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스프레이코팅법에 의한 패시베이션 박막이 플렉시블 CIGS 태양전지의 특성에 미치는 영향
이상희,박병민,김기홍,장영철,피재호,장호정,Lee, Sang Hee,Park, Byung Min,Kim, Ki Hong,Chang, Young Chul,Pyee, Jaeho,Chang, Ho Jung 한국마이크로전자및패키징학회 2016 마이크로전자 및 패키징학회지 Vol.23 No.3
$Cu(In,Ga)Se_2$ (CIGS) 휨성 태양전지의 셀을 보호하기 위하여 스프레이 코팅방법에 의해 수분과 공기로부터의 보호막을 형성하고 그 전기적, 광학적 특성을 평가하였다. 일반적으로 CIGS 휨성 태양전지의 소자층을 보호하기 위해서 EVA(ethylene-vinyl acetate) 필름을 라미네이션 장비를 통하여 여러 겹 보호막을 형성함으로써 복잡한 공정으로 인해 원가상승의 요인으로서 작용한다. 본 연구는 휨성 CIGS 태양전지의 보호막을 라미네이션 박막공정 대신에 간단한 스프레이 코팅공정을 통한 패시베이션(passivation) 박막층을 형성함으로써 CIGS 태양전지 무게의 경량화와 공정시간 단축 연구를 진행하였다. 패시베이션 박막층으로는 PVA(polyvinyl alcohol), SA(sodium alginate) 물질에 $Al_2O_3$ 나노 입자를 첨가하여 유 무기 복합 용액을 사용하였다. 스프레이 코팅된 소자에 비해 에너지 변환 효율특성 62.891 gm/[$m^2-day$]의 비교적 양호한 습기 차단 특성을 나타내었다. In order to protect the solar cells from the moisture and oxygen, we evaluated the electrical and optical properties for the $Cu(In,Ga)Se_2$ (CIGS) solar cells which were prepared by the spray coating method. Generally, the EVA (ethylene-vinyl acetate) films are laminated to protect the CIGS flexible solar cells, which results in a high cost process due to complicated devices. In this study, we tried to prepare the protection layers of the flexible CIGS flexible solar cells by using spray coating method instead of conventional laminating films in order to reduce the device weight as well as the process time. The CIGS solar cells with spray coating method showed an enhanced efficiency than the before treated sample (2.77% to 2.93%) and relatively proper water vapor transmission rate of the solar cells about 62.891 gm/[$m^2-day$].
이상희,박석순 ( Sang Hee Lee,Seok Soon Park ) 한국물환경학회 1997 한국물환경학회지 Vol.13 No.1
A water quality modeling study was performed for network stream located at western part of Lower Nakdong River. Model construction was based on SNSIM(Stream Network Simulation Model which was developed by United States Environmental Protection Agency. The study area includes Western Nakdong River, Joman River, and their tributaries. The area was divided into 22 reaches according to the model structure. Each reach was then subdivided into uniform computational element of 0.1km. In order to characterize study area, two synoptic field surveys were performed during February 6∼7 and March 29∼30, 1991 periods at network stream and input tributaries. The model was calibrated to the February survey data and verified to the March survey data. The water quality parameters simulated in the model included dissolved oxygen(DO), carbonaceous biochemical oxygen demand(CBOD), and nitrogenous biochemical oxygen demand (NBOD). Computer code of SNSIM model was modified in this study to be executable on IBM PC or comparable with metric input/output unit. The study indicated that the modified SNSIM model would be an effective tool to simulate the water qualities in the complicated stream network. The predicted water qualities displayed reasonable agreements with the field measurements during both surveys.