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피라졸 유도체를 함유한 폴리알킬플루오렌 공중합체의 향상된 EL 특성
강인남,이지훈,Kang, In-Nam,Lee, Ji-Hoon 한국전기전자재료학회 2010 전기전자재료학회논문지 Vol.23 No.7
We have synthesized new blue electroluminescent polyalkylfluorene-based copolymers [poly(F-co-Py)x:y, where x:y = 99:1 or 95:5 mole ratios] containing the hole-injecting pyrazole derivative [3,3'-(4,6-bis(octyloxy)-1,3-phenylene)bis(1,5-diphenyl-4,5-dihydro-1H-pyrazole] through Ni(0) mediated polymerization, and their electroluminescent properties were investigated. Electroluminescent (EL) devices were fabricated with ITO / PEDOT:PSS (110 nm) / copolymers or PF homopolymer (80 nm) / Ca (50 nm) / Al (200 nm) configuration. Each EL device constructed from the copolymer exhibited significantly enhanced brightness and efficiency compared with a device constructed from the PF homopolymer. The EL device constructed with poly(F-co-Py)99:1 exhibited the highest luminous efficiency and brightness (0.95 cd/A and $2,907\;cd/m^2$, respectively). The achieved luminous efficiency was an excellent result, providing almost a 4-fold improvement on the efficiency obtainable with the a PF homopolymer device. This enhanced efficiency of the copolymer devices results from their improved hole injection and more efficient charge carrier balance, which arises from the HOMO level (~5.83 eV) of the poly(F-co-Py)99:1 copolymer, which is higher than that of the PF homopolyme (~5.90 eV).
불소 함유된 고분자를 이용한 안정한 청색 발광 유기 EL
강인남,Kang In-Nam 한국전기전자재료학회 2006 전기전자재료학회논문지 Vol.19 No.6
We have synthesized new blue light emitting random copolymers, poly(9,9'-n-dioctylfluorene-co-perfluorobenzene-1,4-diyl)s (PFFBs), via Ni(0)-mediated coupling reactions. The weight-average molecular weights ($M_w$) of the PFFB copolymers ranged from 9,000 to 15,000. The PFFB copolymers dissolved in common organic solvents such as THF and toluene. The PL emission peaks of the PFFB copolymers were at around 420, 440, and 470 nm. EL devices were fabricated in ITO/PEDOT/polymer/Ca/Al configurations using these polymers. These EL devices were found to exhibit pure blue emission with approximate CIE coordinates of (0.15, 0.11) at $100cd/m^2$. The blue emissions of these devices might be due to the restriction of the polymer chains to aggregation by introducing of the highly electronegative fluorine moieties. The maximum brightnesses of the PFFB copolymer devices ranged from 140 to $3600cd/m^2$ with maximum efficiencies from 0.2 to 0.6 cd/A. The enhanced efficiency of the PFFB (8/2) copolymer device results from the inhibition of excimer formation by the introduction of the electronegative fluorine moieties into the copolymers.
강인남,이지훈,Kang In-Nam,Lee Ji-Hoon 한국전기전자재료학회 2006 전기전자재료학회논문지 Vol.19 No.6
We have synthesized a new p-type polymer, poly(9,9'-n-dioctylfluorene-alt-phenoxazine) (PFPO), via the palladium catalyzed coupling reaction. The number average molecular weight ($M_n$) of PFPO was found to be 23,000. PFPO dissolves in common organic solvents such as chloroform and toluene. The UV-visible absorption maximum of the PFPO thin film is clearly blue-shifted with respect to that of F8T2, poly-(9,9'-n-dioctylfluorene-alt-bithiophene). The introduction of the phenoxazine moiety into the polymer system results in better field-effect transistor (FET) performance than that of F8T2. A solution processed PFPO TFT device with a top contact geometry was found to exhibit a hole mobility of $2.7{\times}10^{-4}cm^2/Vs$ and a low threshold voltage of -2 V with high on/off ratio(${\sim}10^4$).
강시환(Kang See Whan),강인남(Kang In Nam),이정렬(Lee Jung Lyul) 대한토목학회 2006 대한토목학회논문집 B Vol.26 No.5B
준설작업으로 인해 재부유된 퇴적물로 구성된 탁도플륨의 이송확산 거동을 예측하기 위해 이(1998)가 제안한 수치 해석의 혼합방법(hybrid method)을 사용하여 3차원 수치모형을 개발하였다. 본 모형에서는 이송 및 확산식의 수치해석에 있어 이송 과정은 전방업자추적기법(forward particle-tracking method), 확산 과정은 유한치분기법을 사용하여 수치계산에 있어 무작위 행보(random walk) 방법에 비해 계산시간이 크게 단축되었으며, 수치모의 결과의 정확성도 크게 향상되었다. 본 모형을 검증하기 위하여 1, 2차원 해석해와의 비교, 그리고 Kuo 등(1985)의 3차원 수리해석모형의 계산결과와 비교하였다. 본 모형의 검증 결과는 비교적 해석해와 잘 일치하였다. In order to predict the dispersion of suspended sediment arising from dredging operation in port and navigation channel, a hybrid model for dispersive transport of turbidity plume was developed using Lee's(1998) hybrid method. Using hybrid modeling scheme advection-diffusion equation was solved by the forward particle-tracking method for advection process and by the fixed Eulerian grid method for diffusion process. To examine numerical model simulation ill accuracy, the simulated results for 1-D, 2-D, and 3-D cases were compared with the analytical solutions including Kuo, et al's (1985) 3-D mathematical model. The model results were in a good agreement with the analytical solutions and mathematical model for the dispersion of turbidity plume.