vinyl alcohol)(PVA) blend films with non-toxicity, biodegradability, and biocompatibility were prepared by solvent blending method. The weight composition ratios of chitosan/PVA blend films were 100/0 (chitosan homopolymer), 75/25, 50/50, 25/75, and 0/100 (PVA homopolymer). Physicochemical properties of the prepared blend films according to various blend ratios were investigated by using universal testing machine, thermogravimeter (TGA), differential scanning calorimeter (DSC), wide angle X-ray diffractometer (WAXD), Fourier transform infrared (FTIR) spectrometer, and scanning electron microscope (SEM). The tensile stress and tensile strain of chitosan/PVA blend films increased as the amount of PVA increased. The thermal stability increased with increasing chitosan content in the chitosan/PVA blend films. The DSC curve of the PVA film shows an endotherm peak around $230^{\circ}C$, and the peak became smaller and broader with increasing chitosan content. The diffraction intensities of chitosan observed at 2 theta of $10^{\circ}$ decreased with increasing the content of PVA in the blend films, but the crystal intensities of the blend films increased as the amount of PVA increased. In the infrared spectra, the absorption band for -OH and -NH stretching vibrations in chitosan broadened and shifted obviously to lower wavenumber with the increase of PVA. Water-retention values of the chitosan/PVA blend films increased as the amount of PVA is increased owing to the hydrophilic nature of PVA. From the structural analyses, it is believed that chitosan and PVA are miscible due to the strong intermolecular hydrogen bonding.
분산염색에서 Cotelomer 타입 계면 활성제의 응용
이재호,최해욱,정영진,황대연,최영호,이언필,Lee, Jae-Ho,Choi, Hae-Wook,Jung, Young-Jin,Hwang, Dae-Youn,Choi, Young-Ho,Lee, Eon-Pil 한국섬유공학회 2010 한국섬유공학회지 Vol.47 No.1
Multi-chain surfactants usually form micelles more easily than single-chain surfactants due to their low surface tension and low solubility in water. In this study we prepared cotelomers of multi-alkylated nonionic surfactants with a molecular structure $xR_nMA$-yVA (x; hydrophobic group, y; hydrophilic group, MA; methacrylic ester, VA; vinyl alcohol, R; alkyl group) and investigated their properties as surfactants for the disperse dyeing of cellulose acetate, nylon 6, and PET fibers. Some cotelomers were synthesized via a radical polymerization of vinyl monomers MA and VA using azobisisobutyronitrile (AIBN) as an initiator. The ratio of x/y and degree of polymerization of $xR_nMA$-yVA with an alkyl chain length (n) of 4 or 6 were controlled by adjusting the ratio of thiol to monomers. We found that a cotelomer with a degree of polymerization 9.9 showed better dispersing performances than cotelomer with a degree of polymerization 4.4 or 12.5, and that the degree of dispersion increased to a certain level and then decreased as concentration of cotelomer increased. The highest value of dye uptake for the three fibers was obtained when using a cotelomer with a monomer unit ratio (x/y) of 0.2 and 0.5 g/l of concentration was 0.5 g/l.