섬진강 주변 지하수의 수질 및 오염특성: 오염원 및 유해성 평가

나춘기(Choon-Ki Na),손창인(Chang-In Son) 대한자원환경지질학회 2005 자원환경지질 Vol.38 No.3

섬진강 유역 지하수는 주로 높은 EC의 Na-Cl형과 낮은 EC의 Na-HCO 3 - 형으로 분리되며, K + , Mg 2+ , NO 3 - 및 SO 4 2- 성분이 부화된 특성을 보인다. 일반적으로 지하수의 EC가 증가할수록 TDS에서 차지하는 Na + +Cl - 의 당량분율은 증가한다. 용존이온들간 상관유형으로부터 Na + 와 Cl - 은 주로 침투된 해수에서 유래되며, K + , Mg 2+ 및 SO 4 2- 은화학비료와 같은 인위오염원에서 주로 유래됨을 알 수 있다. 농업용수 수질기준과 비교하여 그 기준을 초과하는 지하 수는 해수침입을 반영하는 Cl - 의 경우 조사대상 관정의 23%인 반면 인위적 오염원을 대표하는 NO 3 - 의 경우 전체의 50%에 달한다. EC-SAR관계를 바탕으로 한 지하수의 유해성 평가에서 조사대상 지하수의 40%만이 농업용수로서 소다질화와 염류화를 초래할 가능성이 없는 적정한 수질을 나타낸다. 결론적으로 섬진강 유역 지하수의 수질저하를 초래한 오염원은 화학비료의 사용과 해수침입이다. 또한 모든 결과들은 화학비료의 사용이 연구지역의 지하수 오염에 가장 폭넓게 영향을 미치며, 일부 특정지역에서는 강쪽으로의 해수역류 확대라는 일차적 요인과 지하수의 과다양수라는 이차적 요인에 의해 섬진강으로부터 해수가 대수층으로 침투되어 더욱 지하수질이 악화되고 있음을 시사한다. The groundwaters in the basin of Seomjin River are classified mainly into Na-Cl type with high EC and NaHCO 3 type with low EC, and are characterized by enriched K + , Mg 2+ , NO 3 - , and SO 4 2- contents. The epm fraction of Na + +Cl - in TDS increases in general with increasing EC of groundwater. The correlation patterns among dissolved ions indicate that Na + and Cl - are derived mainly from intruded seawater, and K + , Mg 2+ , and SO 4 2- from anthropogenic source such as a chemical fertilizer. The groundwaters that exceed the recommended limits for agricultural irrigation water contains 23% of Cl - reflecting sea-water intrusion, but 50% of NO 3 - as an anthropogenic pollution, among the wells investigated. In risk assessment of groundwaters by the EC-SAR relationship, only 40% of the groundwaters shows the suitable quality for agricultural irrigation water without any sodium and salinity hazards. Consequently, the pollution sources that cause degradation of groundwater quality in the basin of Seomjin River are the usage of chemical fertilizers and the intrusion of seawater, resulted primarily from the extension of riverward backflow of seawater and secondarily from the overpumping of groundwater.

전주 및 순창지역에 분포하는 엽리상화강암류의 성인에 대한 연구(I) - 암석지화학적 특성을 중심으로 -

나춘기,이인성,정재일,Na, Choon-Ki,Lee, In-Sung,Chung, Jae-Il 한국지구과학회 1997 한국지구과학회지 Vol.18 No.6

옥천대의 남서대와 영남육괴의 북서 경계부에 대략 평행한 2열로 분포되어 있는 전주 및 순창 엽리상화강암류의 근원마그마의 분화과정 및 성인을 규명하기 위하여 양 암체의 암석학적 및 지화학적 특성을 비교, 고찰하였다. 주성분 원소의 분석결과는 전주 및 순창엽리상화강암이 암석화학적으로 퍼알루미나 또는 칼크알칼리 계열에 속함을 보였으며, 기존의 화강암류 성인에 대한 I/S형 및 자철석/티탄철석 계열의 분류기준을 적용할 경우 비록 원소화학적으로는 I-형과 자철석 계열이 우세한 경향을 보이지만 일관성있게 분류되지 않는 특성을 보였다. 주성부 원소의 분석결과에 의한 CIPW norm 조성에서, 전주암체는 분화가 진행됨에 따라 화강섬록암에서 화강암으로 진화되는 반면, 순창암체는 화강섬록암에서 석영몬조섬록암으로 진화되는 특성을 보였다. 이는 양 암체가 지각물질과의 동화 혹은 결정분별과정 등을 포함하는 마그마 진화의 후기 과정에서 서로 상이했음을 시사한다. 전주 및 순창암체의 희토류원소 분포형태는 양 암체 모두에서 Eu(-) 이상이 거의 나타나지 않고 LREE가 HREE에 비해 극도로 부화된 경향을 보여 서로 매우 유사했다. 이러한 희토류 원소의 분포형태는 우리나라의 선불국사 화강암류에서 보여지는 공통적인 희토류원소의 분포형태와 유사한 것이다. 이상의 결과들은 전주 및 순창엽리상화강암이 그 조성에 있어 서로 유사한 근원암 즉, 화성암질 조성을 갖는 대륙지각의 부분용융에 의해서 형성된 마그마를 기원으로 하고 있으며, 서로 유사한 마그마 분화정치과정을 거쳤음을 시사한다. In order to understand the processes involved in the petrogenesis and the differentiation of the primary magma spectrum, a petrological and geochemical properties were investigated for the Chonju and the Sunchang foliated granites, which are located in the southwestern part of the Okchon zone and extends up to the northwestern boundary of the Ryongnam massif as two subparallel batholiths. Major element analyses show that the Chonju and Sunchang foliated granites are classified petrologically into a weakly to strongly peraluminous or calc-alkaline, but do not fit neatly into either of the I/S-type or magnetite/ilmenite-series classification schemes for granites, although the I-type and magnetite-series characteristics seem to be predominant based on the major element chemistry. In normative compositions, the Chonju granite is petrographically evolved from granodiorite to granite, whereas the Sunchang granite is from granodiorite to quartz monzodiorite. It seems to suggest a difference of the magmatic evolution processes such as crustal assimilation and/or fractional crystallization in magma. The REE patterns of both batholiths show high similarity and strongly fractionated REE distributions which show high $(Ce/Yb)_N$ ratios and little or no Eu anomalies. These REE patterns correspond broadly to those seen in the pre-Cretaceous granitoids of Korea. Apparently, the evidences obtained from the bulk compositions strongly suggest that the two foliated granitoids were formed by partial meltings of a relatively restricted and similar, may be common, source material which contains a continental crust component having an igneous composition, and have undergone a similar magmatic differentiation processes.

전주 및 순창지역에 분포하는 엽리상 화강암류의 성인에 대한 연구 (II) - Sr 및 Nd 동위원소적 특성을 중심으로 -

나춘기,이인성,정재일,Na, Choon-Ki,Lee, In-Seong,Chung, Jae-Il 대한자원환경지질학회 1997 자원환경지질 Vol.30 No.3

The Sr and Nd isotopic compositions of two foliated granitic plutons located in the Chonju and Sunchang area were determined in order to reconfirm the intrusion ages of granitoids and to study the sources of granitic magmas. The best defined Rb-Sr isochron for the whole rock samples of the Chonju foliated granite (CFGR) give an age of $284{\pm}12Ma$, suggesting early Permian intrusion age. In contrast, the whole rock Rb-Sr data of the Sunchang foliated granite (SFGR) scatter widely on the isochron diagram with very little variation in the $^{87}Rb/^{86}Sr$ ratios and, therefore, yield no reliable age information. Futhermore they show the concordance of mineral and whole rock Rb-Sr isochron and divide into two linear groups with roughly the same slopes and significantly different $^{87}Sr/^{86}Sr$ ratios, indicating some kind of Rb-Sr distortion in whole rock scale and a difference in source material and/or magmatic evolution between two subsets. The reconstructed isochrons of 243 Ma, which was defined from the proposed data by the omission of one sample point with significantly higher $^{87}Rb/^{86}Sr$ ratio than the others, and 252 Ma, from the combined data of it and some of this study, strongly suggest the possibility that the SFGR was intruded appreciably earlier than had previously been proposed, although the reliability of these ages still questionable owing to high scatter of data points and, therefore, further study is necessary. All mineral isochrons for the investigated granites show the Jurassic to early Cretaceous thermal episode ranging from 160 Ma to 120 Ma Their corresponding initial $^{87}Sr/^{86}Sr$ ratios correlate well with their whole rock data, indicating that the mineral Rb-Sr system of the investigated granites was redistributed by the postmagmatic thermal event during Jurassic to early Cretaceous. The initial ${\varepsilon}Sr$ values for the CFGR (64.27 to 94.81) tend to be significantly lower than those for the SFGR (125.43 to 167.09). Thus it is likely that there is a marked difference in the magma source characteristics between the CFGR and the SFGR, although the possibility of an isotopic resetting event giving rise to a high apparent initial ${\varepsilon}Sr$ in the SFGR can not be ruled out. In contrast to ${\varepsilon}Sr$, both batholiths show a highly resticted and negative values of initial ${\varepsilon}Nd$, which is -14.73 to -19.53 with an average $-16.13{\pm}1.47$ in the CFGR and -14.78 to -18.59 with an average $-17.17{\pm}1.01$ in the SFGR. The highly negative initial ${\varepsilon}Nd$ values in the investigated granitoids strongly suggest that large amounts of recycled old continental components have taken part in their evolution. Furthermore, this highly resticted variation in ${\varepsilon}Nd$ is significant because it requires that the old crustal source material, from which the granitoid-producing melts were generated, should have a reasonably uniform Nd isotopic composition and also quit similar age. Calculated T2DM model ages give an average of $1.83{\pm}0.25Ga$ for CFGR and $1.96{\pm}0.19Ga$ for SFGR, suggesting the importance of a mid-Proterozoic episode for the genesis of two foliated granites. Although it is not possible to determine precisely the source rock compositions for the investigated foliatic granites, the Sr-Nd isotopic evidences indicate that midcrustal or less probably, a lower crustal granulitic source could be the most likely candidate.

전주지역 강수의 황동위원소비와 대기오염원의 추적자로서 그 유용성

나춘기,김선영,전서령,이무성,정재일,Na, Choon-Ki,Kim, Seon-Young,Jeon, Sir-Ryeong,Lee, Mu-Seong,Chung, Jae-Il 대한자원환경지질학회 1995 자원환경지질 Vol.28 No.3

In order to investigate the origin of sulfate in rain waters and to evaluate the feasibility of using sulfur isotope method as a tracer of atmospheric pollutants, the sulfur isotopic ratio of sulfate in rain waters collected in Chonju city from October 1994 to March 1995 was monitored and was compared with those of possible sources proposed by previous works. The pH of rain waters shows an intermediate acidic range from 4.45 to 6.88 and their daily variation appears to be well correlated with to the amount of precipitation. The sulfur isotopic ratios of sulfate in rain waters show a highly restricted range from 0.0 to + 1.8‰. The ${\delta}^{34}S$ values are similar to those of soil and pine tree surrounding Chonju city, but largely deviate from those of China. D-parameter($d={\delta}D-8{\delta}^{18}O$) of rain waters varies from 9.4 to 28.8. The values indicate that the rain waters in Chonju city are originated from the rainy front of China continent. All data obtained from this study suggested that sulfate in the rain waters collected in Chonju city was mainly derived from the sulfur dioxide gas emitted by the petroleum combustion. Therefore, sulfur isotopic study for the precipitation provided an excellent tool for environmental assessment in this region and for tracing the source of atmospheric pollutants.

전주 죽림지역 온천수의 화학적 및 동위원소적 특성

나춘기,이무성,이인성,박희열,김옥배,Na, Choon-Ki,Lee, Mu-Seong,Lee, In-Sung,Park, Hee-Youl,Kim, Oak-Bae 대한자원환경지질학회 1997 자원환경지질 Vol.30 No.1

The purpose of this study is to examine the feasibility of using stable isotopes as a hydrologic tracer, and to elucidate the groundwater circulation system and the source of S component dissolved in thermal water of the Chonju Jukrim thermal spring district based on the O, H and S isotopic variabilities of environmental materials including bedrock, rainwater, surface water, shallow subsurface water and thermal spring water. The ${\delta}^{18}O$ and ${\delta}D$ of subsurface waters and surface water show highly restricted range and plotted on the same meteoric water line as a ${\delta}D=8{\delta}^{18}O+19$ line, and derivate from the mean annual isotopic composition of the rain water but are analogous to those of rain waters precipitated during winter season, indicating that ground waters are originated from the meteoric water and are strongly affected by the seasonal variation of air mass. Thermal spring waters are more depleted in ${\delta}^{18}O$ and ${\delta}D$ than those of shallow ground water and surface water. It can be explained by the difference of recharge area. The hydrochemical properties of subsurface waters and surface water devide into two groups: $Ca(HCO_3)_2$ type including shallow subsurface water and surface water, and $Na(HCO_3)$ type of thermal spring waters. The ${\delta}^{34}S$ values of thermal spring water show very high positive and quitely distinct from those of shallow subsurface water and surface water that are similar to those of bed rocks, indicating that sulfate dissolved in thermal spring water has not only a terrigenic origin, but also originates partially from the foreign source containing very heavy ${\delta}^{34}S$ component such as an ancient sea water. However, the presence of $H_2S$ can not be ignore the affact of the isotopic fractionation to explaine the heavy ${\delta}^{34}S$ of thermal spring water. Overall, the Oxygen and Hydrogen stable isotopes can identify the source and the circulation system of the natural waters and the S-isotopes can provide a crucial clue on tracing the dissolved material transports in the circulation system of the natural water.

폐금속광산 하부 농경지 토양의 중금속오염과 그 복구방법으로서 반전객토의 효율성

나춘기,이무성,정재일,Na, Choon-Ki,Lee, Mu-Seong,Chung, Jae-Il 대한자원환경지질학회 1997 자원환경지질 Vol.30 No.2

In order to investigate the dispersion patterns and contamination level of heavy metals in the soil-ecosystem and to evaluate the efficiency of soil remediation by reversed soil method, soils and plants were collected from the Dongjin Au-Ag-Cu mine area and analysed for heavy metals. The dispersion patterns of heavy metals in soils and plants show that heavy metal pollutions caused by waste rump around Dongjin mine are mainly found in the vicinity of the waste rump and in the southward slanting of mine. Toxic metallic pollutants from the mine influence heavy metal contents in paddy soils in downstream area, and may be a potential sources of heavy metal pollution on crop plants. Soil samples collected from the remediated rice farming field by reversed method show similar levels of heavy metal content to those from the polluted rice farming field, but topsoil enrichment of heavy metals are not found. Heavy metal contents of the rice plants collected from remediated rice farming field are significantly lower than those from polluted rice farming field, and it suggests that the reversed soil method is effective for the reduction of bioavailability of heavy metals.

모악 금·은광산에 방치된 폐석이 주변 수계 및 생태계에 미치는 환경적 영향

나춘기,전서령,Na, Choon-Ki,Jeon, Seo-Ryeong 대한자원환경지질학회 1995 자원환경지질 Vol.28 No.3

The heavy metal contents and their dispersion patterns in stream water, stream sediments, land plants and aquatic larvae collected from the hydrologic system flowing via the wasted ore dump of the Moak Au-Ag mine were investigated systematically in order to evaluate the environmental impacts of the abandoned metal mine. The heavy metal content increases abruptly in the vicinity of the wasted ore dump, then attenuated with increasing distance from the mine area. Attenuating rates were stream water > stream sediments > land plants > aquatic larvae. On the other hand, the cumulative content of heavy metals was stream sediments >aquatic larvae > land plants > stream water. Each element tends to be enriched selectively according to media; Zn > Cu > Cd > Pb in stream water, Zn > Pb > Cu > Cd in stream sediments and land plants, and Zn > Cu > Pb > Cd in aquatic larvae. These results show that the degree of enrichment and dispersion of pollutant extruded from the wasted ore dump are different according to elements and media, and that the circulation system of materials of each medium is different. The heavy metals, especially Cu, Pb and Zn, of polluted downstream sediments occur in high proportions of Fe-Mn oxides and organic bounded forms, which show high potential of a secondary pollution source. The content of heavy metals and their dispersion patterns in stream sediments are different from those of ten years ago; pollution levels of heavy metals were degraded in various ranges. The Zn and Cu-polluted areas were widened whereas Fe and Pb-polluted areas were reduced. In crops collected from the farm lands in downstream area, the pepper was more concentrated in all heavy metal than rice. The pepper showed some contaminated level in Cu(9.7ppm) and Zn(149ppm), and the rice in Zn(90ppm). However, both crops showed no significant level in Cd(<0.2ppm) and Pb(<0.5ppm).

하수슬러지를 이용한 완효성 규산칼륨비료의 제조방법(III) - 적용의 보편성 및 중금속 저감방안 -

나춘기 ( Na Choon-ki ),정일현 ( Chung Il-hyun ) 한국환경기술학회 2001 한국환경기술학회지 Vol.2 No.1

하수슬러지가 가지는 다양한 물리화학적 성상 변화 및 높은 중금속 함량은 하수슬러지를 규산칼륨비료의 규산원으로써 재활용하는데 있어 커다란 제약요소로 작용하고 있다. 따라서 이들 제약요소를 어떻게 극복할 것인가는 하수슬러지의 규산칼륨비료화를 위해 필수적 선결과제이다. 본 연구결과, 하수슬러지의 성상 변화가 규산칼륨비료화에 미치는 영향은 하수슬러지의 유기물 함량과 Ca 함량을 보정인자로 하여 첨가제의 첨가율을 조절함으로써 극복할 수 있음을 알 수 있었다. 위 보정인자 중 Ca의 보정은 다량의 Ca를 함유하는 하수슬러지(회분기준 CaO≥6wt.%)의 경우에만 요구되며, 적정 품질의 규산칼륨비료를 얻기 위한 Ca 함량은 최종 생산물 기준으로 CaO함량이 6~8wt.%의 범위였다. 하수슬러지 중의 중금속 함량은 규산칼륨비료 제조 공정에서 하수슬러지의 일부를 대체하여 석탄회, 제지슬러지, 정수슬러지 및 활석 등의 중금속 희석 보조제를 단독 또는 복합적으로 첨가함으로써 비료성능의 저하없이 효율적으로 저감시킬 수 있었다. 특히 활석은 중금속 희석 보조제로써 뿐만 아니라 규산칼륨비료 제조시 필수 첨가제인 Ca성분과 Mg성분을 대신할 수 있는 기능성 첨가제로서도 작용하는 등 그 효과가 뛰어났다. 결론적으로 하수슬러지를 규산칼륨비료의 제조원료로써 재활용하는데 있어 하수슬러지 성상 의 다양성이나 높은 중금속 함량은 첨가제의 첨가율을 조절하거나 중금속 희석 보조제를 첨가 함으로써 제어 가능하였다. In recycling of sewage sludge as a silicate source in the manufacture of potassium silicate fertilizer(PSF), there are played a significant limiting factor that sewage sludge have highly variable physicochemical properties depending on time and location and high concentration of heavy metals. Therefore, it must be predetermined how to clear their limiting factors in order to the recycling of sewage sludge as PSF. The results obtained from this study suggest that the affect of physicochemical variation of sewage sludge on the manufacturing process of PSF could be successfully cleared by readjustment of additives based on the discrepancy of organic and Ca content between sewage sludges. Ca adjustment was required only in the case of Ca-rich sewage sludge(CaO≥6wt.% in ash), and optimum range of Ca contents to achieve proper PSF quality was 6~8wt.% based on CaO of end product. The heavy metal content could also be reduced by means of individual or combined addition of diluents, such as coal fly-ash, paper mill sludge, water treatment sludge and talc, substituted for some ratio of sewage sludge without any serious degradation of PSF quality. It is worth to note that the talc was acted as heavy metal diluent and simultaneously as multi functional additive can be substituted for Ca and Mg compound which are essential additives for the manufacture of PSF.

흡착제의 흡착특성 규명을 위한 흡착모델의 적용성 평가(1)

나춘기(Choon Ki Na),한무영(Moo Young Han),박현주(Hyun Ju Park) 大韓環境工學會 2011 대한환경공학회지 Vol.33 No.8

본 연구는 흡착제의 흡착특성을 이해하는데 이용되는 각종 흡착모델의 적용성을 평가하는데 목적이 있다. 이를 위해상용의 음이온교환수지(PA-308)를 이용하여 NO₃-에 대한 흡착특성을 회분식 실험을 통해 조사하였다. 흡착등온과 흡착속도실험결과는 일반적으로 널리 이용되고 있는 다양한 흡착등온식과 반응속도식을 통해 모델화하였다. 흡착평형실험은 흡착등온식을 적용하는데 있어 실험조건이 미치는 영향을 확인하기 위해 흡착제의 투여량을 일정한 값으로 고정하고 흡착질의 농도변화에 따른 조건과 흡착질의 농도를 일정한 값으로 고정하고 흡착제의 투여량 변화에 따른 조건으로 나누어 수행하였다. 흡착질의 농도를 변화시키는 조건에서의 흡착평형은 Langmuir와 Freundlich 흡착등온식을 결합한 형태의 Sips 흡착등온식과 Redlich-Perterson 흡착등온식에 의해 수식화가 가능하였다. 한편, 흡착제의 무게를 변화시키는 조건에서의 흡착평형은 단층흡착, 균일표면을 가정하는 Langmuir 흡착등온식과 잘 일치하는 경향을 보였다. 이상의 결과는 NO₃-에 대한 음이온교환수지의 흡착 메커니즘이 흡착실험 조건에 의해 달라질 수 있음을 시사한다. The objectives of this study were to evaluate the applicability of adsorption models for adsorption properties of adsorbents. For this study, adsorption experiment of NO₃-ion using anion exchange resin has been investigated under adsorption equilibrium and kinetic in bach process. Adsorption equilibrium experiment were carried out that two conditions is change of adsorbate concentration and change of adsorbent weight. Experiment results have been analyzed by adsorption isotherm models, energy models and kinetic models. Under the condition of change of adsorbate concentration was best described by Sips and Redlich-Perterson isotherm models. However case of change of adsorbent weight was described by Langmuir isotherm models. It seems reasonable to assume that isotherm model was dominated by multiple mechanism according to experiment condition.

염전 폐간수의 재활용(1): 마그네슘 회수

나춘기 ( Choon Ki Na ),박현주 ( Hyunju Park ) 한국공업화학회 2016 공업화학 Vol.27 No.4

본 연구의 목적은 마그네슘 생산을 위한 원료 물질로서 폐간수의 활용 가능성을 검토하는 것이다. 본 연구에서는 간수에 NaOH를 첨가하여 Mg 이온을 수산화마그네슘(Mg(OH)2)으로 회수하는 침전법을 적용하였다. 간수에 용존되어 있는 Mg 이온은 NaOH 첨가량이 [NaOH]/[Mg] 몰비 2.70∼2.75, pH 9.5∼10.0에서 99% 이상이 제거되었다. 알칼리제로 첨가하는 NaOH 용액의 몰 농도는 Mg의 회수효율에 큰 영향을 미치지 않은 것으로 나타났다. 침전반응을 통해 생성되는 Mg(OH)2의 입도는 주로 알칼리제의 첨가속도에 의해 영향을 받았으며 첨가속도가 느릴수록 증가하였다. 침전반응을 통해 간수 1 L당 100∼120 kg의 Mg(OH)2 (순도 약 94%)을 회수할 수 있었다. 이러한 실험결과들은 천일염산업의 부산물인 간수가 해수마그네시아 생산을 위한 유용자원으로 활용될 수 있음을 알 수 있었다. The purpose of the research was to examine the utilization of waste bittern from salt farm as a source for producing magnesium (Mg). In this work, a precipitation process for recovering Mg, where Mg is precipitated as Mg(OH)2 by the addition of NaOH solution, was investigated. At the NaOH/Mg molar ratios of 2.70 : 1 to 2.75 : 1 and pH 9.5-10, > 99% of Mg could be precipitated from the bittern. The molar concentration of NaOH solution added as an alkaline reagent had no significant influence on the recovery efficiency of Mg precipitate. The particle size of Mg precipitate was strongly affected by the flow rate of caustic addition. The faster the flow rate of caustic addition, the smaller particles were formed. The Mg precipitate recovered was 100-120 g per 1 L of bittern and contained 94% Mg(OH)2 after washing with water. Our results showed that the bittern can be used as a potential resource for Mg production.