액정구조가 셀룰로오스 섬유의 역학적 성질에 미치는 영향

윤성호,강태진,김선경,Yun, Seong-Ho,Gang, Tae-Jin,Kim, Seon-Gyeong 한국섬유공학회 1989 한국섬유공학회지 Vol.26 No.6

Cellulose powders were dissolved in the mixture of liquid ammonia and ammonium thiocyanate at room temperature. The cellulose solutions at the mesomorphic concentration were extruded into methanol bath by the dry-wet spinning condition. The tenacity and initial tensile modulus of the fiber increased with the anisotropic phase volume fraction of the solution but decreased with the specific layer birefringence of the mesomorphic solution. The spinning test results showed that the cellulose anisotropic phases were easily deformed by shear deformation that it indicates high potential for spinning this mesomorphic solution into a highperformance cellulosic fibers.

축약법에 의한 구조물 결합부의 동적 거동 예측

윤성호,Yun, Seong-Ho 한국전산구조공학회 2014 한국전산구조공학회논문집 Vol.27 No.6

기계 구조물에서 부재의 결합부가 시스템 전체의 동적 거동에 매우 심각한 영향을 미치고 있다. 따라서 동적인 응답의 정확한 예측은 이러한 결합부를 어떻게 모델링 하느냐에 달려 있다고 해도 과언이 아니다. 본 논문에서는 결합부의 유연성을 정량적으로 표현하기 위하여 서로 대칭이고 마주보는 외팔보의 중앙에 선형 및 비틀림 스프링을 결합부에 이식하였다. 이를 바탕으로 결합부의 강성 변화에 따른 시스템의 재해석은 축약법과 유한요소법으로 계산하였다. 이항 급수로 표현되는 기저 벡터의 수에 따라서 전체 모델의 크기는 획기적으로 감소되어 축약 모델로 매우 짧은 시간에 효율적으로 계산할 수 있었다. 본 연구에서는 두 가지 경우의 수치해석 예가 제시되어 축약 모델의 결과가 정밀해와 잘 일치함을 보여주고 있다. Joints, fasteners or connected parts frequently have a significant effect on the dynamical behavior of assembled mechanical structures. Therefore, the analytical prediction of structural responses depends on the accuracy of joint modeling. This paper deals with the formulation and analysis of dynamic mechanism for joint flexibilities whose relevant magnitudes of stiffnesses are investigated by using linear and torsional springs. The equation of motion is derived by using a generic joint in the middle of clamped-clamped beam. A reanalysis due to changes in magnitudes of joint stiffnesses is based on the reduced analysis where the binomial series terms are used as basis vectors. The solution procedures are straightforward and the method can be readily used with a general finite element method. The computational effort needed by this approach is usually much smaller than the effort needed for complete vibration analysis. Two numerical examples show that accurate results are obtained efficiently by reducing the number of degree in the reduced model.

최신 기술동향: Biolog사의 Phenotype Microarray (PM) Technology

윤성호,Yun, Seong-Ho 한국미생물학회 2006 微生物과 産業 Vol.32 No.2

수계 내 테트라사이클린, 설파다이아졸, 트리톤 X-100 혼합물의 광분해

윤성호,이성종,조은혜,문준관,Yun, Seong Ho,Lee, Sungjong,Jho, Eun Hea,Moon, Joon-Kwan 한국환경농학회 2021 한국환경농학회지 Vol.40 No.1

BACKGROUND: Chemicals such as antibiotics and surfactants can enter agricultural environment and they can be degraded by natural processes such as photolysis. These chemicals exist in mixtures in the environment, but studies on degradation of the mixtures are limited. This study compares the photodegradation of Triton X-100 (TX) and antibiotics [tetracycline (TC) and sulfathiazole (STH)] when they are in a single solution or in mixtures. METHODS AND RESULTS: TC, STH, and TX solutions were exposed to UV-A for the photodegradation tests for 14 days. The residual TC, STH, and TX concentrations were analyzed by using HPLC. The TC degradation was similar regardless of the presence of TX, while the TX degradation was lower in the presence of TC. The STH degradation was similar regardless of the presence of TX, while the TX degradation was greater in the presence of STH. However, the STH degradation was slower in the TC-STH-TX mixture than in the STH-TX mixture. Also, the TX degradation was negligible in the TC-STH-TX mixture. The results show that the photodegradation of TC, STH, and TX can be different in mixtures. This can be attributed to the different emission and absorption wavelengths of each compound and interaction between these compounds and photoproducts. CONCLUSION: Overall, this study emphasizes that photodegradation of single chemicals and chemical mixtures can be different, and more studies on single compounds as well as mixtures are required to understand the fate of chemicals in the environment in order to manage them properly.

로터 시스템 회전운동의 정식화 및 해석

윤성호,임리민,Yun, Seong-Ho,Ren, Li-Min 한국전산구조공학회 2008 한국전산구조공학회논문집 Vol.21 No.5

본 논문은 로터 시스템의 디스크 회전운동을 표현하는데 있어 운동방정식을 통합하는 과정에서 기존 연구자들이 채택한 오일러 각 사용법이 일관성이 없음을 지적하였다. 기존 연구자들은 오일러 각 순서가 달라서 속도와 운동에너지도 달리 산정하였음은 물론, 운동방정식은 오직 선형 시스템만 취급해 왔다 이러한 오일러 각 사용법의 단점을 극복하기 위하여 회전운동을 더욱 단순하게 매개화할 수 있는 4원법(quaternion)과 구 좌표계를 적용하여 비선형 시스템을 도출하였다. 이를 바탕으로 수치해석을 통하여 기존 방법과 비교하여 제안한 방법의 신뢰성과 우수성을 보였다. This paper indicates that the use of Euler angles lacks in its consistency and exactness of analysis when it was applied to incorporate the rotational equation of motion for rotor systems by previous researcher. Kinetic energy and angular velocity are different from case to case depending on the way of choosing Euler angles and thus only the linear system has been investigated even though the rotor system has a very nonlinear behavior. A new methodology is applied by using both spherical coordinate and quaternion in the rotor rotation to overcome weaknesses of Euler angles and shows its superiority It is found through numerical examples that the use of quaternion will be a more useful and valid tool to derive the numerical model of the rotor system.

A Novel Iron(III) Complex with a Tridentate Ligand as a Functional Model for Catechol Dioxygenases: Properties and Reactivity of [Fe(BBA)DBC]$ClO_4$

윤성호,이호진,이강봉,Yun, Seong Ho,Lee, Ho Jin,Lee, Gang Bong Korean Chemical Society 2000 Bulletin of the Korean Chemical Society Vol.21 No.9

[FeIII(BBA)DBC]ClO4 as a new functional model for catechol dioxygenases has been synthesized, where BBA is a bis(benzimidazolyl-2-methyl)amine and DBC is a 3,5-di-tert-butylcatecholate dianion.The BBA complex has a structuralfeature that iron cent er has a five-coordinate geometry similar to that of catechol dioxygenase-substrate complex.The BBA complex exhibits strong absorptionbands at 560 and 820 nm in CH3CN which are assigned to catecholate to Fe(III) charge transfer transitions. It also exhibits EPR signals at g = 9.3 and 4.3 which are typical values for the high-spin FeIII (S = 5/2) complex with rhombicsymmetry. Interestingly, the BBA complex reacts with O2 within an hour to afford intradiol cleavage (35%) and extradiol cleavage (60%) products. Surprisingly, a green color intermediate is observed during the oxygenation process of the BBA com-plex in CH3CN. This green intermediate shows a broad isotropic EPR signal at g = 2.0. Based on the variable temperature EPR study, this isotropic signalmight be originated from the [Fe(III)-peroxo-catecholate] species havinglow-spin FeIII center, not from the simple organic radical. Consequently,it allows O2 to bind to iron cen-ter forming the Fe(III)-superoxide species that converts to the Fe(III)-peroxide intermediate. These present data can lead us tosuggest that the oxygen activation mechanism take place for the oxidative cleavingcatechols of the five-coordinate model systems for catechol dioxygenases.

영구자석의 척력을 이용한 자전거 완충장치 해석

윤성호,Yun, Seong-Ho 한국전산구조공학회 2016 한국전산구조공학회논문집 Vol.29 No.1

자전거의 안장 지주에 영구자석의 척력을 이용하여 완충장치를 설치하고자 자기 해석용 상용프로그램을 이용하였다. 유한요소법으로 구한 해석치를 실험치와 비교하여 유한요소 해석치의 신뢰성을 확보하였다. 그 후에 3 자유도계의 자전거 동역학 모델을 완성하고 자석의 크기에 상응하는 등가 스프링 강성값을 모델에 이식하였다. 자전거의 동역학 모델에서 전륜과 후륜은 주행면의 비평탄도에 의한 입력을 부담하도록 하였다. 전륜과 후륜이 독립적으로, 또는 동시에 반삼각 범프(half-triangular bump)와 정현파 굴곡로(sinusoidal road)를 통과할 때의 동적 거동을 살펴보았다. 운전자와 프레임의 수직거동, 주행방향의 피칭 거동을 관찰하였으며 자전거의 완충 시스템을 보다 구체화할 수 있는 기반을 마련하였다. One commercial package for magnetic analysis was used to apply repulsive forces of permanent magnetics to bicycle cushion system. Reliabilities of finite element analysis were acquired by comparing with those of experimental measurements. Equivalent spring stiffnesses corresponding to various sizes of magnetics were implemented into the bicycle dynamic model with three degree of freedom. Input force caused at front and rear wheels due to road unevenness was considered in the dynamic model. Dynamic behaviors were observed in terms of vertical displacements of the rider and the front reach as well as pitching displacement of the mass center when the bicycle ran over half-triangular bump. The methodology suggested in this paper by the finite element analysis and numerical model will be an useful tool for more accurate prediction of cushion design for any vehicle system if magnetic forces are utilized.

유한요소를 이용한 유연보의 동역학적 정식화 및 해석

윤성호,엄기상,Yun Seong-Ho,Eom Ki-Sang 한국전산구조공학회 2005 한국전산구조공학회논문집 Vol.18 No.4

본 논문에서는 기하학적으로 비선형인 유연한 Timoshenko 보의 대변위 운동방정식에 유한요소를 사용하여 정식화하였다. 비선형 구속방정식은 라그랑지 상수를 이용하여 운동방정식에 통합되었다. 정식화하는 과정과 수치해석에서 선형과 비선형 영향을 파악하였고, 코리올리스(Coriolis)힘과 회전자(Gyroscopic)힘의 효과는 관성력과 감쇠력과는 달리 일반적인 외력으로 간주하여 해석할 수 있었다. Newmark의 시간적분과 Newton-Raphson 반복법을 사용한 수치예제를 통해 정식화의 효용성을 보여주었다. This paper established the dynamic model of a flexible Timoshenko beam capable of geometrical nonlinearities subject to large overall motions by using the finite element method. Equations of motion are derived by using Hamilton principle and are formulated in terms of finite elements in which the nonlinear constraint equations are adjoined to the system using Lagrange multipliers. The Newmark direct integration method and the Newton-Raphson iteration are employed here for the numerical study which is to demonstrate the efficiency of the proposed formulation.

유한회전과 4원수를 이용한 유니버설 조인트 시스템의 기구해석 비교

윤성호,Yun, Seong-Ho 한국전산구조공학회 2010 한국전산구조공학회논문집 Vol.23 No.2

본 논문에서는 자동차의 구동계 등에 사용되는 유니버설 조인트의 기구학적 거동을 관찰하기 위하여 오일러 각과 4원수(quaternion)를 적용한 두 가지 방법을 비교하였다. 이와 관련된 종래의 연구자들은 오일러 각을 사용하여 회전체의 동적인 거동을 해석하였으나 결과의 일관성과 정확도가 부족하였다. 유니버설 조인트 시스템 해석에서도 이러한 단점을 확인하였고 이를 극복하고자 4원수를 적용하였다. 구동시 원동축 1개축 회전과 원동축과 직각방향 회전축 2개의 축이 동시에 존재하는 경우에 대하여 수치해석을 통하여 기하학적인 물리량을 산출하였다. 4원수를 채용한 방법이 세차운동을 포함하는 2개축 회전에서 유니버설 조인트 시스템을 해석하는데 있어 더욱 유용한 방법임을 보여 주었다. This paper deals with the comparison of analysis methodologies by applying both Euler angle and quaternion to observe the kinematical behavior of the universal joint system used as an automotive drive-shaft. At first, conventional approaches are applied to predict a kinematical behavior by introducing only Euler angles into the universal joint system, but turns out to be lack in consistency and reliability of the analysis. Then to overcome this deficiency in numerical analysis a different methodology is proposed by using quaternion in this system. Its corresponding advantage is discussed in terms of kinetic energy, rotational velocity and rotational displacement. The application of quaternions in the numerical experiment is shown to be a more useful and valid way of establishing the ideal analytical model of the universal joint system.

부재간 결합부의 동적 특성 분석 및 강성 예측

윤성호(Seong-Ho Yun) 한국기계가공학회 2019 한국기계가공학회지 Vol.18 No.2

This paper describes the analysis of dynamic characteristics and prediction of the stiffness for the joint between structural members. In the process of deriving the governing equations, the stiffness values responsible for the moment and shear force were modelled by using linear and torsional springs in the middle of a clamped-clamped beam. The sensitivities of the natural frequency and modal assurance criterion were investigated as a function of the dimensionless linear and torsional spring stiffness. The reliability of the predictions for the linear and torsional stiffness values was verified by the inverse computations of the stiffness matrix. The predictive and exact theoretical stiffness values were compared for the stiffness element in the finite element formulation, and their results show an excellent correlation. It is strongly anticipated that although the proposed methodology is currently limited to the analytical utilization, it will provide a useful tool to estimate unknown joint stiffness values based on the experimental natural frequency and mode shape.