남동 - 황해 대륙붕의 준표층 니질퇴적물에서 산출되는 그레자이트

이찬희,진재화,장세원,이성록,이치원 ( Chan Hee Lee,Jae Hwa Jin,Se Won Chang,Sung Rock Lee,Chi Won Lee ) 한국광물학회 1995 광물과 암석 (J.Miner.Soc.Korea) Vol.8 No.1

Geochemical Variation of Authigenic Glauconite from Continental Shelf of the Yellow Sea, off the SW Korea

이찬희,이성록,이치원,최석원,Lee, Chan Hee,Lee, Sung-Rock,Lee, Chi-Won,Choi, Suck-Won The Korean Society of Economic and Environmental G 1997 자원환경지질 Vol.30 No.4

황해 대륙붕의 준고화된 표층퇴적물에서 자생하는 해록석들을 산출상태와 외부조직에 따라 괴상형, 균열형 및 다공질형으로 분류하였다. 이 해록석은 현세의 해침에 의하여 퇴적된 표층의 사질퇴적물내에 산포상으로 산출되며, 보통 0.1~1 mm 크기의 직경을 갖는다. x-선 회절분석 결과로 계산된, 해록석의 단위포와 크기는 $a=5.242{\AA}$, $b=9.059{\AA}$, $c=10.163{\AA}$, ${\beta}=100.5^{\circ}$, $V=474.53{\AA}^3$ 이고, 화학조성과 단위포의 크기로 계산된 밀도는 $2.60{\pm}0.45gm/cc$ 이다. 이 광물은 가열실험시 $10{\AA}$의 회절선이 증가하는 것으로 볼때 일정한 팽윤층을 갖는 것으로 보인다. $O_{10}(OH)_2$를 기준으로 평균조성을 구하면, 팔면체 자리의 Fe 함량은 1.19~2.06 이고, Al 함량은 0.18~0.76 이다. Fe와 Al은 서로 치환관계를 보이며 다공질형에서 괴상형으로 갈수록 Fe의 함량은 증가하고 Al은 감소한다. Mg의 함량은 0.35~0.54로서 Al이 높을수록 Mg의 양도 증가한다. K의 함량은 0.34~0.71의 범위를 보이며 다공질형에서 괴상형으로 갈수록 증가한다. 괴상형 또는 균열형 해록석은 질서/무질서의 혼합층 운모이며, 다공질형의 해록석은 혼합층 일라이트/스멕타이트로서 7~27%의 팽윤층을 포함한다. 이 광물은 표층 퇴적물이 퇴적된후에 극미립의 퇴적입자를 핵으로, 환원환경하에서 발생하는 퇴적물의 분해 및 생물체 파편과의 반응에 따라 자생한 것으로 추정된다. The massive, fractured and porous-type of glauconite, which is subdivided by surface morphology, occur in subtidal sand and semiconsolidated intertidal sand/mud from continental shelf of the southeastern Yellow Sea. This area is presumed to be a part of Holocene transgressive tidal systems tract. The glauconite, pellet-like grains with diameter of 0.1 to 1 mm, is scattered in surface sand sediments. Results of X-ray diffraction data of the minerals are monoclinic with $a=5.242{\AA}$, $b=9.059{\AA}$, $c=10.163{\AA}$, ${\beta}=100.5^{\circ}$, $V=474.53{\AA}^3$. Thermal treatments on the oriented glauconite increase the X-ray diffraction intensity near $10{\AA}$ (001), suggesting the presence of some expandable layers. Specific gravity of the glauconite is $2.60{\pm}0.45gm/cc$ on the basis of chemical composition and unit-cell dimensions. Based on $O_{10}(OH)_2$, chemical composition of glauconites, octahedral Fe content ranges from 1.19 to 2.06 atoms, corresponding octahedral AI is 0.18 to 0.76 atoms, which progressively substitute Fe for AI with increasing from porous to massive-type. The Mg content ranges from 0.35 to 0.54 atoms, and shows higher with increasing Al contents. A systematic increase of interlayer K from 0.34 to 0.71 is also observed with apparent increases from porous to massive-type, and related to a proportion of expandable layers. The clay preserved in glauconite, which is recognized as ordered/disordered (massive to fractured-type). The interstratified illite/smectite (porous-type), contains 7 to 27 % expandable layers. The glauconite seems to originate from post depositional authigenic growth in reducing environments promoted by the dissolution of clay minerals and biogenic debris.

나림광산 수계의 토양과 퇴적물에 관한 지구화학적 특성: 중금속 원소의 분산, 부화 및 기원

이찬희,이현구,이종창,Lee, Chan Hee,Lee, Hyun Koo,Lee, Jong Chang 대한자원환경지질학회 1998 자원환경지질 Vol.31 No.4

Geochemical characteristics of environmental toxic elements at the Narim mine area were investigated on the basis of major, minor, rare earth element geochemistry and mineralogy. Ratios of $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ in soils and sediments range from 11.57 to 22.21 and from 1.86 to 3.93, and are partly negative and positive correlation against $SiO_2/Al_2O_3$ (3.41 to 4.78), respectively. These suggested that sediment source of host granitic gneiss could be due to rocks of high grade metamorphism originated by sedimentary rocks. Characteristics of some trace and rare earth elements of V/Ni (0.33 to 1.95), Ni/Co (2.00 to 6.50), Zr/Hf (11.27 to 53.10), La/Ce (0.44 to 0.55), Th/Yb (4.07 to 7.14), La/Th (2.35 to 3.93), $La_N/Yb_N$ (6.58 to 13.67), Co/Th (0.63 to 2.68), La/Sc (3.29 to 5.94) and Sc/Th (0.49 to 1.00) are revealed a narrow range and homogeneous compositions may be explained by simple source lithology. Major elements in all samples are enriched $Al_2O_3$, MgO, $TiO_2$ and LOI, especially $Fe_2O_3$ (mean=7.36 wt.%) in sediments than the composition of host granitic gneiss. The average enrichment indices of major and rare earth elements from the mining drainage are 2.05 and 2.91 of the sediments and are 2.02 and 2.60 of the soils, normalizing by composition of host granitic gneiss, respectively. Average composition (ppm) of minor and/or environmental toxic elements in sediments and soils are Ag=14 and 1, As=199 and 14, Cd=22 and 1, Cu=215 and 42, Pb=1770 and 65, Sb=18 and 3, Zn=3333 and 170, respectively, and extremely high concentrations are found in the subsurface sediments near the ore dump. Environmental toxic elements were strongly enriched in all samples, especially As, Cd, Cu, Pb, Sb and Zn. The level of enrichment was very severe in mining drainage sediments, while it was not so great in the soils. Based on the EPA value, enrichment index of toxic elements is 8.63 of mining drainage sediments and 0.54 of soils on the mining drainage. Mineral composition of soils and sediments near the mining area were partly variable being composed of quartz, mica, feldspar, amphibole, chlorite and clay minerals. From the gravity separated mineralogy, soils and sediments are composed of some pyrite, arsenopyrite, chalcopyrite, sphalerite, galena, goethite and various hydroxide minerals.

천안-아산 지역 청동기시대 무문토기의 재료학적 특성과 고고과학적 의미

이찬희,조선영,어언일,김란희,Lee, Chan Hee,Cho, Seon Yeong,Eo, Eon Il,Kim, Ran Hee 한국문화재보존과학회 2015 보존과학회지 Vol.31 No.1

이 연구는 천안-아산 지역 출토 청동기시대 토기편과 고토양을 대상으로 재료과학적 분석을 통해 상호 동질성을 검토한 것이다. 토기편은 현미경하에서 1mm 이하의 세립질 광물에서 10mm 정도의 극조립 광물까지 분급과 원마도가 다양한 비짐들이 혼재되어 있다. 또한 대부분 토기편은 조직의 치밀도가 떨어졌으며 다양한 모양과 크기의 기공이 분포하였다. X-선 회절분석에서는 석영, 장석, 운모, 각섬석, 녹니석과 같은 주구성광물 외에 활석이 동정되었으며, 이 활석은 토양에서는 검출되지 않아 인위적으로 첨가한 물질인 것으로 판단된다. 토기편 중 녹니석이 검출되지 않는 것들은 $850^{\circ}C$ 이하에서 소성되었을 것으로 추정하였으며, 운모 및 활석이 동정된 토기는 $900^{\circ}C$ 이하에서 소성이 완료된 것으로 해석된다. 각 유적의 토기와 토양의 지구화학적 분석결과, 주성분, 미량, 희토류원소의 진화경향이 거의 일치하여 각 유적의 토기는 대부분 유적을 구성하는 고토양을 태토로 이용한 것으로 판단된다. The excavated potteries and raw clays of the Bronze Age from the archaeological sites in the Cheonan-Asan area were studied on material scientific characteristics and homogeneity. Under the microscope, grainsize of the tempers in the potteries were distributed from less than 1mm to 10mm. Microtexture of the potteries showed various shapes and sizes of pores. In addition to the main minerals such as quartz, feldspar, mica, hornblende, chlorite and talc were found from the X-ray diffraction analysis of potteries, while talc was not found in the raw clay. Therefore, it was considered as an artificially added mineral. Firing temperature of the potteries, which did not contain chlorite, are assumed that they were baked below $850^{\circ}C$. On the other hand, the potteries which had mica and talc, are assumed that they were fired below $900^{\circ}C$. The geochemical characteristics of the potteries and raw clays showed very similar patterns, that means the potteries were produced by using the raw clay sources from each site.

대청호 상류, 회남일대에 분포하는 탄질 변성니질암과 하상 퇴적물의 환경유해원소에 관한 지화학적 거동, 분산 및 부화

이찬희,이현구,Lee, Chan Hee,Lee, Hyun Koo 대한자원환경지질학회 1997 자원환경지질 Vol.30 No.3

The Hoenam area, up the Taecheong lake, composed mainly of low grade coal-bearing metapelites within the Ogcheon Supergroup. These coal formations are developed discontinuously several hundred meters and swelling from 10 to 300 cm along the host metapelites. Although the formations have been mined for coal, but already mined out, and the formations were higher content (mean value of 42 samples) of environmental toxic elements as As (13 ppm). Ba (1.81 wt. %), Cd (2 ppm), Cr (188 ppm), Cu (87 ppm), Mo (214 ppm), Pb (25 ppm), Sb (3 ppm), Se (12 ppm), U (55 ppm), V (2124 ppm) and Zn (234 ppm) than the host metapelites and the NASC. The Al, Ti, Mg, K and Na contents in stream sediments derived from the Hando and Bugook mine area were highly concentrations than the samples from the Samseongjeil mine area. The mean value (wt. %) of Fe (10.07), Mn (0.15), Ca (0.84), P (0.18) and Ba (0.77) influenced by the Samseongjeil mine were higher than the other mine drainage sediments. The mean content (ppm) of environmental toxic elements in drainage sediments from the Samseongjeil mine were taken As (2083), Cu (447), Mo (202), Ni (720), Pb (42), U (250), V (1070) and Zn (2632), which are extremely high concentrations against NASC and EPA. Characteristics of elemental behavior and dispersion of the all toxic elements are the same as increased with increasing U, V, and Cu. Rare earth elements in the sediments are enriched with LREE (La, Ce and Nd) from the drainage on strong concentration of toxic elements. The pH of stream water is neutral, but pH of the sediments ranged from 4.92 to 6.93 (mean 6.22), those are slightly acid in the Hando mine area. Major elements in the host rocks at the Hoenam area are mostly depleted especially Ca, excepting Ti and Ba, normalized with NASC. The sediments were highly enriched of Ti, Fe, Mg, Mn and Ba, but depleted of Al, K, Ca, Na and P on the basis of host rocks and NASC. Minor and environmental toxic elements in the host rocks were strongly enriched all elements (As, Cd, Mo, Se, D, V and Zn), excepting Co, Ni and Sr. Enrichment index (mean value) about toxic elements (As, Cr, Cu, Fe, Ni, Pb and Zn) of the sediments in this area have taken 41.35 (Hando mine drainage; 2.73, Samseongjeil mine drainage; 113.14 and Bugook mine drainage; 8.19), those are seriously contaminated by environmental toxic elements.

탄산염암 층준교대형 백전광상의 천열수 금-은 광화작용과 생성환경

이찬희,박희인,Lee, Chan Hee,Park, Hee-In 대한자원환경지질학회 1996 자원환경지질 Vol.29 No.2

The Baegjeon Au-Ag and Sb deposits, small of disseminated-type gold deposits are formed as a result of epithermal processes associated a shallow-seated Cretaceous Yeogdun granitoids intrusion. The orebodies are formed by the replacement of carbonate minerals in thin-bedded oolitic limestone beds favorable for mineralization within the upper-most Cambrian Pungchon Limestone Formation. The mineralization can be recognized one stage, ore minerals composed of base metal sulfides, electrum, AgSb-S, Ag-Cu-S, and Sb-S minerals. Gold-bearing minerals consist of electrum and submicroscopic invisible gold in pyrite and arsenopyrite. The composition of electrums ranges from 33.58 to 63.48 atomic % Ag. Fluid inclusion studies reveal that ore fluids were low saline $NaCl-CO_2-H_2O$ system. Temporary fluid mixing and boiling occured in later stage. Fluid inclusion data indicates the homogenization temperatures and salinities of NaCl eqivalent wt% were 176 to $246^{\circ}C$ and from 0.0 to 4.8 wt%, respectively. And $-logfs_2$, of mineralization obtained by thermodynamic considerations as 12.4 to 13.8 atm. The ${\delta}^{34}S_{H_2S}$, values of hydrothermal sulfides were calculated to be 6.8 to 10.2‰ which was of sedimentary origin. The ${\delta}^{18}O_{H_2O}$ and ${\delta}^{13}C_{CO_2}$, range from -3.9 to 9.6‰, from -1.1 to -2.2‰, and ${\delta}D$ range from -89 to -118‰, respectively. The Au deposition during mineralization seems to have occurred as a result of decrease of temperature, $fs_2$, $fo_2$, and pH probably due to oxidation by meteoric water mixing, which destabilized original $Au(HS)^-{_2}$. The mineralization of the Baegjeon deposits is similar to the Carlin-type deposits characterized by sediments-hosted epithermal bedding replacement disseminated gold deposits.

얼굴 영상에서 유전자 알고리즘 기반 형판정합을 이용한 눈동자 검출

이찬희,장경식,Lee, Chan-Hee,Jang, Kyung-Shik 한국정보통신학회 2009 한국정보통신학회논문지 Vol.13 No.7

본 논문에서는 다양한 조명하에서의 단일 얼굴 영상에 대해 유전자 알고리즘과 형판 정합을 이용하여 빠르게 눈동자를 검출하는 방법을 제안한다. 유전 알고리즘을 이용한 기존의 눈동자 검출 방법은 초기 개체군의 위치에 민감하여 낮은 눈 검출율을 보이며, 도한 그 결과가 일관적이지 않은 문제점을 갖는다. 이와 같은 문제점을 해결화기 위해 얼굴영상에서 지역적 최소치를 추출하고 형판과 가장 높은 적합도를 가지는 개체들로 초기 개체군을 생성 하였다. 각각의 개체는 형판의 기하학적 변환 정보로 구성되며, 형판 정합에 의해 눈동자가 검출된다. 실험을 통하여 본 논문에서 제안한 눈 후보 검출을 통하여 단일 영상에서도 눈 검출의 정확도와 높은 검출률을 확인하였다. In this paper, we propose a robust eye detection method using template matching based on genetic algorithm in the single facial image. The previous works for detecting pupil using genetic algorithm had a problem that the detection accuracy is influnced much by the initial population for it's random value. Therefore, their detection result is not consistent. In order to overcome this point we extract local minima in the facial image and generate initial populations using ones that have high fitness with a template. Each chromosome consists of geometrical informations for the template image. Eye position is detected by template matching. Experiment results verify that the proposed eye detection method improve the precision rate and high accuracy in the single facial image.

충남탄전, 대동누층군의 셰일과 탄질암에 관한 암석화학 및 환경지구화학적 특성

이찬희,이현구,김경웅,Lee, Chan Hee,Lee, Hyun Koo,Kim, Kyoung-Woong 대한자원환경지질학회 1997 자원환경지질 Vol.30 No.5

Characteristics of sedimentary rocks and enrichment of toxic elements in shale and coal from the Chungnam coal field were investigated based upon geochemistry of major, trace and rare earth elements. Shale and coal of the area are interbedded along the Traissic to the Jurassic Daedong Supergroup, which can be subdivided into grey shale, black shale and coal. The coal had been mined, however all the mines are abandonded due to the economic problems. The shale and coal are characterized by relatively low contents of $SiO_2$, and $Al_2O_3$ and high levels of loss-on-ignition (LOI), CaO and $Na_2O$ in comparison with the North American Shale Composite (NASC). Light rare earth elements (La, Ce, Yb and Lu) are highly enriched with the coal. Ratios of $Al_2O_3/Na_2O$ and $K_2O/Na_2O$ in shale and coal range from 30.0 to 351.8 and from 4.2 to 106.8, which have partly negative correlations against $SiO_2/Al_2O_3$ (1.24 to 6.06), respectively. Those are suggested that controls of mineral compositions in shale and coal can be due to substitution and migration of those elements by diagenesis and metamorphism. Shale and coal of the area may be deposited in terrestrial basin deduced from high C/S (39 to 895) and variable composition of organic carbon (0.39 to 18.40 wt.%) and low contents of reduced sulfur (0.01 to 0.05 wt.%). These shale and coal were originated from the high grade metamorphic and/or igneous rocks, and the rare earth elements of those rocks are slightly influenced with diagenesis and metamorphism on the basis of $Al_2O_3$ versus La, La against Ce, Zr versus Yb, the ratios of La/Ce (0.38 to 0.85) and Th/U (3.6 to 14.6). Characteristics of trace and rare earth elements as Co/Th (0.07 to 0.86), La/Sc (0.31 to 11.05), Se/Th (0.28 to 1.06), V/Ni (1.14 to 3.97), Cr/V (1.4 to 28.3), Ni/Co (2.12 to 8.00) and Zr/Hf (22.6~45.1) in the shale and coal argue for inefficient mixing of the simple source lithologies during sedimentation. These rocks also show much variation in $La_N/Yb_N$ (1.36 to 21.68), Th/Yb (3.5 to 20.0) and La/Th (0.31 to 7.89), and their origin is explained by derivation from a mixture of mainly acidic igneous and metamorphic rocks. Average concentrations in the shale and coal are As=7.2 and 7.5, Ba=913 and 974, Cr=500 and 145, Cu=20 and 26, Ni=38 and 35, Pb=30 and 36, and Zn=77 and 92 ppm, respectively, which are similar to those in the NASC. Average enrichment indices for major elements in the shale (0.79) and coal (0.77) are lower than those in the NASC. In addition, average enrichment index for rare earth elements in coal (2.39) is enriched rather than the shale (1.55). On the basis of the NASC, concentrations of minor and/or environmental toxic elements in the shale and coal were depleted of all the elements examined, excepting Cr, Pb, Rb and Th. Average enrichment indices of trace and/or potentially toxic elements (As, Cr, Cu, Ni, Pb, U and Zn) are 1.23 to 1.24 for shale and 1.06 to 1.22 for coal, respectively.

천안 도림리 백제시대 분묘 유적 석재의 암석기재적 특성과 원산지 연구

이찬희,조지현,박성미,Lee, Chan Hee,Cho, Jihyun,Park, Sung Mi 한국문화재보존과학회 2021 보존과학회지 Vol.37 No.5

We analyzed the provenance and petrographic characteristics for the rock properties from stone-lined tomb and stone chamber tomb at the Dorim-ri site of the Baekje Kingdom, located in Cheonan. The two tombs consist of 10 kinds of rocks including gneiss, diorite, and andesite. The major rock type is gneiss (54.3%), which composes the main chamber walls of the tombs. Diorite (11.3%) and andesite (10.6%) also make up a large percentage of the rocks, tending to be used to fill the space between the main chamber walls. Thus, the stones appear to have been used according to their shape and the disposition of the site, respectively. Investigation of their provenance, confirmed their source area to be near the Ipjang Reservoir, about 1 km away from the site, and their procurement was probably conducted via a waterway. This result might serve as basic data regarding the material procurement system of ancient tomb culture and for preservation measures for archaeological sites. 이 연구에서는 천안 도림리 유적 출토 백제시대 석곽묘와 석실분의 구성암석에 대한 암석기 재적 특성과 원산지를 분석하였다. 이 두 분묘는 편마암과 섬록암 및 안산암을 비롯한 총 10종의 다양한 석재로 구성되어 있다. 특히 편마암이 가장 높은 점유율(54.3%)을 보이며, 벽석의 주요 석재로 사용되었다. 또한 섬록암(11.3%)과 안산암(10.6%)은 사잇돌로 사용된 경향을 보여, 형태와 상황에 맞게 석재를 활용한 것으로 판단된다. 석재의 공급지는 유적과 약 1 km 떨어진 입장저수지 인근으로 확인되었고, 수로를 통해 조달했을 것으로 해석된다. 이 결과는 고대 분묘문화의 재료조달 체계와 유구의 보존을 위한 기초자료로 활용할 수 있을 것이다.

섬유성이형성증 유래세포의 특성연구

이찬희,한인,서병무,Lee, Chan-Hee,Han, Ihn,Seo, Byoung-Moo 대한구강악안면외과학회 2009 대한구강악안면외과학회지 Vol.35 No.5

Purpose: Fibrous dysplasia (FD) is a fibro-osseous disease associated with activating missense mutations of the gene encoding the $\alpha$-subunit of stimulatory G protein. FD may affect a single bone (called monostotic form) or multiple bones (called polyostotic form). The extent of lesions reflects the onset time of mutation. In this study, cells from monostotic FD in maxilla of a patient were isolated and cultured in vitro for characterization. Materials and Methods: The single cells were released from FD lesion which was surgical specimen from 15 years-old boy. These isolated cells were cultured in vitro and tested their proliferation activity with MTT assay. In osteogenic media, these cells underwent differentiation process comparing with its normal counterpart i.e. bone marrow stromal cells. The proliferated FD cells were detached and transplanted into the dordsal pocket of nude mouse and harvested in 6 weeks and 12 weeks. Results and Summary: FD cells have an increased proliferation rate and poor differentiation. As a result, cells isolated from FD lesion decreased differentiation into osteoblast and increased proliferation capacity. MTT assay presented that proliferation rate of FD cells were higher than control. However, the mineral induction capacity of FD was lesser than that of control. Monostotic FD cells make fewer amounts of bone ossicles and most of them are woven bone rather than lamellar bone in vivo transplantation. In transplanted FD cells, hematopoietic marrow were not seen in the marrow space and filled with the organized fibrous tissue. Therefore, they were recapitulated to the original histological features of FD lesion. Collectively, these results indicated that the FD cells were shown that the increased proliferation and decreased differentiation potential. These in vitro and in vivo system can be useful to test FD cell's fate and possible.