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에너지의 가용성과 열역학의 재구성 (I) 가역세계 열역학
정평석,노승탁 대한기계학회 1993 대한기계학회논문집 Vol.17 No.5
본 연구에서는 또하나의 새로운 서술방식을 제시하게 되는데, 먼저 에너지 이동현상으로서의 일중에서 가용일을 분리하고, 가역과정만이 가능한 세계 즉 가역세 계 안에서 측정과 산정이 가능하도록 열역학의 가장 중요한 물리량인 온도와 엔트로피, 열 등을, 가용일의 가측성을 이용하여 정의한 다음, 그러한 제한조건하에서 기존 열역 학의 기본 법칙들이 어떻게 표시되는가 살펴보고, 이것을 비가역과정에 확장하는 식의 순서에 따라 열역학의 기존원리들에 대한 서술을 재구성하고자 한다. In conventional thermodynamics, energy is regarded as a physical quantity transferring from one system to another, but in present study, the real energy is regarded as a physical quantity coming out from one interaction and absorbing into another interaction between two systems. To reconstruct thermodynamics with such a point of view, available work is distinguished from half work in conventional work concepts, and a special space named reversible world is proposed in which every process is reversible and the only measurable quantity is available work and just the equality between the intensities of two systems can be verified. As results, thermodynamic laws are arranged into two principles in the reversible world-conservations of energy elements and conservation of available energy. It means the exsistences of state properties corresponding to transferring energy elements and the available work. The former are extensive properties and the later is named potential work which is a property of the composite system and a kind of mathematical distance. The conventional available energy (exergy) and internal energy can be explained as the special cases of potential work, and the conventional first law of thermodynamics can be derived from the principle of the conservation of available energy. With these new concepts, the description of thermodynamic processes is more comprehensive. The second law of thermodynamics is no longer needed in the reversible world.
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정평석,김수연,Jeong, Pyeong-Seok,Kim, Su-Yeon 대한기계학회 1997 大韓機械學會論文集B Vol.21 No.2
Thermodynamic behavior of a composite system which is composed of two simple thermal subsystems with constant heat capacities is analyzed, and several thermodynamic phenomena are investigated. The changes of the states and the potential work of the composite system are shown as the interaction between the subsystems in the composite system. The potential work is defined as the possible maximum available work from the composite system, and it is a thermodynamic property of the composite system. The decrease of the potential work is the same as the available work output from the composite system in reversible processes. The dissipation of available work is directly connected to the generation of entropy. The concepts of exergy and internal energy can be explained as a special case of the potential work.
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정평석,김창욱,김효경 대한기계학회 1990 대한기계학회논문집 Vol.14 No.4
본 연구에서는 비열이 일정하고 초기온도가 주어진 열원으로부터, 일정한 열 전달 용량의 열교환기를 사용하여 최대의 에너지를 전달시키기 위한 조건을 구해 보기 로 한다. 즉, 저온유동은 고온의 열원유동과 대항류로서 열교환하며 위치에 따라 저 온유체의 온도가 가역 단열압축 또는 팽창에 의하여 임의로 조절될 수 있는 일반적인 경우에 대하여, 저온유체가 최대의 가용 에너지를 흡수하기 위한 온도분포를 변분법 문제로서 해석하고 그에 다른 부수조건들을 검토하고자 한다.
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정평석,김수연 대한기계학회 1987 대한기계학회논문집 Vol.11 No.6
본 연구에서는 최적설계를 위한 기초로서, 고정된 두 열원사이에서 작동하는 열기관을 예로 들어 운전조건에 따른 출력과 효율의 변화를 정성적으로 설명하여 출력 과 효율의 최대값이 극대값으로 나타남을 보이고, 경제적 측면에서 이들의 의의 및 경 제적 최적운전조건과의 관계 등을 고찰하려 한다. Considering heat transfer and heat loss processes for the heat engine operating between two fixed heat reservoirs, it may be qualitatively explained that the maxima of power output and its efficiency depending upon operating conditions are extreme maxima. Furthermore, it is also found that from an economic point of view the above two extremes are related to extreme minima of plant cost per unit power output and operation cost per unit power output respectively, and the condition of minimum cost per unit power output exists between the extreme minimum conditions of plant cost per unit power output and that of operation cost per unit power output.
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정평석,김수연,김중엽,류제욱 대한기계학회 1993 대한기계학회논문집 Vol.17 No.1
본 연구에서는 이 사이클 주위에 열전달이 추가된 열기관에 대하여 최대출력 조건 등을 구하고, 내부의 사이클이 각각 타노 사이클 및 브레이튼 사이클인 경우의 결과와 비교하여, 내적가역 최대출력 사이클들의 특성을 밝히고자 한다. Pseudo-Brayton cycle is defined as an ideal Brayton cycle admitting the difference between heat capacities of working fluid during heating and cooling processes. The endo-pseudo-Brayton cycle which is a pseudo-Brayton cycle with heat transfer processes is analyzed with the consideration of maximum power conditions and the results were compared with those of the endo-Carnot cycle and endo-Brayton cycle. As results, the maximum power is an extremum with respect to the cycle temperature and the flow heat capacities of heating and cooling processes. At the maximum power condition, the heat capacity of the cold side is smaller than that of heat sink flow. And the heat capacity of endo-Brayton cycle is always between those of heat source and sink flows and those of the working fluids of pseudo-Brayton cycle. There is another optimization problem to decide the distribution of heat transfer capacity to the hot and cold side heat exchangers. The ratios of the capacies of the endo-Brayton and the endo-pseudo-Braton cycles at the maximum power condition are just unity. With the same heat source and sink flows and with the same total heat transfer caqpacities, the maximum power output of the Carnot cycle is the least as expected, but the differences among them were small if the heat transfer capacity is not so large. The thermal efficiencies of the endo-Brayton and endo-Carnot cycle were proved to be 1-.root.(T$_{7}$/T$_{1}$) but it is not applicable to the pseudo-Brayton case, instead it depends on comparative sizes of heat capacities of the heat source and sink flow.w.
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