잔사회를 이용한 인공경량골재의 발포기구

이기강,Lee, Ki-Gang 한국결정성장학회 2012 한국결정성장학회지 Vol.22 No.3

본 연구는 석탄 잔사회의 재활용률을 높이기 위하여 잔사회 인공경량골재의 발포기구를 규명하는 것이다. 본 실험의 원료는 잔사회와 준설토이다. 인공경량골재는 10 mm 크기의 구형 성형체를 제조하고, 이를 승온소성법으로 $1200^{\circ}C$에서 $1275^{\circ}C$까지 소결하였다. 인공경량골재의 온도별, 조성별 비중 및 흡수율 등의 물성을 측정하고, 단면과 표면을 관찰하였다. 비중 곡선의 결과 잔사회 함량이 80 wt.%일 때 변곡점을 나타내었다. 잔사회 인공경량골재의 미세구조를 관찰한 결과 잔사회 함량이 80 wt.%를 넘으면 블랙코어가 없고, 자기화 발포로 균일한 미세기공이 다량으로 존재하며, 잔사회 함량이 80 wt.% 이하이면 잔사회 인공경량골재는 블랙코어가 존재하면서 매우 큰 기공이 불균일하게 존재한다. The purpose of this study is to improve recycling rate of the coal reject ash by investigating bloating mechanism for artificial lightweight aggregate of reject ash. In this study, we use reject ash (R/A) and dredged soil (D/S) as raw materials. The artificial lightweight aggregates were formed by plastic forming (${\phi}$ = 10 mm) and sintered by temperature raising method at different temperatures (between 1200 and $1275^{\circ}C$). The physical properties of the aggregates such as bulk specific gravity, adsorption and microstructure of surface and cross-section are investigated with the sintering temperature and rate of R/A-D/S contents. As the result of the bulk specific gravity graphs, we can found out the inflection point at content of R/A 80 wt.%. From the microstructure images, we considered the artificial lightweight aggregates content of R/A over 80 wt.% are distributed numerous uniform micro-pores by vitrification without Black Core and the artificial lightweight aggregates of R/A below 80wt.% are distributed macro-pores with Black Core.

저회의 계면 화학적 특성 규명

이기강,Lee, Ki-Gang 한국결정성장학회 2011 한국결정성장학회지 Vol.21 No.2

화력발전소에서 발생하는 석탄회의 일종인 저회는 현재 적절한 재활용 방법이 연구 되지 않아 대부분 매립에 의존하고 있는 실정이다. 본 연구에서는 비가소성 분체인 저회의 재활용율을 높이며, 저회를 점토 대체 원료로 재활용하기 위하여 저회와 점토의 계면화학적 성질을 조절하여 Bottom-ash(B/A)-Hard Clay(H/C) 소지의 물성변화를 관찰하였다. H/C 100 %, H/C60 % + B/A40 %에 대하여 각 조성별 pH에 따른 침강높이를 관찰한 결과 점토와 저회는 계면 화학적 성질이 비슷하여 혼합하여 슬립제조 시 hetero-polar 응집현상이 없었다. 또한 각 조성별 점도가 조절된 Slip을 주입 성형하여 $1100{\sim}1250^{\circ}C$에서 $50^{\circ}C$ 간격으로 소결하여 각 시편에 대한 비중, 흡수율을 측정하고 미세구조를 관찰하였다. 그 결과 분산된 점토와 저회 슬립은 Bingham 가소성 거동을 보이므로 주입성형 및 가소성형이 가능하며, 분산된 점토와 저회 슬립으로부터제조된 소결체는 $1250^{\circ}C$에서 KSL 4201과 KSL 1001의 규격을 만족할 뿐 아니라 특히 비중이 약 15 % 이상 경량이므로 도자기나 위생도기 등의 소지로 응용 가능성이 있다고 사료된다. Landfill is the main treatment method for bottom-ash because it has not only an irregular particle size and ingredients but also not proper recycling treatment. The aim of this study is to raise recycling rate of bottom-ash(nonplasticity pulverulent) and for the purpose of alternatives of clay to investigate the properties of Bottom-ash (B/A)-Hard Clay (H/C) bodies with controlled interfacial chemistry properties. After investigating the sedimentation height of suspensions with controlled pH, it was discovered that there was no hetero-polar aggregation for mixed slips because hard clay and bottom-ash had similar interfacial chemistry properties. Also, bulk density, water absorption, and microstructure properties of each pellet was observed that made by silp casting method and manufactured at $50^{\circ}C$ intervals between $1000{\sim}1250^{\circ}C$. As a result, dispersed slip of clay and bottom ash are possible for slip casting and plastic forming process because they exhibit Bingham plastic behavior. Products that made by slip with dispersed clay and bottom ash are not only suitable for KS L 4201 and KS L 1001 at $1250^{\circ}C$ but it is also possible to apply for ceramic and sanitary ware because specific gravity was about 15 % lighter than general ceramic materials.

세라믹소지에 생성되는 석회에 의한 백화현상분석

이기강,Lee, Ki-Gang 한국결정성장학회 2006 韓國結晶成長學會誌 Vol.16 No.3

The efflorescence mechanism of ceramic bodies with different sintering temperature was studied by quantitative analysis for the effect of various metal ions and anions. SEM and EDS characterization for efflorescence formed on the surface of the ceramic body showed that the main components of the efflorescence were Ca and S atoms. Leaching concentrations of various metal ions and anions for the ceramic bodies prepared by wet mixing with pH 7 and pH 10 were evaluated by ICP and IC analysis. The results of leaching test showed that the concentration of Ca ion at pH 7 body was eight times more than that of pH 10 body. Ca-rich efflorescence was not formed on the surface of ceramic body which prepared at pH 10 and sintered over $1100^{\circ}C$. 세라믹소지에 발생하는 온도별 백화생성기구를 백화를 형성하는 양이온과 음이온을 분석하여 규명하였다. 백화가 발생된 세라믹 소지의 표면을 SEM과 EDS 분석을 하여 백화의 주 성분은 Ca와 S임을 확인하였다. 세라믹소지를 pH 7과 pH 10에서 각기 습식혼합 하였으며, 이때 여과된 액을 ICP와 IC 분석을 하여, 양이온 및 음이온 농도분석을 하였다. pH 7에서 제조된 세라믹 소지의 Ca 이온농도는 pH 10에서 제조된 세라믹소지의 Ca 이온농도의 8배 값을 보였으며, pH 10에서 제조된 세라믹소지는 $1100^{\circ}C$ 이상으로 소결된 소지에서도 백화가 발견되지 않았다.

도염식 가스가마의 설계 I.설계

이기강,김환,임응극,Lee, Ki-Gang,Kim, Hwan,Lim, Eung-Keuk 한국세라믹학회 1986 한국세라믹학회지 Vol.23 No.6

This work is concerned with the experimental and theoretical investigation of a kiln with the aim to obtain th best conditions of firing in a kiln, The 0.3$m^3$ down draft kiln of gas firing was designed and constructed. Temperature distributions in kiln combustion gas temperature primary and secondary air flow were measured in the kiln burnt with propane LP gas. And the temperature distri-butions of kiln surface were measured by the thermo camera.

도염식 가스 가마의 설계 -II. 화염의 거동

이기강,김환,임응극,Lee, Ki-Gang,Kim, Hwan,Lim, Eung-Keuk 한국세라믹학회 1987 한국세라믹학회지 Vol.24 No.2

An experimental study of the characteristics and the behavior of flames, and the aerodynamic flow pattern was carried out in the present work on a down draft kiln for gas firing. The aim of this work is to establish a behavior of flames and to know the extent to which the flow pattern is affected by the height of baffle plate. The measurements of temperature, concentrations of fuelgas, and kiln pressure were conducted at different temperature in kiln, and at different height of baffle plate. From the obtained results, it was found that the characteristics of thestagnation zone are greatly affected when changing over the height of baffle plate, and the best condition of that was 115m/m.

철분이 많이 함유된 석탄회의 발포거동

이기강,Lee, Ki Gang 한국결정성장학회 2014 韓國結晶成長學會誌 Vol.24 No.2

본 연구는 순환자원인 저회, 잔사회 그리고 준설토로 인공 경량골재를 제조할 때 철분의 종류와 양이 발포기구에 미치는 영향을 분석하는 것이다. 원료의 화학적 특성을 X선 회절 분석과 X선 형광 분석으로 측정하였다. 준설토 50 %, 저회 15 % 그리고 잔사회 35 %를 무게비로 혼합하고 철분함량을 5 % 단위로 30 %까지 첨가하였으며, 철분의 종류는 $Fe_2O_3$와 $Fe_3O_4$로 선정하였다. 성형된 골재는 급속 소성법으로 $40^{\circ}C$ 간격으로 $1060^{\circ}C$에서 $1180^{\circ}C$까지 소결하고, 비중과 흡수율을 측정하였다. 인공 경량골재는 철분 함유량이 10~15 %일 때 가장 낮은 비중을 보이며, 철분량이 증가할수록 액상 소결이 되어 비중이 증가하였다. The purpose of this study was to figure out the impacts of iron oxide types and dosages to bloating when producing artificial lightweight aggregates by utilization of recycled resources such as bottom-ash, reject-ash and dredgedsoil. In order to figure out chemical characteristics of raw materials, XRD and XRF analyses were performed. 50 wt% of dredged-soil, 15 wt% of bottom-ash and 35wt.% of reject-ash were mixed, then the amount of iron oxide was varied at 5 to 30 wt% with intervals of 5 wt% with $Fe_2O_3$ and $Fe_3O_4$ respectively. As molded aggregates were sintered by rapid sintering in intervals of $40^{\circ}C$ from $1060^{\circ}C$ to $1180^{\circ}C$, specific gravity and water absorption were measured. As a result, the artificial lightweight aggregate with iron oxide of 10~15 vol% showed the lowest specific gravity, and it was identified that the more iron oxide vol% increases, the more specific gravity increases because of liquid phase sintering.

펠레타이저 공정변수와 인공경량골재의 성형체와 소성체 물성과의 상관관계

위영민,이기강,Wie, Young-Min,Lee, Ki-Gang 한국세라믹학회 2007 한국세라믹학회지 Vol.44 No.10

For the manufacturing lightweight fine aggregate, clay and waste material was formed by pelletizer. The fine aggregate of 1-5 mm diameter was formed by diameter 76 cm pelletizer disc. Pelletization variables were : (1) pelletizer disc angle, (2) speed of revolution of pelletizer, (3) added pelletization time. Green and sintered aggregate were measured specific gravity, absorption rate and average size. The optimum condition were found that the pelletization variables were angle at $70^{\circ}$, speed of revolution of pelletizer at 23.2 rpm, and water/solid ratio at 1/5. At these conditions, it was formed that fine aggregate green whose average size was $2.0{\sim}3.35mm$. Specific gravity and average size are increased with low angle of disc and fast revolution speed of disc. Specific gravity and average size were not distinctly influenced by added pelletization time. Sintered aggregate was distinctly influenced by properties of green.

폐유리를 재활용한 인공경량골재의 발포기구

강신휴,이기강,Kang, Shin-Hyu,Lee, Ki-Gang 한국세라믹학회 2010 한국세라믹학회지 Vol.47 No.5

The purpose of this study is to improve recycling rate of the waste glasses by investigating bloating mechanism. In this study, we use waste glass(W/G) and hard clay(H/C) as raw materials. The artificial lightweight aggregates were formed by plastic forming($\phi$=10 mm) and sintered by fast firing method at different temperatures(between 700 and $1250^{\circ}C$). The physical properties of the aggregates such as bulk specific gravity, adsorption and microstructure of surface and cross-section are investigated with the sintering temperature and rate of W/G-H/C contents. As the result of the bulk specific gravity graphs, we can found out the inflection point at content of W/G 60 wt%. From the microstructure images, we considered the artificial lightweight aggregates content of W/ G over 60wt% are distributed numerous micro-pores by organic oxidation without Black Core and the artificial lightweight aggregates of W/G below 60 wt% are distributed macro-pores with Black Core.

CaO 화합물이 다량 함유된 비산재의 탄산화

심준수,이기강,김유택,강승구,Sim, Jun Soo,Lee, Ki Gang,Kim, Yu Taek,Kang, Seung Ku 한국세라믹학회 2013 한국세라믹학회지 Vol.50 No.1

This study was conducted to recycle fly ash containing an abundance of CaO generated from combustion in a circulating layer as a carbon storage medium. The study utilized XRD, TG-DTA and XRF analyses during the hydration of fly ash and identified calcium substances within fly ash that could be used in a carbonation process. $Ca^{2+}$ ions in the calcium substances were easily converted to hydrates. A carbonation experiment was done, which used the method of $CO_2$ gas injection to produce suspensions by mixing fly ash with distilled water. The results were analyzed using TG-DTA, XRD, and pH meter measurements. The study was able to verify that the reaction was completed at a $CO_2$ flow rate of 300cc/min approximately 30 minutes after an injection into a solution with a solid-liquid ratio of 1 : 10 of fly ash and distilled water. Moreover, the stirring time of the suspensions did not influence the reaction, and the reaction time was found to diminish as the portion of the fly ash became smaller. Thus, this study produced carbon storage fly ash having a $CO_2$ storage rate of about 71% through the utilization of the CaO content contained within fly ash.

EAF 더스트-점토계의 중금속 용출 및 안정화에 미치는 pH의 영향

이지영,이기강,김유택,강승구,김정환,Lee, Jee-Young,Lee, Ki-Gang,Kim, Yoo-Taek,Kang, Seung-Gu,Kim, Jung-Hwan 한국결정성장학회 2006 韓國結晶成長學會誌 Vol.16 No.2

유해한 중금속을 다량 함유하는 EAF(electric arc furnace) 더스트를 세라믹 원료로 재활용하기 위해서 EAF 더스트, EAF 더스트-점토에 대해서 pH와 혼합비에 따른 중금속 용출농도의 변화를 분석하였다. 소성과정 중에서 발생하는 중금속의 휘발량을 소지 내의 중금속 이온의 총량을 측정하여 평가하였으며 TCLP(toxicity characteristic leaching procedure)분석을 통해 중금속 이온의 안정화 정도를 평가하였다. EAF 더스트-점토 슬러리의 pH를 10으로 조절하였을 경우에 습식혼합 여액중의 중금속 이온의 농도가 가장 낮은 값을 가졌다. pH 10의 슬러리에 대해서 혼합비와 소성온도에 따른 소지내 중금속 이온의 총량을 측정한 결과 소성온도와 EAF 더스트의 함량이 증가할수록 중금속의 휘발이 증가하였으며, 점토의 혼합비가 증가할수록 중금속 이온의 휘발이 억제되었다. TCLP 분석결과 점토의 혼합비와 소성온도가 증가할수록 중금속의 용출은 감소하였으며 중금속의 용출농도는 기준치 이하로 안정화되었음을 확인할 수 있었다. To recycle the electric arc furnace (EAF) dust as a ceramic raw materials, the leaching concentrations of heavy metals (Zn, Pb, Cr, Cd) were analysed with various pH and mixing ratios for EAF dust and EAF dust-clay mixtures. The evaporation amounts of the some heavy metals were evaluated by measuring their total concentrations in the sintered bodies of EAF dust-clay mixtures with various mixing ratio and sintering temperature. Toxicity characteristic leaching procedure (TCLP) test was conducted for evaluating the chemical stabilities of the heavy metal elements. Leaching concentrations of heavy metal ions shows minimum leaching concentration at the pH 10. Evaporation amount of heavy metals in the sintered bodies were evaluated for the mixtures of pH 10 depenidng on mixing ratio and sintering temperature. Evaporation of heavy metal components were increased with increasing the sintering temperature and contents of the EAF dust. The evaporation of the heavy metal components in EAF dust was effectively suppressed by increasing the clay content. The leaching concentrations of heavy metal components were decreased with increasing clay content and temperature.