영남문집해제 : 괴당집

이만승 영남대학교 민족문화연구소 1988 민족문화연구소 자료총서 Vol.4 No.-

니켈과 코발트 혼합 염산용액의 이온평형

이만승,오영주 대한금속재료학회 2004 대한금속·재료학회지 Vol.42 No.9

A chemical model was developed for the mixed chloride solution of nickel and cobalt at 25℃. This model consisted of chemical equilibria, mass and charge balance equations. The activity coefficients of solutes and water activity were calculated by using Bromley equation. Cobalt ion has a strong tendency to form complexes with chloride ion such as CoCl₃^(-) and CoCl₄^(2-), while the nickel chloride complex was only NiCI'. Distribution of nickel and cobalt species with the compositions and pH values of the solution was obtained from the analysis of ionic equilibria in mixed chloride solutions. The predicted pH values for NiC1₂-CoC1₂-HCI-H₂O system agreed well with those measured at 25℃ up to ionic strength of 9.53 m.

회전냉각기에서 고체와 가스의 온도분포해석

이만승,최주석,전철근 한국자원리싸이클링학회 2002 資源 리싸이클링 Vol.11 No.3

회전냉각기에서 일어나는 정상상태 열전달을 1차원으로 해석하였다 회전냉각기로 입력되고 배출되는 공기온도를 경계조건으로 삼았다. 경계 및 조업조건으로부터 2개의 상미분방정식과 2개의 대수방정식을 동시에 만족시키는 해를 계산하여 고체, 공기 벽의 온도분포를 구하였다. 본 연구에서 계산한 외벽온도는 실제 가동중인 회전냉각기에서 실측한 외벽온도와 서로 잘 일치하였다. Heat transfer occurring in the rotary cooler was analyzed by applying a one-dimensional steady state. The temperature of inlet gas and the measured temperature of outlet gas were used as boundary conditions. Axial temperature distribution of solid, gas and wall were calculated by solving two differential equations and two algebraic equations under the constraint of two point boundary conditions and operating conditions. The temperatures of outer wall calculated in this study were in good agreement with those measured from running rotary cooler.

염산용액에서 Bromley식을 이용한 염화니켈의 이온평형해석

이만승,이광섭,Lee Man-Seung,Lee Gwang-Seop 한국자원리싸이클링학회 2003 資源 리싸이클링 Vol.12 No.3

화학평형, 물질수지 및 전기적 중성식을 고려하고 Bromley식으로 용질들의 활동도계수를 구하여 염산용액에서 염화니켈의 이온평형을 해석하였다. 본 연구에서 고려한 조성범위에서 니켈을 함유한 화학종의 대부분은 $Ni^{2+}$ 와 $NiCl^{+}$ 로 존재하고 니켈수산화물의 농도분율은 매우 낮으나, 용액의 pH가 증가함에 따라 $Ni_4$ $(OH)_{4}^{4+}$ 의 농도분율은 급격히 증가하였다. $NiCl_2$ $-HCl-NaOH-H_2$O 계에 대해 전해질의 농도를 변화시키며 $25^{\circ}C$에서 측정한 pH값과 계산값은 이온강도 9.4m정도의 범위까지 서로 잘 일치하였다. ionic equilbria of nickel chloride in hydrochloric acid solutions were analyzed by considering chemical equilibria, mass and charge balance equations. The activity coefficients of solutes were calculated by using Bromley equation. It was found that most of species containing nickel existed as $Ni^{2+}$ 와 $NiCl^{+}$. The mole fractions of nickel hydroxides were very low in the con-centration ranges considered in this study and the mole fraction of$Ni_4$ $(OH)_{4}^{4+}$ increased greatly with the pH of the solution. The pH values of $NiCl_2$ $-HCl-NaOH-H_2$O system at $25^{\circ}C$ calculated in this study agreed well with those experimentally measured up to ionic strength of 9.4m.

Alamine336염에 의한 FeCl₃ 용매추출평형

이만승,이경주 대한금속재료학회 2004 대한금속·재료학회지 Vol.42 No.2

Solvent extraction experiments of FeCl_(3) with Alamine336 salt were performed. It was found from the oading capacity of Alamine336 salt that the solvent extraction reaction depended on the ratio of initial concentration of Alamine336 to FeCl_(3). When the concentration of Alamine336 was in excess compared to that of FeCl_(3), alamine336 participated in the extraction reaction as a dimer. When the initial concentration ratio of Alamine336 to FeCl_(3) was below three, ferric chloride was extracted by monomeric Alamine336. The equilibrium constants of solvent extraction, K_(ex)-2.22×10^(4) and K_(ex)=6.41×10^(5) for monomeric and dimeric Alamine336 respectively, were determined from extraction data by considering activity coefficient of solutes in the aqueous phase. The predicted distribution coefficients of iron agreed well with those experimentally measured.

염산용액에서 PC88A에 의한 Sm의 용매추출

이만승,이광섭,이진영,김성돈,김준수 대한금속재료학회 2004 대한금속·재료학회지 Vol.42 No.10

Solvent extraction experiments of Sm were performed from chloride solution with PC88A and saponified PC88A. Solvent extraction reaction of Sm with PC88A and the corresponding equilibrium constant were evaluated from the experimental and ionic equilibria data as follows Sm^(3+)_(aq)+ 1.5H₂A_(2,org)= SmA_(3,org)+ 3H^(+)_(aq) , K = 0.33. The predicted distribution coefficients of Sm agreed well with the experimental results. The distribution coefficients of Sm with saponified PC88A and the values of equilibrium pH depended on the initial extraction conditions. When the concentration of PC88A was in excess of that of Sm, saponification of PC88A greatly enhanced the extraction of Sm. (Received June 21, 2004)

비누화 PC88A에 의한 NdCl₃와 SmCl₃용매추출의 화학모델

이만승,이광섭,이진영,김성돈,김준수 대한금속재료학회 2004 대한금속·재료학회지 Vol.42 No.10

A chemical model was developed to estimate equilibrium constant for the solvent extraction of Nd and Sm from chloride solution with saponified PC88A. The model could be employed to predict the distribution coefficient of metal from the initial extraction conditions. The model consisted of chemical equilibria, mass balance, charge balance and solvent extraction reaction. By applying the model to the experimental conditions and data, equilibrium constants for the solvent extraction of Nd and Sm were obtained. The effect of the saponification of PC88A on the extraction of Nd was explained in terms of the equilibrium constant obtained in this study and the change of equilibrium pH. The predicted distribution coefficients of Nd and Sm agreed well with those measured. (Received July 14, 2004)

Mixer-settler를 이용한 용매추출로 에칭폐액로부터 철과 니켈의 분리

이만승,이경주,이진영,안재우,오영주 대한금속재료학회 2004 대한금속·재료학회지 Vol.42 No.12

Solvent extraction and stripping experiments were conducted to separate iron from a spent FeC13 etching solution containing nickel. In the operation of mixer-settler, 7 extraction stages with 1.0 M Alamine336 in toluene, led to 98% extraction percentage of iron at equal phase ratio, when the flow rate of organic and aqueous were 35 mL/min and 5 mL/min, respectively. At equal phase ratio of aqueous to organic, 10 stripping stages with 0.01 M HC1 solution resulted in 99% stripping percentage of iron when the flow rate of stripping solution and loaded organic were 5 mL/min and 35 mL/min, respectively. The concentration of iron in the stripped solution was 133 g/L and this solution could be reused in the etching of nickel lead frame. (Received June 15, 2004)

염화(鹽貨)구리와 염화철(鹽貨鐵) 혼합용액(混合溶液)의 조성(組成)이 pH와 용액전위(溶液電位)에 미치는 영향(影響)

이만승,손성호,Lee, Man-Seung,Son, Seong-Ho 한국자원리싸이클링학회 2008 資源 리싸이클링 Vol.17 No.6

염화 제 2철용액에 의한 구리황화광의 침출액을 모사하기 위해 $FeCl_3$-$FeCl_2$-$CuCl_2$-CuCl-NaCl-HCl-$H_2O$의 조성을 지닌 합성용액을 제조하였다. 합성용액에서 염화철과 염화구리의 농도를 0.1에서 1 m까지 변화시키며 성분의 농도변화에 따른 $25^{\circ}C$에서 용액의 pH와 전위의 변화를 측정하였다. 염산의 농도가 일정한 조건에서 CuCl의 농도를 증가시키면 용액의 pH는 증가하였다. 그러나 염산과 CuCl의 농도가 일정한 조건에서 다른 용질의 농도를 증가시키면 수소이온의 활동도계수가 증가하면서 용액의 pH는 감소하였다. CuCl의 농도를 증가시키면 염화 제 1구리이온이 안정해지는 방향으로 반응이 진행하나 $FeCl_3$은 반대의 효과를 나타냈다. In order to simulate the leaching solution of copper sulfide ore in $FeCl_3$ solutions, synthetic solutions with composition of $FeCl_3$-$FeCl_2$-$CuCl_2$-CuCl-NaCl-HCl-$H_2O$ were prepared. The concentration of iron and copper chloride was varied from 0.1 to 1 m in synthetic solutions. The effect of composition on the mixed solution pH and potential at $25^{\circ}C$ was measured. When HCl concentration was constant, the increase of CuCl concentration increased solution pH. The increase of other solutes excluding HCl and CuCl decreased solution pH owing to the increase of the activity coefficient of hydrogen ion. A high CuCl concentration favored the redox equilibrium in the direction of Cu(I), while $FeCl_3$ had the opposite effect.

25℃에서 ZnSO₄-Fe₂(SO₄)₃-Na₂SO₄-H₂SO₄-NaOH-H₂O계에 대해 Pitzer식과 Vasil'ev식에 의한 이온평형해석 비교

이만승,이경주,남상호,Lee, Man-Seung,Lee, Kyoung-Ju,Nam, Sang-Ho 한국분석과학회 2003 분석과학 Vol.16 No.2

아연산화광 황산침출액에 적용가능한 이온평형모델을 개발하기 위해 Vasil'ev식과 Pitzer식에 의한 해석방법을 비교하였다. 이온강도가 9 m정도로 증가할수록 Vasil'ev식보다는 Pitzer식에 의한 용액의 이온평형결과가 정확하였다. 아연산화광 황산침출액을 모사하기위해 $25^{\circ}C$에서 $ZnSO_4-Fe_2(SO_4)_3-Na_2SO_4-H_2SO_4-NaOH-H_2O$계에 대해 전해질의 농도를 변화시키며 혼합한 용액의 pH 측정값과 본 연구에서 계산한 pH값은 서로 잘 일치하였다. To develop an ionic equilibria model applicable to the sulfuric acid leaching solutions of zinc oxide ore, the method of the Pitzer equation and that of the Vasil'ev equation were compared. As the ionic strength of the solution increased to 9 m, the results of ionic equilibria by the Pitzer equation were more accurate than those by Vasil'ev. To simulate the sulfuric acid leaching solutions of zinc oxide ore, the mixed solutions with the various composition of $ZnSO_4-Fe_2(SO_4)_3-Na_2SO_4-H_2SO_4-NaOH-H_2O$ were prepared. The pH values calculated in this study agreed well with those measured at $25^{\circ}C$.