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      • Chalcogenization-Derived Band Gap Grading in Solution-Processed CuIn<sub><i>x</i></sub>Ga<sub>1–<i>x</i></sub>(Se,S)<sub>2</sub> Thin-Film Solar Cells

        Park, Se Jin,Jeon, Hyo Sang,Cho, Jin Woo,Hwang, Yun Jeong,Park, Kyung Su,Shim, Hyeong Seop,Song, Jae Kyu,Cho, Yunae,Kim, Dong-Wook,Kim, Jihyun,Min, Byoung Koun American Chemical Society 2015 ACS APPLIED MATERIALS & INTERFACES Vol.7 No.49

        <P>Significant enhancement of solution-processed CuInxGa1-x(Se,S)(2) (CIGSSe) thin-film solar cell performance was achieved by inducing a band gap gradient in the film thickness, which was triggered by the chalcogenization process. Specifically, after the preparation of an amorphous mixed oxide film of Cu, In, and Ga by a simple paste coating method chalcogenization under Se vapor, along with the flow of dilute H2S gas, resulted in the formation of CIGSSe films with graded composition distribution: S-rich top, In- and Se-rich middle, and Ga- and S-rich bottom. This uneven compositional distribution was confirmed to lead to a band gap gradient in the film, which may also be responsible for enhancement in the open circuit voltage and reduction in photocurrent loss, thus increasing the overall efficiency. The highest power conversion efficiency of 11.7% was achieved with J(sc) of 28.3 mA/cm(2), V-oc of 601 mV, and FF of 68.6%.</P>

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        저주파수 및 저입력전압용 박막형 다중접합 열전변환기

        황찬순,이형주,김진섭,이정희,박세일,권성원 한국센서학회 2002 센서학회지 Vol.11 No.3

        저주파수의 저전압용 크로멜-알루멜 다중접합 열전변환기를 개발하고자 NiCr 히터의 두께를400 nm, 600 nm 및 800 nm로 변화시켰다. 40 Hz∼10 kHz의 직류 역방향 주파수 범위로 0.5 V의 교류 실효전압을 열전변환기에 인가시켰을 때 히터의 두께가 400 nm인 열전변환기가 ±0.51∼±1.69 ppm 범위의 열전효과에 의한 교류-직류 전압 변환오차를 나타내었고, 열전효과 및 주파수에 의한 교류-직류 변환오차는 40 Hz∼l MHz의 주파수 범위에서 ±40∼±115 ppm 범위를 나타내어, 저주파수의 저전압용으로 사용할 수 있었다. NiCr-heaters with three different thicknesses ranging from 400 nm to 800 nm were fabricated and their characteristics were compared for the purpose of developing a chromel-alumel multijunction thermal converter for low input voltage with low frequency. The thermoelectric effect-induced AC-DC voltage transfer difference of the thermal converter with a built-in NiCr-heater of 400 nm-thickness was ±0.51∼±1.69 ppm in the DC reversing frequency of 40 Hz∼10 kHz with appling 0.5 V_rms and the difference was increased to ±40∼±115 ppm in the frequency of 40 Hz~l MHz, when both thermoelectric effects and frequency effects were considered, showing the thermal converter would be suitable for the low input voltage application with low frequency.

      • Interleukin-2가 Mouse 폐장의 폐포간 중격의 미세구조에 미치는 영향

        황세진,김종우,정호삼,이규식 한양대학교 의과대학 1990 한양의대 학술지 Vol.10 No.1

        Interleukin-2, a kind of lymphokine which is produced by activated T-lymphocytes during an immune response, is known to act not only as a growth factor for many cells of immune system but stimulates differentiation of cells of immune system. Although interleukin-2 is a useful agent for cancer immunotherapy and inhibiting agent of tumor cell metastasis, administration of interleukin-2 to cancer patient may cause various side effects such as pulmonary edema due to capillary leakage. In this experiment the author pursued the effects of interleukin-2 on ultrastructure of interalveolar septum in lung of mouse. Healthy male mice weighing about 20gm were used as experimental animals and divided into control group and experimental group. During the experiment water and foods were given ad libitum. Animals of control group were injected 0.2 ml of distilled water and animals of experimental grouup were injected 2 million units per kg body weight of interleukin-2 intraperitoneally Experimental animals were sacrified at 3 hours, 6 hours, 12 hours, 24 hours, 48 hours and 72 hours after administration and lung specimens were obtained. All specimens, which were prefixed in 2% glutaradehyde-2.5% paraformaldehyde and postfixed in osmium tetraoxide were dehydrated and embedded in Epon Araldite 502. Ultrathinsection about 600-800 in thickness, and uranyl acetate and lead citrate double stain were performed and all electron microscopic specimens were observed with JEM 100cx-II electron microscope. The results obtained were as follows: 1. The type I pneumocyte of interalveolar septum of lungs in interleukin-2 treated mice were swollen, separated from basal lamina. 2. Capillary endothelial cell of interalveolar septum of lungs in interleukin-2 treated mice were swollen, and pinocytic vesicles in endothelial cell were enlarged and increased in number. 3. Lamellar bodies of type II pneumocytes of interalveolar septum of lungs in interleukin-2 treated mice were enlarged, and vacuolized. 4. Mitochondria and microvilli of type II pneumocytes of interalveolar septum of lungs in interleukin-2 treated mice were decreased in number. It is consequently suggested that interleukin-2 induces intracellular edema of both the type I pneumocyte and the endothelial cell and damages to type II pneumocyte of interalveolar septum of lung in mice but alveolar epithelial cells and endothelial cells are recover as time goes by.

      • 흰쥐 갑상선 소포세포의 분화에 관한 전자현미경적 연구

        황세진,정호삼,유신철,이규식 한양대학교 의과대학 1991 한양의대 학술지 Vol.11 No.1

        The thyroid gland is an endocrine organ which is mainly derived from endodermal cell of the primitive pharynx. It is well known that time of morphological and functional maturation of thyroid gland is so variable among the species of animal that functionl maturation of thyroid gland of the rat occurs only after birth of the animal, while the human fetal thyroid gland can secrete thyroid hormones at 10-14 weeks of gestation. In this study the author pursued the ultrastructural differentiation of thyroid follicular cells of rats in the late fetal and early postnatal lives. The fetal rats of 18th and the 20th day of gestation and rats of the 1st, the 7th, the 14th and the 21st day of postnatal life were sacrificed and thyroid glands were extracted. Rats of the 8th weeks of postnatal life were served as control group. All specimens prefixed in 2% glutaraldehyde-2.5% paraformaldehyde and postfixed in osmium tetraoxide, were dehydrated and embeded in Epon Araldite 502. Ultrathin section about 600-800 in thickness were made with LKB ultramicrotome and stained with uranyl acetate and lead citrate and lead citrate All electron microscopic preparations were observed with JEM 100cx-II electron microscope The result obtained were as follows: 1. The nucleus of the follicular cell in the rat thyroid gland was composed of euchromatin at the 18th day of gestation, some unclei with euchromatin and heterochromatin were observed at the 20th day of gestation, and all nuclei of the follicular cells were composed of euchromatin and heterochromatin after the 1st day of postnatal life. 2. Rough endoplasmic reticulum of the follicular cell in the rat thyroid gland was consisted of column shaped scant cisternae at the 18th day of gestation, and rough endoplasmic reticulum with unmerous dilated cisterne was observed at the 7th day of gestation. 3. The Golgi complex of the follicular cell in the rat thyroid gland was composed of narrow cisternae and small sized vesicles at the 18th day of gestation. Folgi complex with wide cisternae and large sized vesicles and vacuoles was observed at the 14th day of posnatal life. 4. Mitochondria of the follicular cell in the rat thyroid gland were scanty at the 18th day of gestation and number of mitochondria increased during development of thyroid gland. 5. Lysosmes of the follicular cell in the rat thyroid gland were observed from the 1st day of postnatal life. 6. Collid lumen and microvilli of the thyroid follicle were observed from the 20th day of gestation and the matured colloid lumen was observed at the 1st day of postnated life. It is consequently suggested that the thyroid follicleis are formed from the 20th day of gestation to the 1st day of postnatal life, and cytoplasmic organelles of the folliculat cell are matured morphologically between the 7th and the 14th day of postnatal life in albino rats.

      • Bleomycin이 Mouse신사구체 및 근위요세관 상피세포의 미세구조에 미치는 영향

        김진택,황세진,정호삼,이규식 한양대학교 의과대학 1988 한양의대 학술지 Vol.8 No.2

        Bleomycin, a glycopeptide antibiotic isolated from Streptomyces Verticillus, has been used as an anticancer drug active against human squamous cell carcinoma of skin and lung. It is well known that bleomycin inhibits DNA synthesis of tumor cell by scissoring DNA molecule and inhibiting DNA polymerase activity. Although bleomycin is very effective on various human cancers, it may damage certain normal cells to cause pulmonary and skin toxicity. In this experiment, the author pursued the effect of bleomycin on the mouse kidney, observing the ultrastructural changes in the proximal convoluted tubular epithelial cells and glomeruli. Healthy male mice(ICR strain) were used as experimental animals which were divided into two groups, the control and bleomycin treated groups. The bleomycin treated groups were subdivided into group of 3 times successive bleomycin treated and group of 7 times successive bleomycin treated. All experimental animals were given food and water ad libitum. The animals of bleomycin treated group were administered bleomycin 3 times and 7 times respectively, in a dose of 20 units per kg of body weight with 3 days interval. The experimental animals were sacrified in 24 hours after final administration of bleomycin. The specimens obtained from cortical region of left kidney were stained with uranyl acetate and lead citrate by the double contrast method and were observed with JEM 100cx-Ⅱ electron microscope. The results obtained were as follows: 1. In the epithelial cells of the proximal tubule the pinocytic vesicles were increased in number and also numerous autophagic vacuoles and the multivesicular bodies were found. 2. The deformed mitochondria and the dilated cisternae of rough endoplasmic reticulum were appeared in the epithelial cells of proximal renal tubule. 3. The basal infoldings were dilated and basement membrane were thickened and irregulary arranged at the basal portion of the epithelial cells of proximal tubule. 4. In the glomeruli the lamine densa of filterating membrane were irregulary arranged and thickened and many of the pedicles of podocytes were fusal together. It is consequently suggested that bleomycin damages both proximal convoluted tubular epithelial cells and glomeruli in mice kidney.

      • 록인 증폭기에 의한 L(C,R) 회로 공진점 결정의 한 방법

        정세민,홍진태,최규황,노지현 東亞大學校 附設 基礎科學硏究所 1994 基礎科學硏究論文集 Vol.11 No.1

        L(C,R)회로의 공진점을 결정하기 위해 록인 증폭기에 의한 sequential spectrum analysis(SSA)법을 적용해 보았다. 시료는 변압기였으며, 단일 소인방식과 왕복 소인방식을 비교해 보았다. 또한 실험 결과의 신뢰도를 확인해보기 위해 실험결과를 변압기의 제작사 자료와 Q 미터(HP,4277A USA)에 의한 측정 결과와 비교하였다. 제작사 자료에 의하면 시료의 공진점은 두 권선의 각각은 5kHz(10kHz/2)였으나, 왕복소인에 의한 측정에서 시료의 공진점은 5.1kHz, 실험 결과로부터 계산된 Q 값은 4.3으로 주어졌고, 단일 소인법에 의해서는 공진점이 5.78KHz로 주어졌으며, Q 미터에 의한 Q 값은 4.9(9.8/2)였다. 실험 결과들과 기준 Q 미터에 의한 측정결과를 비교해본 결과, 양방향 소인법이 단일 방향소인법 보다 더 신뢰할 수 있음을 알 수 있었으며, SSA법에 의한 측정이 기존의 상용 전문기기에 의한 측정에 못지 않음과 전문기기의 측정 하한 문제를 극복하는 좋은 대안이 될 수 있음을 알 수 있었다. An accurate method named the sequential spectrum analysis(SSA) using a lock-in amplifier(LIA) of the heterodyne type was investigated to determine the resonance frequency of a LC(C,R) circuit : A heavy winding transformer was used as an inductor in the circuit. In this experiment, two types of the sweep method-one way and round trip method were examined. The resonance frequency of each method were compared with the manufacturer's data and those by the reference Q meter(HP,4277A, USA)for the experimental confidence: Measured resonance frequency by the round-trip method was 5.1 kHz, Q value at this frequency was about 4.3, while those by the single-sweep method were given by 5.78 kHz for the resonance frequency, 2.3 for the Q. On the other hand, the resonance frequency of manufacturer's data was 5 kHz and Q value by the reference Q meter was 4.9(9.8/2)at that frequency. From the comparison, it might be concluded that the SSA by the round-trip method was more reliable and accurate than the one-way method and relatively inexpensive, good alternative with respect to the professional instrument.

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