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진경호,채명진,이규,이교선,Chin, Kyung-Ho,Chae, Myung-Jin,Lee, Giu,Lee, Kyo-Sun 한국건설관리학회 2009 한국건설관리학회 논문집 Vol.10 No.6
Infrastructure asset management can be defined as the long term and cost effective management strategy to meet the required service level. In most developed countries, the major motivations of the introduction of asset management are increment in number of assets, extension of maintenance field, accounting approaches of public facilities, performance-based FM(Facility Management), limitations of public funds and public-private partnership, life cycle cost approach, and the development of information technology. This paper discusses the strategic and stepwise methods of introducing infrastructure asset management. Strategic approaches are suggested to develop the practical methods of condition and value assessment of assets, and long-term capital investment plan for optimized decision making(ODM). Required systematic processes are analyzed in terms of resource and technical limitations and detailed implementation plan for each development phases are suggested. 자산관리는 사회기반시설물의 요구되는 서비스수준을 만족시키기 위한 장기적인 비용 효율적 관리라고 정의할 수 있다. 선진외국의 경우 사회기반시설물의 증가와 유지관리 시장의 확대, 유지관리를 위한 회계적 접근방식, 성능 중심의 시설관리, 자원의 한계와 민간과의 협업 강화, 생애주기 비용 개념의 확대 적용, 정보화기술의 발전이 동인이 되어 자산관리가 도입되었다. 본 논문에서는 국내외 자산관리의 현황 및 문제점을 분석하여 사회기반시설물의 자산관리체계 도입 방안과 추진 전략에 관한 연구를 수행하였다. 먼저, 국가자산의 합리적인 평가와 동시에 유지관리를 포함한 장기적 최적 투자 의사결정을 수행할 수 있는 국가적 차원의 자산관리체계 구축을 위해 국내의 도입 환경을 분석하여 도입방안을 모색하였다. 그리고 성공적 사회기반시설물 자산관리체계 도입을 위해 제도적, 프로세스적, 자원적, 기술적 측면에서 요구되는 핵심 전략을 분석하여 세부전략별로 실천과제를 분석하여 단계별 추진 전략을 제시하였다.
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폴리에스터 폴리올과 폴리우레탄의 합성과 구조분석에 대한 연구
진경호 ( Kyung Ho Jin ),조을룡 ( Ur Ryong Cho ) 한국고무학회 2014 엘라스토머 및 콤포지트 Vol.49 No.1
Sebacic acid, isophthalic acid, ethylene glycol, neopentyl glycol를 각각 1몰씩 사용하여 폴리에스터 폴리올을 합성하였다. 합성된 폴리올의 수산기가는 56.6 mg KOH/g이고 분자량은 1,980 g/mole 이었다. 합성한 폴리에스터 폴리올에 toluene diisocyanate와 쇄연장제로 ethylene glycol, 1,4-butandiol, 1,2-propylene glycol을 각각 넣고 폴리우레탄을 합성하였다. GPC로 측정한 3 가지 폴리우레탄의 분자량은 각각 5850, 6160, 6480 g/mole 이었다. FT-IR에 의한 구조분석에서 폴리에스터 폴리올은 3600 cm-1 부근에서 -OH 기가 관찰되었고, 2950 cm-1 에서 sebacic acid의 -CH shoulder가 나타났으며, ester의 carbonyl group은 1730 cm-1 부근에서 나타났고, isophthalic acid의 benzene ring은 1600 cm-1, 740 cm-1에 관찰되었다. 폴리우레탄의 -OH 피크가 3600 cm-1 에서 나타났고, 3300 cm-1 부근과 1530 cm-1 에서 우레탄기 중의 .NH 기를 확인할 수 있었다. 1H NMR에 의한 구조분석에서 폴리에스터 폴리올은 sebacic acid는 1.3, 1.5, 2.1 ppm에서, isophthalic acid는 7.3, 8.1, 8.7 ppm에서, ethylene glycol은 4.2 ppm에서, neopentyl glycol은 0.8, 3.2, 3.9 ppm에서 관찰되었다. 폴리우레탄의 경우에는 폴리에스터 폴리올과 유사하나 toluene diisocyanate의 도입에 의한 벤젠고리의 피크가 7 ppm에서 미약하게 나타났다. Polyester polyols were synthesized by using each one mole of sebacic acid, isophthalic acid, ethylene glycol, and neopentyl glycol. The synthesized polyol had 56.6 mg KOH/g of hydroxy value and 1980 g/mole of molecular weight. From FT-IR structure analysis of polyester polyol, Hydroxy group(-OH) was observed around 3600 cm-1, -CH shoulder of sebacic acid at 2950 cm-1, carbony group of ester around 1730 cm-1, and benzene ring of isophthalic ring was represented at 1600 cm-1, 740 cm-1. In case of polyurethane, hydroxy peak was showed at 3600 cm-1, and .NH group around 3300 cm-1, 1530 cm-1. From 1H NMR measurement of polyester polyol, it was found that sebacic acid was represented at 1.3, 1.5, 2.1 ppm, isophthalic acid at 7.3, 8.1, 8.7 ppm, ethylene glycol at 4.2 ppm, and neopentyl glycol at 0.8, 3.2, 3.9 ppm, respectively. In the polyurethane, it is almost the same as spectrum of polyester polyol, but showed very week peak at 7 ppm by benzene ring of toluene diisocyanate.
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세바식 산으로 중합된 폴리에스터 폴리올을 원료로 사용한 폴리우레탄 접착제에 관한 연구
진경호 ( Kyung Ho Jin ),김민수 ( Min Su Kim ),조을룡 ( Ur Ryong Cho ) 한국고무학회 2013 엘라스토머 및 콤포지트 Vol.48 No.3
본 연구에서는 피마자유 유래의 sebacic acid를 isophthalic acid 및 glycol과 병용하여 폴리에스터 폴리올을 중합하고 이어서 폴리우레탄 접착제를 제조하였다. 접착력을 측정한 결과에서 sebacic acid를 병용한 폴리올이 adipic acid를 사용한 폴리올 보다 응집에너지가 커서 접착력이 우수하게 나타났고, glycol은 선형구조 보다 메틸기를 포함하는 가지구조가 더 좋은 접착력을 보였다. 쇄연장제는 1,4-butane diol(BD)를 사용한 것이 가장 접착력이 좋게 나타났다. 또한 TGA 측정결과 내열성은 BD가 가장 높고, 1,2-propylene glycol(PG)가 다음, ethylene glycol(EG)가 가장 낮았다. DMA 측정에서 유리전이온도는 PG, EG, BD의 순서로 높게 나타났다. In this study, sebacic acid made from castor oil was used as monomer with isophthalic acid and glycols for polyester polyol synthesis. Polyurethane adhesive was synthesized from the various polyester polyol. From the result of adhesion strength test, polyester polyol made from sebacic acid showed better adhesive force than that of adipic acid due to higher cohesive energy. Branched glycol containing methyl group represented better adhesion than linear glycol. In the chain extender, adhesion strength increased going from PG, EG, BD. From the measurement of TGA, BD showed the best heat stability, and followed by PG, EG. Glass transition temperature increased in the order PG, EG, BD by the result of DMA.
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Study on Mechanical Properties and Viscoelastic Properties of Bio-polyurethanes
Xiang Xu Li(리시앙수),Kyung Ho Jin(진경호),Ur Ryong Cho(조을룡) 한국고분자학회 2019 폴리머 Vol.43 No.5
바이오매스 유래의 azelaic acid, 1,3-propanediol(1,3-PD)를 사용하여 바이오 폴리에스터 폴리올을 합성하였다. 합성한 폴리에스터 폴리올에 MDI(4,4"-methylenebis (phenyl isocyanate)), H12MDI and IPDI(isophorone diisocyanate)와 사슬연장제로 1,4-butanediol(1,4-BD)을 넣고 바이오 폴리우레탄을 합성하였다. 그리고 사슬연장제 없이 poly(1,4-butylene adipate)를 폴리올로 사용하여 일반 폴리우레탄을 합성하였다. 고분자 가공분석기(RPA)의 변형 스윕(strain sweep) 기능을 사용하여 제조된 폴리우레탄의 점탄성을 조사하였다. UTM, shore A, ball rebound 및 taber기계를 사용하여 폴리우레탄의 인장강도, 경도, 반발탄성 및 내마모성 측정을 통하여 기계적 물성을 확인하였다. 제조된 바이오 폴리우레탄은 일반 폴리우레탄보다 더 좋은 점탄성, 내마모성 및 신장률(elongation rate)을 보였다. The bio-polyester polyol has been prepared by azelaic acid and 1,3-propanediol(1,3-PD) from biomass with esterification synthesis method, and MDI (4,4"-methylenebis (phenyl isocyanate)), H12MDI and IPDI (isophorone diisocyanate) were used as isocyanates, 1,4-butanediol(1,4-BD) was used as chain extender. It also had been set the general polyurethane with SS-106 polyol, and bio-polyurethane without chain extender as control groups. The viscoelastic behaviors of the bio-polyurethanes were explored using a rubber processing analyzer (RPA) in the mode of strain sweep. And the mechanical properties (tensile strength, hardness value, resilience, abrasion resistance) were characterized by UTM, shore A tester, ball rebound and taber abrasion resistance tester. From the results above, the bio-polyurethane which synthesized in this research with bio-polyester polyol showed better abrasion resistance, elongation rate and viscoelastic properties compared to the general polyurethane material as elastomers.
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연구논문 : 다중회귀모형을 이용한 벤츄리가 없는 충격기류식 여과집진장치 압력손실 예측
서정민 ( Jeong Min Suh ),박정호 ( Jeong Ho Park ),조재환 ( Jae Hwan Cho ),진경호 ( Kyung Ho Jin ),정문섭 ( Moon Sub Jung ),이병인 ( Pyong In Yi ),홍성철 ( Sung Chul Hong ),시바쿠마르최금찬 ( S Sivakumar ),최금찬 ( Kum Chan Choi ) 한국환경과학회 2014 한국환경과학회지 Vol.23 No.12
In this study, pressure drop was measured in the pulse jet bag filter without venturi on which 16 numbers of filter bags (Ø140 × 850 ℓ) are installed according to operation condition(filtration velocity, inlet dust concentration, pulse pressure, and pulse interval) using coke dust from steel mill. The obtained 180 pressure drop test data were used to predict pressure drop with multiple regression model so that pressure drop data can be used for effective operation condition and as basic data for economical design. The prediction results showed that when filtration velocity was increased by 1%, pressure drop was increased by 2.2% which indicated that filtration velocity among operation condition was attributed on the pressure drop the most. Pressure was dropped by 1.53% when pulse pressure was increased by 1% which also confirmed that pulse pressure was the major factor affecting on the pressure drop next to filtration velocity. Meanwhile, pressure drops were found increased by 0.3% and 0.37%, respectively when inlet dust concentration and pulse interval were increased by 1% implying that the effects of inlet dust concentration and pulse interval were less as compared with those changes of filtration velocity and pulse pressure. Therefore, the larger effect on the pressure drop the pulse jet bag filter was found in the order of filtration velocity(Vf), pulse pressure(Pp), inlet dust concentration(Ci), pulse interval(Pi). Also, the prediction result of filtration velocity, inlet dust concentration, pulse pressure, and pulse interval which showed the largest effect on the pressure drop indicated that stable operation can be executed with filtration velocity less than 1.5 m/min and inlet dust concentration less than 4 g/m3. However, it was regarded that pulse pressure and pulse interval need to be adjusted when inlet dust concentration is higher than 4 g/m3. When filtration velocity and pulse pressure were examined, operation was possible regardless of changes in pulse pressure if filtration velocity was at 1.5 m/min. If filtration velocity was increased to 2 m/min. operation would be possible only when pulse pressure was set at higher than 5.8 kgf/cm2. Also, the prediction result of pressure drop with filtration velocity and pulse interval showed that operation with pulse interval less than 50 sec. should be carried out under filtration velocity at 1.5 m/min. While, pulse interval should be set at lower than 11 sec. if filtration velocity was set at 2 m/min. Under the conditions of filtration velocity lower than 1 m/min and high pulse pressure higher than 7 kgf/cm2, though pressure drop would be less, in this case, economic feasibility would be low due to increased in installation and operation cost since scale of dust collection equipment becomes larger and life of filtration bag becomes shortened due to high pulse pressure.
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