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        Hydrothermal stability of different zeolites in supercritical water: Implication for synthesis of supported catalysts by supercritical water impregnation

        Yuechao Zhang,Yingjie Li,Junjie Gu,Senlin Tian,Ping Ning 한국화학공학회 2018 Korean Journal of Chemical Engineering Vol.35 No.9

        Supercritical water (SCW) impregnation is an efficient and feasible method that has been used to prepare highly dispersed supported catalysts, but few studies have investigated the stability of support materials in supercritical water. Thus, our aim was to investigate the hydrothermal stability of zeolite supports (ZSM-5, TS-1, ZSM-35, HY, 13X, Beta, SAPO-11 and SAPO-34) as model compounds in supercritical water. Results showed that almost all of zeolites suffered from crystallinity change, structural properties degradation, obvious desilication and dealumination. The decrease of surface areas and the collapse of crystalline structures in HY, 13X, Beta, SAPO-11 and SAPO-34 were more serious compared to ZSM-5, ZSM-35 and TS-1. The micropore areas and acidity of all SCW-treated zeolites were reduced. 13X with lower Si/Al ratio had higher hydrothermal stability than HY due to the formation of extra-framework Al (EFAL). EFAl also generated strong Lewis acid sites determined by ammonia temperature-programmed desorption and 27Al magic angle spinning nuclear magnetic resonance. Desilication and dealumination were simultaneous, and led to the increase of framework Si/Al ratio. ZSM zeolites (ZSM-5, ZSM-35 and TS-1) had higher hydrothermal stability than HY, 13X, Beta, SAPO-11 and SAPO-34 in SCW.

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        A Bi-Target Based Mobile Relay Selection Algorithm for MCNs

        ( Huijun Dai ),( Xiaolin Gui ),( Zhaosheng Dai ),( Dewang Ren ),( Yingjie Gu ) 한국인터넷정보학회 2017 KSII Transactions on Internet and Information Syst Vol.11 No.11

        Multi-hop cellular networks (MCNs) reduce the transmit power and improve the system performance. Recently, several research studies have been conducted on MCNs. The mobile relay selection scheme is a rising issue in the design of MCNs that achieves these advantages. The conventional opportunistic relaying (OR) is performed on the single factor for maximum signal-to-interference-plus-noise ratio (SINR). In this paper, a comprehensive OR scheme based on Bi-Target is proposed to improve the system throughput and reduce the relay handover by constraining the amount of required bandwidth and SINR. Moreover, the proposed algorithm captures the variability and the mobility that makes it more suitable for dynamic real scenarios. Numerical and simulation results show the superiority of the proposed algorithm in both enhancing the overall performance and reducing the handover.

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